Increasing levels and biomagnification of persistent organic pollutants (POPs) in Antarctic biota

Representatives of the Antarctic food web (krill, cephalopod, fish, penguin, seal) of the area around Elephant Island and from the Weddell Sea were analysed for the most recalcitrant organochlorine compounds. Due to sorption of the compounds to sinking particles and accumulation in sediments, two benthic fish species (Gobionotothen gibberifrons, Chaenocephalus aceratus) feeding on benthos invertebrates and fish reflected significantly increasing concentrations within a decade (1987-1996), while a benthopelagic species (Champsocephalus gunnari) feeding on krill did not. In the pelagic food chain, lipid normalised concentrations of all compounds increased from Antarctic krill to fish proving that biomagnification of highly lipophilic pollutants (log octanol-water partition coefficient>5) occurs in water-breathing animals. As top predators Weddell and southern elephant seals (Leptonychotes weddellii, Mirounga leonina) biomagnified the persistent organic pollutants relative to krill 30-160 fold with the exception of hexachlorobenzene, the levels of which were lower than in fish indicating its intense specific elimination.     

Analysis of the positive ionospheric response to a moderate geomagnetic storm using a global numerical model

Current theories of F-layer storms are discussed using numerical simulations with the Upper Atmosphere Model, a global self-consistent, time dependent numerical model of the thermosphere-ionosphere-plasmasphere-magnetosphere system including electrodynamical coupling effects. A case study of a moderate geomagnetic storm at low solar activity during the northern winter solstice exemplifies the complex storm phenomena. The study focuses on positive ionospheric storm effects in relation to thermospheric disturbances in general and thermospheric composition changes in particular. It investigates the dynamical effects of both neutral meridional winds and electric fields caused by the disturbance dynamo effect. The penetration of short-time electric fields of magnetospheric origin during storm intensification phases is shown for the first time in this model study. Comparisons of the calculated thermospheric composition changes with satellite observations of AE-C and ESRO-4 during storm time show a good agreement. The empirical MSISE90 model, however, is less consistent with the simulations. It does not show the equatorward propagation of the disturbances and predicts that they have a gentler latitudinal gradient. Both theoretical and experimental data reveal that although the ratio of [O]/[N₂] at high latitudes decreases significantly during the magnetic storm compared with the quiet time level, at mid to low latitudes it does not increase (at fixed altitudes) above the quiet reference level. Meanwhile, the ionospheric storm is positive there. We conclude that the positive phase of the ionospheric storm is mainly due to uplifting of ionospheric F2-region plasma at mid latitudes and its equatorward movement at low latitudes along geomagnetic field lines caused by large-scale neutral wind circulation and the passage of travelling atmospheric disturbances (TADs). The calculated zonal electric field disturbances also help to create the positive ionospheric disturbances both at middle and low latitudes. Minor contributions arise from the general density enhancement of all constituents during geomagnetic storms, which favours ion production processes above ion losses at fixed height under day-light conditions.     

Sea‐level and ocean‐current control on carbonate‐platform growth,Maldives, Indian Ocean

Multichannel high‐resolution seismic and multibeam data were acquired from the Maldives‐isolated carbonate platform in the Indian Ocean for a detailed characterization of the Neogene bank architecture of this edifice. The goal of the research is to decipher the controlling factors of platform evolution, with a special emphasis on sea‐level changes and changes of the oceanic currents. The stacking pattern of Lower to Middle Miocene depositional sequences, with an evolution of a ramp geometry to a flat‐topped platform, reflects variations of accommodation, which here are proposed to be primarily governed by fluctuations of relative sea level. Easterly currents during this stage of bank growth controlled an asymmetric east‐directed progradation of the bank edge. During the late middle Miocene, this system was replaced by a twofold configuration of bank development. Bank growth continued synchronously with partial bank demise and associated sediment‐drift deposition. This turnover is attributed to the onset and/or intensification of the Indian monsoon and related upwelling and occurrence of currents, locally changing environmental conditions and impinging upon the carbonate system. Mega spill over lobes, shaped by reversing currents, formed as large‐scale prograding complexes, which have previously been interpreted as deposits formed during a forced regression. On a regional scale, a complex carbonate‐platform growth can occur, with a coexistence of bank‐margin progradation and aggradation, as well as partial drowning. It is further shown that a downward shift of clinoforms and offlapping geometries in carbonate platforms are not necessarily indicative for a sea‐level driven forced regression. Findings are expected to be applicable to other examples of Cenozoic platforms in the Indo‐Pacific region.     

Automated mapping of rock slope geometry,kinematics and stability with RSS-GIS

A GIS-implemented, deterministic approach for the automated spatial evaluation of geometrical and kinematical properties of rock slope terrains is presented. Based on spatially distributed directional information on planar geological fabrics and DEM-derived topographic attribute data, the internal geometry of rock slopes can be characterized on a grid cell basis. For such computations, different approaches for the analysis and regionalization of available structural directional information applicable in specific tectonic settings are demonstrated and implemented in a GIS environment. Simple kinematical testing procedures based on feasibility criteria can be conducted on a pixel basis to determine which failure mechanisms are likely to occur at particular terrain locations. In combination with hydraulic and strength data on geological discontinuities, scenario-based rock slope stability evaluations can be performed. For conceptual investigations on rock slope failure processes, a GIS-based specification tool for a 2-D distinct element code (UDEC) was designed to operate with the GIS-encoded spatially distributed rock slope data. The concepts of the proposed methodology for rock slope hazard assessments are demonstrated at three different test sites in Germany.     

Singular value decomposition and cluster analysis as regression diagnostics tools for geodetic applications

It is well known that high-leverage observations significantly affect the estimation of parameters. In geodetic literature, mainly redundancy numbers are used for the detection of single high-leverage observations or of single redundant observations. In this paper a further objective method for the detection of groups of important and less important (and thus redundant) observations is developed. In addition, the parameters which are predominantly affected by these groups of observations are identified. This method thus complements other diagnostics tools, such as, e.g., multiple row diagnostics methods as described in statistical literature (see, e.g., Belsley et al. in Regression diagnostics: identifying influential data and sources of collinearity. Wiley, New York, 1980). The method proposed in this paper is based on geometric aspects of adjustment theory and uses the singular value decomposition of the design matrix of an adjustment problem together with cluster analysis methods for regression diagnostics. It can be applied to any geodetic adjustment problem and can be used for the detection of (groups of) observations that significantly affect the estimated parameters or that are of negligible impact. One of the advantages of the proposed method is the improvement of the reliability of observation plans and thus the reduction of the impact of individual observations (and outliers) on the estimated parameters. This is of particular importance for the very long baseline interferometry technique which serves as an application example of the regression diagnostics tool.     

On the topographic bias in geoid determination by the external gravity field

The topographic bias is defined as the error/bias committed by continuing the external gravity field inside the topographic masses by a harmonic function. We study the topographic bias given by a digital terrain model defined by a spherical template, and we show that the topographic bias is given only by the potential of an inner-zone cap, and it equals the bias of the Bouguer shell, independent of the size of the cap. Then we study the effect on the real Earth by decomposing its topography into a template, and we show also in this case that the topographic bias is that of the Bouguer shell, independent of the shape of the terrain. Finally, we show that the topographic potential of the terrain at the geoid can be determined to any precision by a Taylor expansion outside the Earth’s surface. The last statement is demonstrated by a Taylor expansion to fourth order.     

Seasonal variation of carbon fluxes in a sparse savanna in semi arid Sudan

Background

Large spatial, seasonal and annual variability of major drivers of the carbon cycle (precipitation, temperature, fire regime and nutrient availability) are common in the Sahel region. This causes large variability in net ecosystem exchange and in vegetation productivity, the subsistence basis for a major part of the rural population in Sahel. This study compares the 2005 dry and wet season fluxes of CO₂ for a grass land/sparse savanna site in semi arid Sudan and relates these fluxes to water availability and incoming photosynthetic photon flux density (PPFD). Data from this site could complement the current sparse observation network in Africa, a continent where climatic change could significantly impact the future and which constitute a weak link in our understanding of the global carbon cycle.

Results

The dry season (represented by Julian day 35–46, February 2005) was characterized by low soil moisture availability, low evapotranspiration and a high vapor pressure deficit. The mean daily NEE (net ecosystem exchange, Eq. 1) was -14.7 mmol d^-1 for the 12 day period (negative numbers denote sinks, i.e. flux from the atmosphere to the biosphere). The water use efficiency (WUE) was 1.6 mmol CO₂ mol H₂O^-1 and the light use efficiency (LUE) was 0.95 mmol CO₂ mol PPFD^-1. Photosynthesis is a weak, but linear function of PPFD. The wet season (represented by Julian day 266–273, September 2005) was, compared to the dry season, characterized by slightly higher soil moisture availability, higher evapotranspiration and a slightly lower vapor pressure deficit. The mean daily NEE was -152 mmol d^-1 for the 8 day period. The WUE was lower, 0.97 mmol CO₂ mol H₂O^-1 and the LUE was higher, 7.2 μmol CO₂ mmol PPFD^-1 during the wet season compared to the dry season. During the wet season photosynthesis increases with PPFD to about 1600 μmol m^-2s^-1 and then levels off.

Conclusion

Based on data collected during two short periods, the studied ecosystem was a sink of carbon both during the dry and wet season 2005. The small sink during the dry season is surprising and similar dry season sinks have not to our knowledge been reported from other similar savanna ecosystems and could have potential management implications for agroforestry. A strong response of NEE versus small changes in plant available soil water content was found. Collection and analysis of flux data for several consecutive years including variations in precipitation, available soil moisture and labile soil carbon are needed for understanding the year to year variation of the carbon budget of this grass land/sparse savanna site in semi arid Sudan.