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331.
Luis O'Dogherty Agustín Martín-Algarra Hans-Jürgen Gursky Roque Aguado 《International Journal of Earth Sciences》2001,90(4):831-846
Middle Jurassic radiolarites and associated pelagic limestones occur in the Rondaide Nieves unit of the Betic Cordillera, southern Spain. The Rondaide Mesozoic includes: (a) a thick succession of Triassic platform carbonates, comparable to the Alpine Hauptdolomit and Kössen facies; (b) Lower Jurassic pelagic limestones comparable to the Alpine Hierlatz and Adnet facies; (c) the Middle Jurassic Parauta Radiolarite Formation, described herein; and (d) a thin Upper Jurassic-Cretaceous condensed limestone succession. The Parauta Radiolarite Formation and associated limestones were studied with respect to stratigraphy, petrography, micropalaeontology (radiolarians, calcareous nanno- and microfossils) and facies. Radiolarite sedimentation occurred in the Middle Bathonian in a restricted and dysoxic deep Nieves basin, perched in the distal zone of a continental margin fringing the Tethyan ocean. This margin was adjacent to a young narrow oceanic basin between the South-Iberian margin and a continental block called Mesomediterranean Terrane. The Nieves basin was part of a marine corridor between the Proto-Atlantic and Piedmont-Ligurian basins of the Alpine Tethys. The regional tectonic position, the stratigraphical evolution since the Triassic, the age and the nature of the Mesozoic facies and the palaeogeographic relations to adjacent domains show striking analogies between the Betic Rondaide margin and coeval units of the Alps. 相似文献
332.
The incorporation of hydrogen (deuterium) into the coesite structure was investigated at pressures from 3.1 to 7.5 GPa and
temperatures of 700, 800, and 1100 °C. Hydrogen could only be incorporated into the coesite structure at pressures greater
5.0 GPa and 1100 °C . No correlation between the concentration of trace elements such as Al and B and the hydrogen content
was observed based on ion probe analysis (1335 ± 16 H ppm and 17 ± 1 Al ppm at 7.5 GPa, 1100 °C). The FTIR spectra show three
relatively intense bands at 3575, 3516, and 3459 cm−1 (ν1 to ν3, respectively) and two very weak bands at 3296 and 3210 cm−1 (ν4 and ν5, respectively). The band at 3516 cm−1 is strongly asymmetric and can be resolved into two bands, 3528 (ν2a) and 3508 (ν2b) cm−1, with nearly identical areas. Polarized infrared absorption spectra of coesite single-crystal slabs, cut parallel to (0 1
0) and (1 0 0), were collected to locate the OH dipoles in the structure and to calibrate the IR spectroscopy for quantitative
analysis of OH in coesite (ɛ
i
,tot=190 000 ± 30 000 l mol−1
H2O cm−2). The polarized spectra revealed a strong pleochroism of the OH bands. High-pressure FTIR spectra at pressures up to 8 GPa
were performed in a diamond-anvil cell to gain further insight into incorporation mechanism of OH in coesite. The peak positions
of the ν1, ν2, and ν3 bands decrease linearly with pressure. The mode Grüneisen parameters for ν1, ν2, and ν3 are −0.074, −0.144 and −0.398, respectively. There is a linear increase of the pressure derivatives with band position which
follows the trend proposed by Hofmeister et al. (1999). The full widths at half maximum (FWHM) of the ν1, ν2, and ν3 bands increase from 35, 21, and 28 cm−1 in the spectra at ambient conditions to 71, 68, and 105 in the 8 GPa spectra, respectively. On the basis of these results,
a model for the incorporation of hydrogen in coesite was developed: the OH defects are introduced into the structure by the
substitution Si4+(Si2)+4O2−= [4]□(Si2) + 4OH−, which gives rise to four vibrations, ν1, ν2a, ν2b, and ν3. Because the OH(D)-bearing samples do contain traces of Al and B, the bands ν4 and ν5 may be coupled to Al and/or B substitution.
Received: 19 December 2000 / Accepted: 23 April 2001 相似文献
333.
An experimental study of the effect of iron on magnesiochloritoid-talc-clinochlore-kyanite stability
The influence of Fe on the reaction clinochlore+kyanite&ding3F;magnesiochloritoid+talc (1) was determined experimentally as a function of pressure (1.6-2.6 GPa) and composition at 600 and 540 °C. Analytical electron microscopy (AEM) was used to determine the compositions of the coexisting phases in these complex multiphase run products. Within the compositional range studied (xFebulk=0.12-0.34), chlorite solid solutions were always richer in magnesium than the coexisting chloritoid solid solutions. Fractionation of Fe into the chloritoid extends the stability field of the assemblage chloritoid plus talc towards lower pressures. However, the extent of the stability field for increasing xFe is less than one would expect for ideal mixing behaviour in chloritoid and chlorite, and indicates a moderate positive deviation from ideality for chloritoid solid solutions. The thermodynamic data for magnesiochloritoid given in two earlier studies are in good agreement with the present experiments, those of a third study yield pressures which are much too high, at least compared with the experiments at 600 °C. 相似文献
334.
335.
A coordinated ground-based observational campaign using the IMAGE magnetometer network, EISCAT radars and optical instruments on Svalbard has made possible detailed studies of a travelling convection vortices (TCV) event on 6 January 1992. Combining the data from these facilities allows us to draw a very detailed picture of the features and dynamics of this TCV event. On the way from the noon to the drawn meridian, the vortices went through a remarkable development. The propagation velocity in the ionosphere increased from 2.5 to 7.4 km s−1, and the orientation of the major axes of the vortices rotated from being almost parallel to the magnetic meridian near noon to essentially perpendicular at dawn. By combining electric fields obtained by EISCAT and ionospheric currents deduced from magnetic field recordings, conductivities associated with the vortices could be estimated. Contrary to expectations we found higher conductivities below the downward field aligned current (FAC) filament than below the upward directed. Unexpected results also emerged from the optical observations. For most of the time there were no discrete aurora at 557.7 nm associated with the TCVs. Only once did a discrete form appear at the foot of the upward FAC. This aurora subsequently expanded eastward and westward leaving its centre at the same longitude while the TCV continued to travel westward. Also we try to identify the source regions of TCVs in the magnetosphere and discuss possible generation mechanisms. 相似文献
336.
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339.
Seismic anisotropy beneath Southern Tibet 总被引:2,自引:0,他引:2
SeismicanisotropybeneathSouthernTibetQING-TIANLUI(吕庆田),KAI-YIMA(马开义),MEIJIANG'(姜枚),A.HirnandA.Nercessian(InstituteofMineralDe... 相似文献
340.