Tellurides from Sunrise Dam gold deposit, Yilgarn Craton, Western Australia: a new occurrence of nagyágite

Summary The Cu–Fe–Au–Mo (W) deposits in southeastern Hubei are an important component of the Middle–Lower Yangtze River metallogenic belt. Molybdenite from the Fengshandong Cu- (Mo), Ruanjiawan W–Cu- (Mo), Qianjiawan Cu–Au, Tongshankou Cu–Mo and Tonglüshan Cu- (Fe) deposits yielded Re–Os ages of 144.0 ± 2.1 Ma, 143.6 ± 1.7 Ma, 137.7 ± 1.7 Ma, 142.3 ± 1.8–143.7 ± 1.8 Ma and 137.8 ± 1.7–138.1 ± 1.8 Ma, respectively. Phlogopite from the Tieshan Fe- (Cu) deposit yielded an Ar–Ar age of 140.9 ± 1.2 Ma. These data and other published isotopic ages (Re–Os molybdenite and Ar–Ar mica ages) for the Cu–Fe–Au–Mo (W) deposits in the Middle–Lower Yangtze River metallogenic belt show that Cu–Fe–Au–Mo (W) mineralisation in the Tongling, Anqing, Jiurui and Edong ore districts developed in a narrow time span between 135.5 and 144.9 Ma, reflecting an important regional metallogenic event. An integrated study of available petrological and geochronological data, together with relationships to magmatism and the regional geodynamic framework, indicate that the Cu–Fe–Au–Mo (W) mineralisation in the Middle–Lower Yangtze River belt occurred during a regime of lithospheric extension. This extension is probably related to Late Mesozoic processes of lower crustal delamination and lithospheric thinning in East China.     

Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

The role of sedimentation rate and permeability in the slope stability of the formerly glaciated Norwegian continental margin: the Storegga slide model

Despite the gently dipping slopes (ca 1°), large-scale submarine slope failures have occurred on the mid-Norwegian continental margin (Storegga, Sklinnadjupet, Traenadjupet), suggesting the presence of special conditions predisposing to failure in this formerly glaciated margin. With a volume estimated between 2,400 and 3,200 km³ and an affected area of approximately 95,000 km², the Storegga slide represents one of the largest and best-studied submarine slides of Holocene age known worldwide. Finite element modeling of slope failure indicates that a large (6.5 < Ms < 7.0) seismic triggering mechanism would not be sufficient to cause failure at more than 110 m below the seabed as observed for the slip planes at Storegga (northern sidewall). This implies that other factors (e.g., liquefaction, strain softening, gas charging, rapid burial) are needed to explain the occurrence of the Storegga slide with a deep surface of failure. In this paper, we discuss the importance of the compaction effect of rapidly accumulated sediments in the slide area. During compaction, sediment grains reorganize themselves, thereby, expelling pore water. Consequently, depending on sedimentation rate and permeability, excess pore pressures might result beneath less permeable sediments. Our modeling and cross-checking illustrate how excess pore pressure generation due to high sedimentation rate could explain the development of layers of weakness, and thus, how such a large slide might have been initiated in deep sediments. Using the highest sedimentation rate estimated in the area (36 and 27 m/kyr between 16.2 and 15 kyr BP), 1D modeling shows excess pore pressure values of around 200 kPa at a depth of 100 m below the seafloor 15 kyr BP and 60 kPa at a depth of 100 m at the time of the slide (8 kyr BP). Excess pore pressure apparently drastically reduced the resistance of the sediment (incomplete consolidation). In addition, 2D modeling shows that permeability anisotropies can significantly affect the lateral extent of excess pore pressure dissipation, affecting, that way, normally consolidated sediments far from the excess pore pressure initiation area.     

<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.     

Slowness-backazimuth weighted migration: A new array approach to a high-resolution image

We have developed a new array method combining conventional migration with a slowness-backazimuth deviation weighting scheme. All seismic traces are shifted based on the theoretical traveltime of the scattered wave from specific gridpoints in a 3-D volume. Observed slowness and backazimuth are calculated for each raypath and compared with theoretical values in order to estimate slowness and backazimuth deviations. Subsequently, stacked energy calculated by a conventional migration method is weighted by the slowness and backazimuth deviations to suppress any arrival energy whose slowness and backazimuth are inconsistent with the expected theoretical values. This new method was applied to two P- wave data sets which comprise (1) underside reflections at the 410 and 660 km mantle discontinuities and (2) D" reflections as well as their corresponding synthetic data sets. The results show that the weighting scheme dramatically increases the resolution of the migrated images and enables us to obtain well-constrained, focused images, making upper-mantle discontinuities and D" reflections more distinct by reducing their surrounding energy.     

New insights into the P- and S-wave velocity structure of the D" discontinuity beneath the Cocos plate

Broad-band P - and S -waves from earthquakes in South America recorded at Californian network stations are analysed to image lateral variations of the D"-discontinuity beneath the Cocos plate. We apply two array processing methods to the data set: a simplified migration method to the P -wave data set and a double-array method to both the P - and S -wave data sets, allowing us to compare results from the two methods. The double-array method images a dipping reflector at a depth range from 2650 to 2700 km in the southern part of the study area. We observe a step-like topography of 100 km to a shallower reflector at about 2600 km depth to the north, as well as evidence for a second (deeper) reflector at a depth range from 2700 to 2750 km in the north. Results from the simplified migration agree well with those from the double-array method, similarly locating a large step in reflector depth in a similar location (about 2650 km depth in the south and about 2550 km in the north) as well as the additional deeper reflector at the depth of about 2750 km in the north. Waveform modelling of the reflected waves from both methods suggests a positive velocity contrast for S waves, but a negative velocity contrast for P waves for the upper reflector in agreement with predictions from mineral physical calculations for a post-perovskite phase transition. The data also show some evidence for the existence of another deeper reflector that could indicate a double intersection of the geotherm with the post-perovskite stability field, that is, the back-transformation of post-perovskite to perovskite close to the core–mantle boundary.     

Evolution of vegetation and climate since the last glacial maximum recorded at Dahu peat site, South China

Sporopollen analysis on a 346 cm peat record at Dahu, Jiangxi, chronologically constrained by 16 AMS 14C datings, provides an opportunity to reconstruct the vegetation evolution stages responding to cli-mate change in South China since the last glacial maximum. The result shows that during 18330-15630 cal a B.P., broad-leaved forest dominated the area, corresponding to mild, cool and fairly humid climate. At the interval of 15630-11600 cal a B.P., several evergreen broad-leaved species appeared within the broad-leaved forest, indicating moderate and humid condition. During early Holocene, broad-leaved evergreen forest community was constructed as Castanopsis/Lithorcarpus principally developed, suggesting a warm and humid scenario until 6000 cal a B. P. Since 6000 cal a B. P., abrupt forest deterioration happened with an contemporary increase of fern and herb communities, repre-senting a turnover to relatively cool and dry condition and as well, possible impact from human activi-ties. Meanwhile, several relatively cool and dry events can be identified in the sporopollen record, they can be correlated to the North Atlantic Heinrich event, YD and Holocene millennial-scale oscillations, implying that the low latitude climate was coupled with high latitude influences. Moreover, the varia-tions of temperature and humidity since LGM at Dahu were much smaller when compared with the re-cords in north monsoonal China.