Mineralogy and geochemistry of alluvium contaminated by metal mining in the Rio Tinto area, southwest Spain

The Rio Tinto in SW Spain drains Cu and pyrite mines which have been in operation since at least the Bronze Age. Extensive metal mining, especially from 1873 to 1954, has resulted in contamination of the Rio Tinto alluvium with As, Cu, Pb, Ag and Zn. X-ray diffraction (XRD), wavelength-dispersive X-ray mapping, scanning electron microscope petrography and X-ray energy-dispersive (EDX) analysis has revealed that 4 major groups of contaminant metal and As-bearing minerals, including sulphides, Fe-As oxides, Fe oxides/hydroxides/oxyhydroxides, and Fe oxyhydroxysulphates, occur in the alluvium. Sulphide minerals, including pyrite, chalcopyrite, arsenopyrite and sphalerite, occur in alluvium near the mining areas. Iron hydroxides and oxyhydroxides such as goethite and possibly ferrihydrite occur in cements in both the mining areas and alluvium downstream, and carry minor amounts of As, Cu and Zn. Iron oxyhydroxysulphates, including jarosite, plumbojarosite and possibly schwertmannite, are the most common minerals in alluvium downstream of the mining areas, and are major hosts of Cu, Pb, Zn and of As, next to the Fe-As minerals. This work, and other field observations, suggest that (1) the extreme acidity and elevated metal concentrations of the river water will probably be maintained for some time due to oxidation of pyrite and other sulphides in the alluvium and mine-waste tips, and from formation of secondary oxide and oxyhydroxysulphates; (2) soluble Fe oxyhydroxysulphates such as copiapite, which form on the alluvium, are a temporary store of contaminant metals, but are dissolved during periods of high rainfall or flooding, releasing contaminants to the aqueous system; (3) relatively insoluble Fe oxyhydroxysulphates and hydroxides such as jarosite and goethite may be the major long-term store of alluvial contaminant metals; and (4) raising river pH will probably cause precipitation of Fe oxyhydroxides and oxides/hydroxides/oxyhydroxides and thus have a positive effect on water quality, but this action may destabilise some of these contaminant metal-bearing minerals, releasing metals back to the aqueous system.     

Mapping biomass with remote sensing: a comparison of methods for the case study of Uganda

Background  

Assessing biomass is gaining increasing interest mainly for bioenergy, climate change research and mitigation activities, such as reducing emissions from deforestation and forest degradation and the role of conservation, sustainable management of forests and enhancement of forest carbon stocks in developing countries (REDD+). In response to these needs, a number of biomass/carbon maps have been recently produced using different approaches but the lack of comparable reference data limits their proper validation. The objectives of this study are to compare the available maps for Uganda and to understand the sources of variability in the estimation. Uganda was chosen as a case-study because it presents a reliable national biomass reference dataset.     

Dynamical evolution of NEAs: Close encounters, secular perturbations and resonances

We discuss the main mechanisms affecting the dynamical evolution of Near-Earth Asteroids (NEAs) by analyzing the results of three numerical integrations over 1 Myr of the NEA (4179) Toutatis. In the first integration the only perturbing planet is the Earth. So the evolution is dominated by close encounters and looks like a random walk in semimajor axis and a correlated random walk in eccentricity, keeping almost constant the perihelion distance and the Tisserand invariant. In the second integration Jupiter and Saturn are present instead of the Earth, and the 3/1 (mean motion) and v ₆ (secular) resonances substantially change the eccentricity but not the semimajor axis. The third, most realistic, integration including all the three planets together shows a complex interplay of effects, with close encounters switching the orbit between different resonant states and no approximate conservation of the Tisserand invariant. This shows that simplified 3-body or 4-body models cannot be used to predict the typical evolution patterns and time scales of NEAs, and in particular that resonances provide some “fast-track” dynamical routes from low-eccentricity to very eccentric, planet-crossing orbits.     

Hydrological impacts of climate change predicted for an inland lake catchment in Ontario by using monthly water balance analyses

Potential hydrological impacts of climate change on long‐term water balances were analysed for Harp Lake and its catchment. Harp Lake is located in the boreal ecozone of Ontario, Canada. Two climate change scenarios were used. One was based on extrapolation of long‐term trends of monthly temperature and precipitation from a 129‐year data record, and another was based on a Canadian general circulation model (GCM) predictions. A monthly water balance model was calibrated using 26 years of hydrological and meteorological data, and the model was used to calculate hydrological impact under two climate change scenarios. The first scenario with a warmer and wetter climate predicted a smaller magnitude of change than the second scenario. The first scenario showed an increase in evaporation each month, an increase in catchment runoff in summer, fall and winter, but a decrease in spring, resulting in a slight increase in lake level. Annual runoff and lake level would increase because the precipitation change overrides evaporation change. The second scenario with a warmer, drier climate predicted a greater change, and indicated that evaporation would increase each month, runoff would increase in many months, but would decrease in spring, causing the lake level to decrease slightly. Annual runoff and lake level would decrease because evaporation change overrides precipitation change. In both scenarios, the water balance changes in winter and spring are pronounced. Copyright © 2009 John Wiley & Sons, Ltd.     

Searching for the Parent of the Tunguska Cosmic Body

We present the results of an extensive study of the Tunguska Cosmic Body (TCB) origin on dynamical grounds. To identify the TCB parent, or a plausible candidate, we applied the well-known concept of dynamical similarity whereby we have compared the geocentric and heliocentric dynamical parameters of a selected set of the Near Earth Objects (NEOs) and TCB particles. First, we made use the idea of Kresak by comparing geocentric coordinates of the TCB radiant with those of the NEOs. Second, we studied the long-term dynamical evolution of all NEOs and TCB particles searching for similarities between their heliocentric orbits. As a general result, we observed many more similar cases and a different pattern of the high orbital similarity among the TCB particles and the asteroid orbits than we did for comets.     

Injection of Oort Cloud comets: the fundamental role of stellar perturbations

We present Monte Carlo simulations of the dynamical evolution of the Oort cloud over the age of the Solar System, using an initial sample of one million test comets without any cloning. Our model includes perturbations due to the Galactic tide (radial and vertical) and passing stars. We present the first detailed analysis of the injection mechanism into observable orbits by comparing the complete model with separate models for tidal and stellar perturbations alone. We find that a fundamental role for injecting comets from the region outside the loss cone (perihelion distance q > 15 AU) into observable orbits (q < 5 AU) is played by stellar perturbations. These act in synergy with the tide such that the total injection rate is significantly larger than the sum of the two separate rates. This synergy is as important during comet showers as during quiescent periods and concerns comets with both small and large semi-major axes. We propose different dynamical mechanisms to explain the synergies in the inner and outer parts of the Oort Cloud. We find that the filling of the observable part of the loss cone under normal conditions in the present-day Solar System rises from <1% for a < 20 000 AU to about 100% for a ? 100 000 AU.     

Texture‐based image segmentation applied to the quantification of superficial sand in salmonid river gravels

The presence of ?ne sediment in river gravels is widely recognized as being detrimental to salmonid habitat quality. In order to facilitate quanti?cation of sand presence at larger scales, this paper presents an application of image processing allowing for rapid and accurate assessments of super?cial sand presence in dry exposed ?uvial gravels. Images for the process are acquired with a 35 mm SLR ?lm camera and then scanned with a desktop scanner. Texture‐based segmentation is then applied to differentiate between sand and clast areas. Results show that the method is accurate and therefore it offers an alternative to bulk sampling in cases where rapid assessments of sand presence are required. Copyright © 2005 John Wiley & Sons, Ltd.     

Behaviour of Li and its isotopes during metasomatism of French Massif Central lherzolites

Li behaviour and distribution in the mantle were investigated by ion microprobe in situ measurements on co-existing olivine (ol), orthopyroxene (opx), clinopyroxene (cpx) and amphibole (amp) in xenoliths from the French Massif Central. The fertile spinel lherzolites of this study record increasing degrees of mantle metasomatism, from unmetasomatised anhydrous samples through cryptically metasomatised samples to highly metasomatised amphibole-rich samples. In anhydrous lherzolites, Li is preferentially incorporated into olivine (1.1-1.4 ppm, average values) compared to pyroxenes (0.2-0.9 ppm). The hydrous samples clearly show enrichment of Li in ol (1.5-5.0 ppm), opx (1.1-2.4 ppm) and cpx (2.4-5.4 ppm), while amphibole incorporates less Li than the co-existing phases (0.8-1.3 ppm). Average δ⁷Li values range from +7.6 to +14.5‰ in ol, from 5.1 to +13.7‰ in opx and from 8.8 to +10.3‰ in cpx from the anhydrous lherzolites. A layered peridotite sample (Sdi) shows higher Li content in all phases, with lighter isotopic composition in opx and cpx (−0.6 and −2‰ average δ⁷Li values, respectively). In the hydrous lherzolites average δ⁷Li values both overlap and extend beyond these ranges in ol (up to 17.5 ‰) and in opx (up to 22.9‰), and vary widely in cpx (−2.7 to +9.7‰). Low δ⁷Li values are observed in some opx (−10.4‰) and cpx (−13‰) from sample Sdi, and in cpx from three hydrous samples (from −9.7 to −5.3‰). The different anhydrous phases from the hydrous samples show large intra-grain variations in Li isotopic ratios (e.g., up to 18‰) compared to the same phases from the anhydrous samples (mostly less than 6‰), excepting sample Sdi which has up to 20.4‰ variation in cpx. Similar to the anhydrous silicates, amphiboles show a wide variation of δ⁷Li values on the intra-grain scale (2-27‰). These variations are interpreted to result from fractionation processes during metasomatism by a silicate melt undergoing compositional changes as it percolates through and reacts with the peridotite phases. Thus Li abundances and isotopic in situ measurements are useful for tracing metasomatic processes but the heterogeneities observed in the samples preclude any identification of a specific mantle source by its Li signature.     

Hydraulic geometry and changes in flow velocity at a river confluence with coarse bed material

A survey of flows was conducted at a river confluence with coarse bed material. Bridges were installed on both tributaries, at the confluence and farther downstream on the receiving stream. At these stations, flow velocities were measured over a dense grid for seven conditions ranging from very low flows to the bankfull stage. Hydraulic geometry relationships established at all four stations revealed that flow is accelerated through the confluence as stage rises. At bankfull discharge, average velocity is 1.6 times higher at the confluence than on either tributary. Flow acceleration occurs at and above intermediate flow stages and is concentrated at the centre of a linear pool located at the confluence. The development of a zone of high shear stress is also associated with the cell of high flow velocity. Flow acceleration is dissipated at the exit of the pool where water surges over boulder ribs. The acceleration is not related to the development of flow separation zones as observed by Best and Reid (1984) for wide junction angles, nor is it explained by the reduction of the friction exerted by the banks. Acceleration is associated with the plan geometry of the confluence, with the lateral slopes which permit water to converge, and with a reduction in grain roughness at the confluence. Owing to the curvature of the tributary and to the acute angle of entry, relative power losses through the confluence decrease with increasing stages.