Visual characterization technique for gravel‐cobble river bed surface sediments; validation and environmental applications Contribution to the programme of CIRSA (Centre Interuniversitaire de Recherche sur le Saumon Atlantique)

This paper presents an evaluation of the feasibility and the reliability of a visual characterization technique for gravel–cobble river bed surface substrate. Based on principal axis regressions, using phi scale (ϕ), comparisons of visual estimation and grid sampling techniques show that useful predictive relations (R² = 0·78–0·88) exist between visual estimates of the surface d₁₆, d₅₀ and d₈₄ and estimates obtained for the same percentiles with the grid sampling technique. Comparisons of visual estimation and the surface‐bulk sampling technique also indicate a predictive relation (R² = 0·70) between the d₅₀ of the two methods. Trained operators can visually estimate gravel–cobble bed surface d₁₆ to uncertainties of 41 per cent, d₅₀ to 15 per cent and d₈₄ to 11 per cent (for example, there is a 5·5 mm error on a d₈₄ size of 50 mm). Furthermore, evidence shows that if operators are properly trained, a calibration relation for each percentile can be applied independently of operators. This visual characterization allows effective detailed mapping of spatial patterns in substrate size distribution along extensive reaches of gravel‐bed rivers. The technique can be very useful in creating terrain models for various geomorphological, hydrological and biological applications such as the determination of entrainment thresholds, hydraulic roughness and substrate suitability for benthic insects or salmonid habitat. Copyright © 2001 John Wiley & Sons, Ltd.     

Genetic differentiation of populations of Greenlandic Arctic fox

Most microsatellites are very polymorphic. This makes them powerful markers for observing genetic differentiation between closely related populations. The population structure of the Greenlandic Arctic fox ( Alopex lagopus ) was studied genetically by analysing six polymorphic microsatellite loci of 75 foxes from four populations in different parts of Greenland. Genotypes were determined at the six loci for most of the individuals. Population differentiation was quantified in three different ways both within the total population and pairwise between all populations. The tests were Fisher's exact test, Rho estimates and Fst estimates, all of which supported a highly significant subdivision of the total population, and they showed significant differentiation in allele frequencies between all pairs of localities. It is concluded that the known long-distance migration of the Greenlandic Arctic fox has not resulted in complete genetic mixing of the populations. Fisher's exact test was also used to estimate levels of genetic differentiation between the two colour morphs: white and blue. No difference was found between allele frequencies of the two color morphs in any of the locations, and it was concluded that the white and blue morphs of the Greenlandic Arctic fox share the same habitat, at least during the mating season.     

Ocean/ice shelf interaction in the southern Weddell Sea: results of a regional numerical helium/neon simulation

Ocean/ice interaction at the base of deep-drafted Antarctic ice shelves modifies the physical properties of inflowing shelf waters to become Ice Shelf Water (ISW). In contrast to the conditions at the atmosphere/ocean interface, the increased hydrostatic pressure at the glacial base causes gases embedded in the ice to dissolve completely after being released by melting. Helium and neon, with an extremely low solubility, are saturated in glacial meltwater by more than 1000%. At the continental slope in front of the large Antarctic caverns, ISW mixes with ambient waters to form different precursors of Antarctic Bottom Water. A regional ocean circulation model, which uses an explicit formulation of the ocean/ice shelf interaction to describe for the first time the input of noble gases to the Southern Ocean, is presented. The results reveal a long-term variability of the basal mass loss solely controlled by the interaction between waters of the continental shelf and the ice shelf cavern. Modeled helium and neon supersaturations from the Filchner–Ronne Ice Shelf front show a “low-pass” filtering of the inflowing signal due to cavern processes. On circumpolar scales, the simulated helium and neon distributions allow us to quantify the ISW contribution to bottom water, which spreads with the coastal current connecting the major formation sites in Ross and Weddell Seas.

Distributed discharge and sediment concentration predictions in the sub‐humid Ethiopian highlands: the Debre Mawi watershed

Experimental research in the Ethiopian highlands found that saturation excess induced runoff and erosion are common in the sub‐humid conditions. Because most erosion simulation models applied in the highlands are based on infiltration excess, we, as an alternative, developed the Parameter Efficient Distributed (PED) model, which can simulate water and sediment fluxes in landscapes with saturation excess runoff. The PED model has previously only been tested at the outlet of a watershed and not for distributed runoff and sediment concentration within the watershed. In this study, we compare the distributed storm runoff and sediment concentration of the PED model against collected data in the 95‐ha Debre Mawi watershed and three of its nested sub‐watersheds for the 2010 and 2011 rainy seasons. In the PED model framework, the hydrology of the watershed is divided between infiltrating and runoff zones, with erosion only taking place from two surface runoff zones. Daily storm runoff and sediment concentration values, ranging from 0.5 to over 30 mm and from 0.1 to 35 g l^?1, respectively, were well simulated. The Nash Sutcliffe efficiency values for the daily storm runoff for outlet and sub‐watersheds ranged from 0.66 to 0.82, and the Nash–Sutcliffe efficiency for daily sediment concentrations were greater than 0.78. Furthermore, the model uses realistic fractional areas for surface and subsurface flow contributions, for example between saturated areas (15%), degraded areas (30%) and permeable areas (55%) at the main outlet, while close similarity was found for the remaining hydrology and erosion parameter values. One exception occurred for the distinctly greater transport limited parameter at the actively gullying lower part of the watershed. The results suggest that the model based on saturation excess provides a good representation of the observed spatially distributed runoff and sediment concentrations within a watershed by modelling the bottom lands (as opposed to the uplands) as the dominant contributor of the runoff and sediment load. Copyright © 2014 John Wiley & Sons, Ltd.     

Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens

X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [Fe^II₄Fe^III₂(OH)₁₂CO₃: GR1(CO₃)], which completely converted into ferrous-carbonate hydroxide (Fe^II₂(OH)₂CO₃: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO₃) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO₃) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO₃) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)₂ phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)₂ nanoparticles as oligomers binding to the edges of Fe(OH)₆ octahedra at the edges of the octahedral layers of Fe(OH)₂. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.     

Loading and fate of particulate organic carbon from the Himalaya to the Ganga-Brahmaputra delta

We use the evolution of river sediment characteristics and sedimentary C_org from the Himalayan range to the delta to study the transport of C_org in the Ganga-Brahmaputra system and especially its fate during floodplain transit.A detailed characterisation of both mineral and organic particles for a sampling set of river sediments allows taking into account the sediment heterogeneity characteristic of such large rivers. We study the relationships between sediment characteristics (mineralogy, grain size, specific area) and C_org content in order to evaluate the controls on C_org loading. Contributions of C3 and C4 plants are estimated from C_org stable isotopic composition (δ¹³C_org). We use the evolution of δ¹³C_org values from the Himalayan range to the delta in order to study the fate of C_org during floodplain transit.Ganga and Brahmaputra sediments define two distinct linear relations with specific area. In spite of 4-5 times higher specific area, Ganga sediments have similar C_org content, grain size and mineralogy as Brahmaputra sediments, indicating that specific area does not exert a primary control on C_org loading. The general correlation between the total C_org content and Al/Si ratio indicates that C_org loading is mainly related to: (1) segregation of organic particles under hydrodynamic forces in the river, and (2) the ability of mineral particles to form organo-mineral aggregates.Bed and suspended sediments have distinct δ¹³C_org values. In bed sediments, δ¹³C_org values are compatible with a dominant proportion of fossil C_org derived from Himalayan rocks erosion. Suspended sediments from Himalayan tributaries at the outflow of the range have low δ¹³C_org values (−24.8‰ average) indicating a dominant proportion of C3 plant inputs. In the Brahmaputra basin, δ¹³C_org values of suspended sediments are constant along the river course in the plain. On the contrary, suspended sediments of the Ganga in Bangladesh have higher δ¹³C_org values (−22.4‰ to −20.0‰), consistent with a significant contribution of C4 plant derived from the floodplain. Our data indicate that, during the plain transit, more than 50% of the recent biogenic C_org coming from the Himalaya is oxidised and replaced by floodplain C_org. This renewal process likely occurs during successive deposition-erosion cycles and river course avulsions in the plain.     

The particle background of the <Emphasis Type="Italic">X-IFU</Emphasis> instrument

In this paper we are going to review the latest estimates for the particle background expected on the X-IFU instrument onboard of the ATHENA mission. The particle background is induced by two different particle populations: the so called “soft protons” and the Cosmic rays. The first component is composed of low energy particles (< 100s keV) that get funnelled by the mirrors towards the focal plane, losing part of their energy inside the filters and inducing background counts inside the instrument sensitivity band. The latter component is induced by high energy particles (> 100 MeV) that possess enough energy to cross the spacecraft and reach the detector from any direction, depositing a small fraction of their energy inside the instrument. Both these components are estimated using Monte Carlo simulations and the latest results are presented here.     

Clastic matrix in EH3 chondrites

Abstract— Patches of clastic matrix (15 to 730 μm in size) constitute 4.9 vol% of EH3 Yamato (Y‐) 691 and 11.7 vol% of EH3 Allan Hills (ALH) 81189. Individual patches in Y‐691 consist of 1) ?25 vol% relatively coarse opaque grain fragments and polycrystalline assemblages of kamacite, schreibersite, perryite, troilite (some grains with daubréelite exsolution lamellae), niningerite, oldhamite, and caswellsilverite; 2) ?30 vol% relatively coarse silicate grains including enstatite, albitic plagioclase, silica and diopside; and 3) an inferred fine nebular component (?45 vol%) comprised of submicrometer‐size grains. Clastic matrix patches in ALH 81189 contain relatively coarse grains of opaques (?20 vol%; kamacite, schreibersite, perryite and troilite) and silicates (?30 vol%; enstatite, silica and forsterite) as well as an inferred fine nebular component (?50 vol%). The O‐isotopic composition of clastic matrix in Y‐691 is indistinguishable from that of olivine and pyroxene grains in adjacent chondrules; both sets of objects lie on the terrestrial mass‐fractionation line on the standard three‐isotope graph. Some patches of fine‐grained matrix in Y‐691 have distinguishable bulk concentrations of Na and K, inferred to be inherited from the solar nebula. Some patches in ALH 81189 differ in their bulk concentrations of Ca, Cr, Mn, and Ni. The average compositions of matrix material in Y‐691 and ALH 81189 are similar but not identical‐matrix in ALH 81189 is much richer in Mn (0.23 ± 0.05 versus 0.07 ± 0.02 wt%) and appreciably richer in Ni (0.36 ± 0.10 versus 0.18 ± 0.05 wt%) than matrix in Y‐691. Each of the two whole‐rocks exhibits a petrofabric, probably produced by shock processes on their parent asteroid.