Behavior of diorite under impact by variously-shaped projectiles

SummaryBehavior of Diorite Under Impact by Variously-Shaped Projectiles The effects of striker diameter and tip geometry on the crater and crack network produced in diorite by normal projectile impact in the energy range from 4–30 J was investigated. Ejecta kinematics were determined by high-speed photography; elastic strain wave propagation was measured by embedded gages in a composite specimen; and the damage pattern was ascertained from an examination of the sectioned specimen. It was found that the projectile nose shape exerts a strong influence on the shape of the elastic transient, on the crater geometry, on the extent of the crack network and on the average size of the ejecta. The crater depth was found to be the most repeatable parameter in identical tests using the same striker and initial kinetic energy.With 7 Figures     

Carbon-13 exchange between CO2 and CH4 under geothermal conditions

On the basis of recently reported data on the kinetics of carbon-13 exchange between CO₂ and CH₄ at temperatures above 500°C, first order rate constants $\text{log k = 11.16?10,190/T}$ were derived allowing variations in Δ, the difference in the isotopic composition of coexisting CO₂ and CH₄, to be evaluated as a function of initial composition and cooling rate of the rising geothermal fluid. Observed Δ-values in geothermal discharges are likely to represent frozen in compositions attained after minimum residence times of 20 ka at 400°C or 10 Ma at 300°C. The carbon-13 contents of any biogenic gases are unlikely to have been affected by thermal re-equilibration at temperatures below 200°C. The chemical equilibrium involving CO₂ and CH₄ can be expected to proceed about a hundred times faster than isotopic equilibration.     

The legacy of crystal-plastic deformation in olivine: high-diffusivity pathways during serpentinization

Crystal-plastic olivine deformation to produce subgrain boundaries composed of edge dislocations is an inevitable consequence of asthenospheric mantle flow. Although crystal-plastic deformation and serpentinization are spatio-temporally decoupled, we identified compositional readjustments expressed on the micrometric level as a striped Fe-enriched ( [`(X)]<sub>\textFe</sub> \bar{X}_{\text{Fe}}  = 0.24 ± 0.02 (zones); 0.12 ± 0.02 (bulk)) or Fe-depleted ( [`(X)]_\textFe \bar{X}_{\text{Fe}}  = 0.10 ± 0.01 (zones); 0.13 ± 0.01 (bulk)) zoning in partly serpentinized olivine grains from two upper mantle sections in Norway. Focused ion beam sample preparation combined with transmission electron microscopy (TEM) and aberration-corrected scanning TEM, enabling atomic-level resolved electron energy-loss spectroscopic line profiling, reveals that every zone is immediately associated with a subgrain boundary. We infer that the zonings are a result of the environmental Fe²⁺Mg₋₁ exchange potential during antigorite serpentinization of olivine and the drive toward element exchange equilibrium. This is facilitated by enhanced solid-state diffusion along subgrain boundaries in a system, which otherwise re-equilibrates via dissolution-reprecipitation. Fe enrichment or depletion is controlled by the silica activity imposed on the system by the local olivine/orthopyroxene mass ratio, temperature and the effect of magnetite stability. The Fe-Mg exchange coefficients K_\textD^{\textAtg/\textOl} K_{\text{D}}^{{{\text{Atg}}/{\text{Ol}}}} between both types of zoning and antigorite display coalescence toward exchange equilibrium. With both types of zoning, Mn is enriched and Ni depleted compared with the unaffected bulk composition. Nanometer-sized, heterogeneously distributed antigorite precipitates along olivine subgrain boundaries suggest that water was able to ingress along them. Crystallographic orientation relationships gained via electron backscatter diffraction between olivine grain domains and different serpentine vein generations support the hypothesis that serpentinization was initiated along olivine subgrain boundaries.     

Determining the trophic guilds of fishes and macroinvertebrates in a seagrass food web

We established trophic guilds of macroinvertebrate and fish taxa using correspondence analysis and a hierarchical clustering strategy for a seagrass food web in winter in the northeastern Gulf of Mexico. To create the diet matrix, we characterized the trophic linkages of macroinvertebrate and fish taxa present inHalodule wrightii seagrass habitat areas within the St. Marks National Wildlife Refuge (Florida) using binary data, combining dietary links obtained from relevant literature for macroinvertebrates with stomach analysis of common fishes collected during January and February of 1994. Heirarchical average-linkage cluster analysis of the 73 taxa of fishes and macroinvertebrates in the diet matrix yielded 14 clusters with diet similarity ≥ 0.60. We then used correspondence analysis with three factors to jointly plot the coordinates of the consumers (identified by cluster membership) and of the 33 food sources. Correspondence analysis served as a visualization tool for assigning each taxon to one of eight trophic guilds: herbivores, detritivores, suspension feeders, omnivores, molluscivores, meiobenthos consumers, macrobenthos consumers and piscivores. These trophic groups, corss-classified with major taxonomic groups, were further used to develop consumer compartments in a network analysis model of carbon flow in this seagrass ecosystem. The method presented here should greatly improve the development of future network models of food webs by providing an objective procedure for aggregating trophic groups.     

Caractérisation des paragenèses et des paléocirculations fluides dans l'indice d'or de Bleı̈da (Anti-Atlas,Maroc)Characterization of the paragenesis and the fluid palaeo-circulations in the gold showings of Bleida (Anti-Atlas,Morocco)

The gold showings at Bleida are hosted in Late Pan-African N50–80 °E quartz–hematite–chlorite 1 tension lenses that are related to the activity of major sinistral sub-east–west thrusts. Ores result from three superimposed stages of fluid migration. Gold occurs in microcracks offsetting the earlier minerals. Fluids evolved from COHN compositions with a saline component to boiling aqueous fluids. Pressure and temperature decreased from 50 MPa and 300 °C to less than 4 MPa and 150 °C. Thus, the gold showings at Bleida were formed in a typical geothermal (epithermal) setting, likely controlled by the Late Pan-African magmatism. To cite this article: A. Barakat et al., C. R. Geoscience 334 (2002) 35–41     

Gaps in cubic closest packing: from MgO via spinel to the pharmacosiderite crystal structure type

Numerous ordered defect structures are known that are related to the sodium chloride (or MgO) structure type, thus they are basically cubic closest packed (ccp) arrangements with vacancies. For example the NbO type is an MgO type in which one quarter each of the anions and the cations are missing compared to the ccp in such a way that both anions and cations are in square-planar coordination. In spinel, Al₂MgO₄, one half of the octahedrally coordinated cations are missing compared with the MgO type and only one eighth of the tetrahedrally coordinated sites within the ccp are occupied. What these cases have in common is that all these derivatives are rather dense. This is different in pharmacosiderite, K[Fe₄(OH)₄As₃O₁₂]. 6 to 7H₂O, where one half of the anion positions, three quarters of the octahedral sites and five eighth of the tetrahedral sites remain vacant, compared to the spinel type. Pharmacosiderite is a wide open porous structure with zeolitic properties. We are illustrating these relationships using a Bärnighausen symmetry tree and by tables relating the various structure types to each other.     

Multiple ways of producing intermediate and silicic rocks within Thingmúli and other Icelandic volcanoes

Major and trace element compositions of rocks and coexisting phenocrysts of the Thingmúli volcano suggest a revision of the existing models for the formation of intermediate and silicic melts in Iceland. The new data define two compositional tholeiitic trends with a significant gap between them. A high-iron trend (HFe) contains 6–14 wt% total FeO in silicic rocks with c. 1 wt% MgO, as well as sodic plagioclase and hedenbergite phenocrysts. A low-iron trend (LFe) contains 3–5 wt% FeO at c. 1 wt% MgO, which is typical of Iceland but higher than MORB compositions. The most evolved phenocrysts of the LFe trend do not reach iron-rich end members. The HFe trend is interpreted as a result of fractional crystallization; numerical modelling using the MELTS algorithm suggests that crystallization took place under redox conditions constrained to one-log unit below the fayalite-magnetite-quartz oxygen buffer (FMQ-1). The LFe trend is explained by a combination of mixing between rhyolite and ferrobasalt, assimilation of hydrated crust and fractional crystallization under higher redox conditions (FMQ). The two trends and the gap are best defined in a plot of Mg# versus SiO₂ that is useful to unravel petrogenetic processes. For example, intermediate and silicic rocks of the Holocene volcanic systems of spreading rifts (e.g. Krafla), propagating rifts (e.g. Hekla) and off-rifts (Öræfajökull) also fall into high- and low-iron fields and outline a gap similar to Thingmúli. The identification of two compositional trends in erupted intermediate and silicic volcanic products shows that processes in the deep roots of single volcanic systems are highly diverse and likely controlled by local variations in the thermal gradients and the extend of hydrothermal alteration. Generalizations about the relationship between the compositions of intermediate and silicic rocks and plate tectonic setting, therefore, should be avoided.     

Geomorphic expression of neotectonic activity in a low relief area in an Airborne Laser Scanning DTM: A case study of the Little Hungarian Plain (Pannonian Basin)

The NW corner of the Little Hungarian Plain, which lies at the junction of the Eastern Alps, the Pannonian Basin and the Western Carpathians, is a neotectonically active region linking the extrusional tectonics of the Eastern Alps with the partly subsiding Little Hungarian Plain. The on-going deformation is verified by the earthquake activity in the region. An extremely flat part of the area, east of Neusiedlersee, the so-called Seewinkel, has been investigated with Airborne Laser Scanning (ALS, also known as airborne LiDAR) techniques, resulting in a digital terrain model (DTM) with a 1 m grid resolution and vertical precision of better than 10 cm. The DTM has been compared with known and inferred neotectonic features.Potential neotectonic structures of the DTM have been evaluated, together with geological maps, regional tectono-geomorphic studies, geophysical data, earthquake foci, as well as geomorphological features and the Quaternary sediment thickness values of the Seewinkel and the adjacent Parndorfer plateau. A combined evaluation of these data allows several tectonic features with a relief of < 2 m to be recognized in the DTM. The length of these linear geomorphological structures ranges from several hundred meters up to several kilometers. The most prominent feature forms a 15 km long, linear, 2 m high NE–SW trending ridge with gravel occurrences having an average grain size of ca. 5 cm on its top. We conclude this feature to represent the surface expression of the previously recognized Mönchhof Fault. In general, this multi-disciplinary case study shows that ALS DTMs are extremely important for tectono-geomorphic investigations, as they can detect and accurately locate neotectonic structures, especially in low-relief areas.     

Modelling of Tsunami Propagation in the Vicinity of the French Coast of the Mediterranean

The problem of tsunami-risk for the French coast of the Mediterraneanis discussed. Historical data of tsunami manifestation on the French coast are described and analysed.Numerical simulation of potential tsunamis in the Ligurian Sea is done and the tsunami wave heightdistribution along the French coast is calculated. For the earthquake magnitude 6.8 (typical value forMediterranean) the tsunami phenomenon has a very local character. It is shown that the tsunami tide-gaugerecords in the vicinity of Cannes–Imperia present irregularoscillations with characteristic periodof 20–30 min and total duration of 10–20h.Tsunami propagating from the Ligurian sea to the west coastof France have significantly lesser amplitudes and they are more low-frequency (period of 40–50min).The effect of far tsunamis generated in the southern Italy and Algerian coast is studied also, thedistribution of the amplitudes along the French coast for far tsunamis is more uniform.     

Petrology and Geochemistry of the Volcanic Rocks Dredged from the Geophysicist Seamount in the Kurile Basin: Evidence for the Existence of Thinned Continental Crust

Dredged samples from the Geophysicist seamount volcano in the northeastern part of the Kurile Basin include volcanic and volcanoclastic rocks ranging from basalt to andesite. The rocks have geochemical features typical of high-K island-arc calc-alkaline volcanism. They are enriched in LILE and depleted in Zr, Ti, Nb, Ta and Y. The chondrite-normalized REE patterns are characterized by enrichment of LREE similar to those of island-arc lava from the submarine volcanoes of rear-arc zone of the Kurile Island Arc. The volcanic rocks have a wide range of ⁸⁷Sr/⁸⁶Sr ratios (0.70287-0.70652), varying ¹⁴³Nd/¹⁴⁴Nd and Pb isotopic ratios. Their trace-element compositions and Sr-Nd-Pb isotope signatures may be explained by a small addition of crustal continental component to mantle-derived magmas that suggest the existence of thinned continental basement under the eastern part of the Kurile Basin.