The ichnology of carbonate drifts

Carbonate drifts have so far not been as intensely investigated as their siliciclastic equivalents, especially from an ichnological perspective. The aim of this work is therefore to provide an overview of the different bioturbation styles in carbonate drifts for ichnologists and sedimentologists working in such deposits. Different types of carbonate drifts from the Maldives were studied to address this objective. The cores recovered during International Ocean Discovery Program Expedition 359 were examined to provide the sedimentological and ichnological data for a detailed analysis of the ichnology of carbonate drifts. The ichnological characteristics of the Maldives drifts are compared to other carbonate drifts in order to discuss similarities and differences, and thus provide an overview of the general characteristics of carbonate drift ichnology. These drifts are located in the Santaren Channel which lines Great Bahama Bank, along the Marion Plateau in Australia, in the Limassol and Larnaca basins in Cyprus and in the Danish Basin in Denmark. The common characteristics of bioturbation in carbonate drifts are: (i) the complete bioturbation of the sediment with bioturbation indexes between four and six; (ii) the occurrence of distinctive trace fossils limited to facies contacts or condensed intervals; (iii) a typical ichnoassemblage consisting of Thalassinoides, Scolicia, Planolites, Zoophycos, Chondrites, Phycosiphon and Palaeophycus; (iv) the contiguous occurrence of ichnogenera from different tiers, with only Zoophycos and Chondrites as deep tiers; and (v) distinct infills of the traces including particulate organic matter, pyrite, silica and celestine. In addition, the main ichnofacies of carbonate drifts is the Zoophycos ichnofacies. Ichnofabrics grade from coarse‐grained and completely bioturbated to ichnofabrics with present to rare trace fossils and preserved sedimentary structures. The type and intensity of the bioturbation is controlled by the amount of organic matter and the oxygenation at the sea floor that is determined by the action of bottom currents and the sea‐level fluctuations affecting the carbonate factory in carbonate platforms bordering the basins where the carbonate drifts form. The study of the bioturbation in core and outcrop provides palaeoenvironmental information about carbonate‐drift deposits that complement the classical sedimentological data.     

History of scoria-cone eruptions on the eastern shoulder of the Kenya–Tanzania Rift revealed in the 250-ka sediment record of Lake Chala near Mount Kilimanjaro

Reconstructions of the timing and frequency of past eruptions are important to assess the propensity for future volcanic activity, yet in volcanic areas such as the East African Rift only piecemeal eruption histories exist. Understanding the volcanic history of scoria-cone fields, where eruptions are often infrequent and deposits strongly weathered, is particularly challenging. Here we reconstruct a history of volcanism from scoria cones situated along the eastern shoulders of the Kenya–Tanzania Rift, using a sequence of tephra (volcanic ash) layers preserved in the ~250-ka sediment record of Lake Chala near Mount Kilimanjaro. Seven visible and two non-visible (crypto-) tephra layers in the Lake Chala sequence are attributed to activity from the Mt Kilimanjaro (northern Tanzania) and the Chyulu Hills (southern Kenya) volcanic fields, on the basis of their glass chemistry, textural characteristics and known eruption chronology. The Lake Chala record of eruptions from scoria cones in the Chyulu Hills volcanic field confirms geological and historical evidence of its recent activity, and provides first-order age estimates for seven previously unknown eruptions. Long and well-resolved sedimentary records such as that of Lake Chala have significant potential for resolving regional eruption chronologies spanning hundreds of thousands of years.     

Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.     

Sulfide and platinum mineralization in the Merensky Reef: evidence from hydrous silicates and fluid inclusions

The base metal sulfides of the Merensky Reef are associated with hydrous silicates and intense deuteric hydrous alteration of cumulus and postcumulus silicates. Biotite and phlogopite crystallized in the vicinity of sulfides from a volatile-enriched highly fractionated intercumulus melt. Amphibole, chlorite, and talc are later alteration phases of cumulus pyroxene and intercumulus plagioclase. Biotite is often accompanied by zircon, rutile, and quartz. Accessory quartz hosts a complex suite of H₂O-NaCl-(CaCl₂)-CO₂-CH₄ fluid inclusions which have thus far not been described from the Merensky Reef. The earliest fluid inclusion compositions are NaCl-(H₂O) with less than 10 vol.% water; CO₂ coexisting with a halite daughter crystal and brine; and polyphase inclusions with up to six daughter and accidental phases and high contents of divalent cations. The maximum trapping temperature is around 730° C at 4 to 5 kb pressure. Later inclusion generations are H₂O-NaCl, CO₂-H₂O, and pure CO₂ and CH₄. The presence of Cl-rich fluids during the intercumulus stage of the crystallizing Merensky Reef is directly related to the mode of sulfide precipitation. Prior to sulfide unmixing in a hydrous magma sulfur is likely to be present as H₂S. Sulfur saturation causes reaction of H₂S with oxides of the silicate melt to form a sulfide melt plus water. During reaction the magma is enriched in water until a separate fluid unmixes. It carries all compounds with high fluid/melt partition coefficients, as well as metals capable of forming OH- and Cl-complexes. Precious metals are assumed to have fractionated into the Cl-rich fluid as Cl-complexes rather than being dissolved in the sulfide melt. During the cooling evolution of the fluid the precious elements precipitate around the periphery of sulfide melt droplets. The model proposed explains the distribution pattern of platinum-group minerals in the Merensky Reef better than any orthomagmatic mineralization concept offered so far.     

Archean regional transpression and paleomagnetism in northwestern Ontario, Canada

The Archean metamorphic rocks of the Superior province of the Canadian Shield occur in lithologically defined belts or subprovinces. The tectonically more stable interiors of belts possess consistent primary components of magnetic remanence. In the case of the Quetico belt, these stable directions are tightly grouped about 005°/55° with some minor dispersion and most were acquired during the cooling that followed syntectonic recrystallisation.

This study examines the directions of primary remanence components for rocks along the margins of the Quetico belt, within 4 km of the strongly deformed vertical, ENE-trending boundaries. The boundaries are known to have experienced dextral transpression involving penetrative single-phase deformation which out-lasted metamorphism. Within a few kilometres of the belt boundaries, the primary remanence components are re-distributed along a vertical ENE-trending, great-circle girdle which is nearly parallel to the plane of transpressive shear and regional schistosity. It is suggested that the effects of transpression have mechanically deflected the components of primary remanence toward this plane.     

Scientific problems addressed by the Spektr-UV space project (world space Observatory—Ultraviolet)

The article presents a review of scientific problems and methods of ultraviolet astronomy, focusing on perspective scientific problems (directions) whose solution requires UV space observatories. These include reionization and the history of star formation in the Universe, searches for dark baryonic matter, physical and chemical processes in the interstellar medium and protoplanetary disks, the physics of accretion and outflows in astrophysical objects, from Active Galactic Nuclei to close binary stars, stellar activity (for both low-mass and high-mass stars), and processes occurring in the atmospheres of both planets in the solar system and exoplanets. Technological progress in UV astronomy achieved in recent years is also considered. The well advanced, international, Russian-led Spektr-UV (World Space Observatory—Ultraviolet) project is described in more detail. This project is directed at creating a major space observatory operational in the ultraviolet (115–310 nm). This observatory will provide an effective, and possibly the only, powerful means of observing in this spectral range over the next ten years, and will be an powerful tool for resolving many topical scientific problems.     

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.     

Spatial Periodic Boundary Condition for MODFLOW

Small‐scale hyporheic zone (HZ) models often use a spatial periodic boundary (SPB) pair to simulate an infinite repetition of bedforms. SPB's are common features of commercially available multiphysics modeling packages. MODFLOW's lack of this boundary type has precluded it from being effectively utilized in this area of HZ research. We present a method to implement the SPB in MODFLOW by development of the appropriate block‐centered finite‐difference expressions. The implementation is analogous to MODFLOW's general head boundary package. The difference is that the terms on the right hand side of the solution equations must be updated with each iteration. Consequently, models that implement the SPB converge best with solvers that perform both inner and outer iterations. The correct functioning of the SPB condition in MODFLOW is verified by two examples. This boundary condition allows users to build HZ‐bedform models in MODFLOW, facilitating further research using related codes such as MT3DMS and PHT3D.     

A multi-proxy record of the Last Glacial Maximum and last 14,500?years of paleoenvironmental change at Lone Spruce Pond, southwestern Alaska

Sediment cores from Lone Spruce Pond (60.007°N, 159.143°W), southwestern Alaska, record paleoenvironmental changes during the global Last Glacial Maximum (LGM), and during the last 14,500 calendar years BP (14.5?cal?ka). We analyzed the abundance of organic matter, biogenic silica, carbon, and nitrogen, and the isotope ratios of C and N, magnetic susceptibility, and grain-size distribution of bulk sediment, abundance of alder shrub (Alnus) pollen, and midge (Chironomidae and Chaoboridae) assemblages in a 4.7-m-long sediment sequence from the depocenter at 22?m water depth. The basal unit contains macrofossils dating to 25?C21?cal?ka (the global LGM), and is interpreted as glacial-lacustrine sediment. The open water requires that the outlet of the Ahklun Mountain ice cap had retreated to within 6?km of the range crest. In addition to cladocerans and diatoms, the glacial-lacustrine mud contains chironomids consistent with deep, oligotrophic conditions; several taxa associated with relatively warm conditions are present, suggestive of relative warmth during the global LGM. The glacial-lacustrine unit is separated from the overlying non-glacial lake sediment by a possible disconformity, which might record a readvance of glacier ice. Non-glacial sediment began accumulating around 14.5?cal?ka, with high flux of mineral matter and fluctuating physical and biological properties through the global deglacial period, including a reversal in biogenic-silica (BSi) content during the Younger Dryas (YD). During the global deglacial interval, the ??¹³C values of lake sediment were higher relative to other periods, consistent with low C:N ratios (8), and suggesting a dominant atmospheric CO₂ source of C for phytoplankton. Concentrations of aquatic faunal remains (chironomids and Cladocera) were low throughout the deglacial interval, diversity was low and warm-indicator taxa were absent. Higher production and air temperatures are inferred following the YD, when bulk organic-matter (OM) content (LOI 550?°C) increased substantially and permanently, from 10 to 30?%, a trend paralleled by an increase in C and N abundance, an increase in C:N ratio (to about 12), and a decrease in ??¹³C of sediment. Post-YD warming is marked by a rapid shift in the midge assemblage. Between 8.9 and 8.5?cal?ka, Alnus pollen tripled (25?C75?%), followed by the near-tripling of BSi (7?C19?%) by 8.2?cal?ka, and ??¹⁵N began a steady rise, reflecting the buildup of N and an increase in denitrification in soils. Several chironomid taxa indicative of relatively warm conditions were present throughout the Holocene. Quantitative chironomid-based temperature inferences are complicated by the expansion of Alnus and resulting changes in lake nutrient status and production; these changes were associated with an abrupt increase in cladoceran abundance and persistent shift in the chironomid assemblage. During the last 2,000?years, chironomid-assemblage changes suggest cooler temperatures, and BSi and OM values were generally lower than their maximum Holocene values, with minima during the seventh and eighth centuries, and again during the eighteenth century.     

Geochemistry and shock petrography of the Crow Creek Member,South Dakota,USA: Ejecta from the 74‐Ma Manson impact structure

Abstract— The Crow Creek Member is one of several marl units recognized within the Upper Cretaceous Pierre Shale Formation of eastern South Dakota and northeastern Nebraska, but it is the only unit that contains shock‐metamorphosed minerals. The shocked minerals represent impact ejecta from the 74‐Ma Manson impact structure (MIS). This study was aimed at determining the bulk chemical compositions and analysis of planar deformation features (PDFs) of shocked quartz; for the basal and marly units of the Crow Creek Member. We studied samples from the Gregory 84‐21 core, Iroquois core and Wakonda lime quarry. Contents of siderophile elements are generally high, but due to uncertainties in the determination of Ir and uncertainties in compositional sources for Cr, Co, and Ni, we could not confirm an extraterrestrial component in the Crow Creek Member. We recovered several shocked quartz grains from basal‐unit samples, mainly from the Gregory 84‐21 core, and results of PDF measurements indicate shock pressures of at least 15 GPa. All the samples are composed chiefly of SiO₂ (29–58 wt%), Al₂O₃ (6–14 wt%), and CaO (7–30 wt%). When compared to the composition of North American Shale Composite, the samples are significantly enriched in CaO, P₂O₅, Mn, Sr, Y, U, Cr, and Ni. The contents of rare earth elements (REE), high field strength elements (HFSE), Cr, Co, Sc, and their ratios and chemical weathering trends, reflect both felsic and basic sources for the Crow Creek Member, an inference, which is consistent with the lithological compositions in the environs of the MIS. The high chemical indices of alteration and weathering (CIA' and CIW': 75–99), coupled with the Al₂O₃‐(CaO*+Na₂O)‐K₂O (A‐CN'‐K) ratios, indicate that the Crow Creek Member and source rocks had undergone high degrees of chemical weathering. The expected ejecta thicknesses at the sampled locations (409 to 219 km from Manson) were calculated to range from about 1.9 to 12.2 cm (for the present‐day crater radius of Manson), or 0.4 to 2.4 cm (for the estimated transient cavity radius). The trend agrees with the observed thicknesses of the basal unit of the Crow Creek Member, but the actually observed thicknesses are larger than the calculated ones, indicating that not all of the basal unit comprises impact ejecta.