Scanning electron microscopy,cathodoluminescence, and Raman spectroscopy of experimentally shock‐metamorphosed quartzite

Abstract— We studied unshocked and experimentally (at 12, 25, and 28 GPa, with 25, 100, 450, and 750°C pre‐shock temperatures) shock‐metamorphosed Hospital Hill quartzite from South Africa using cathodoluminescence (CL) images and spectroscopy and Raman spectroscopy to document systematic pressure or temperature‐related effects that could be used in shock barometry. In general, CL images of all samples show CL‐bright luminescent patchy areas and bands in otherwise nonluminescent quartz, as well as CL‐dark irregular fractures. Fluid inclusions appear dominant in CL images of the 25 GPa sample shocked at 750°C and of the 28 GPa sample shocked at 450°C. Only the optical image of our 28 GPa sample shocked at 25°C exhibits distinct planar deformation features (PDFs). Cathodoluminescence spectra of unshocked and experimentally shocked samples show broad bands in the near‐ultraviolet range and the visible light range at all shock stages, indicating the presence of defect centers on, e.g., SiO₄ groups. No systematic change in the appearance of the CL images was obvious, but the CL spectra do show changes between the shock stages. The Raman spectra are characteristic for quartz in the unshocked and 12 GPa samples. In the 25 and 28 GPa samples, broad bands indicate the presence of glassy SiO₂, while high‐pressure polymorphs are not detected. Apparently, some of the CL and Raman spectral properties can be used in shock barometry.     

Chemical composition and iron oxidation state of amorphous matrix silicates in the carbonaceous chondrite Acfer 094

Nanoscale amorphous silicates are a major component in primitive carbonaceous chondrite matrices and anhydrous interplanetary dust particles. Owing to their metastability and sensitive response to reactions with water, this material is of particular interest in understanding nebular and parent body processes in the early solar system. Here we investigated the amorphous silicate matrix (ASM) in the ungrouped carbonaceous chondrite Acfer 094 regarding its texture, chemical composition, and Fe oxidation state. We applied transmission electron microscopy techniques on six, focused ion beam technique-prepared, electron-transparent lamellae of Acfer 094 to determine the textures of this material. Furthermore, we used energy-dispersive X-ray analysis and electron energy loss spectroscopy to quantify the Fe content and the Fe oxidation state of the ASM. Textural investigations reveal differences in sulfide content, porosity, and distribution of the ASM among the samples, as well as evidence for rare recrystallization of phyllosilicate fibers. The chemical composition reveals mobilization of Fe. Furthermore, the determined Fe³⁺/ΣFe ratios of the ASM in the six samples display a homogeneously high oxidation state (0.66–0.73). This high and homogeneous Fe oxidation state in the ASM of Acfer 094 disagrees with its formation as a primary phase in a reduced solar gas and must have been induced in a later stage process. Most likely, this process was aqueous alteration on the Acfer 094 parent body, which led to hydration and oxidation of the ASM, which is supported by textural and chemical evidence of aqueous alteration.     

The STAGES view of red spirals and dusty red galaxies: mass-dependent quenching of star formation in cluster infall

We investigate the properties of optically passive spirals and dusty red galaxies in the A901/2 cluster complex at redshift ∼0.17 using rest-frame near-ultraviolet–optical spectral energy distributions, 24-μm infrared data and Hubble Space Telescope morphologies from the STAGES data set. The cluster sample is based on COMBO-17 redshifts with an rms precision of  σ _cz ≈ 2000 km s⁻¹  . We find that 'dusty red galaxies' and 'optically passive spirals' in A901/2 are largely the same phenomenon, and that they form stars at a substantial rate, which is only four times lower than that in blue spirals at fixed mass. This star formation is more obscured than in blue galaxies and its optical signatures are weak. They appear predominantly in the stellar mass range of  log  M _*/M_⊙=[10, 11]  where they constitute over half of the star-forming galaxies in the cluster; they are thus a vital ingredient for understanding the overall picture of star formation quenching in clusters. We find that the mean specific star formation rate (SFR) of star-forming galaxies in the cluster is clearly lower than in the field, in contrast to the specific SFR properties of blue galaxies alone, which appear similar in cluster and field. Such a rich red spiral population is best explained if quenching is a slow process and morphological transformation is delayed even more. At  log  M _*/M_⊙ < 10  , such galaxies are rare, suggesting that their quenching is fast and accompanied by morphological change. We note that edge-on spirals play a minor role; despite being dust reddened they form only a small fraction of spirals independent of environment.     

Wind-induced drift of objects at sea: The leeway field method

A method for conducting leeway field experiments to establish the drift properties of small objects (0.1-25 m) is described. The objective is to define a standardized and unambiguous procedure for condensing the drift properties down to a set of coefficients that may be incorporated into existing stochastic trajectory forecast models for drifting objects of concern to search and rescue operations and other activities involving vessels lost at sea such as containers with hazardous material.An operational definition of the slip or wind and wave-induced motion of a drifting object relative to the ambient current is proposed. This definition taken together with a strict adherence to a 10 m wind speed allows us to refer unambiguously to the leeway of a drifting object. We recommend that all objects if possible be studied using what we term the direct method, where the object’s leeway is studied directly using an attached current meter.We establish a minimum set of parameters that should be estimated for a drifting object for it to be included in the operational forecast models used for prediction of search areas for drifting objects.We divide drifting objects into four categories, depending on their size. For the smaller objects (less than 0.5 m), an indirect method of measuring the object’s motion relative to the ambient current must be used. For larger objects, direct measurement of the motion through the near-surface water masses is strongly recommended. Larger objects are categorized according to the ability to attach current meters and wind monitoring systems to them.The leeway field method proposed here is illustrated with results from field work where three objects were studied in their distress configuration; a 1:3.3 sized model of a 40-foot Shipping container, a World War II mine and a 220 l (55-gallon) oil drum.     

Methane evolution from UV-irradiated spacecraft materials under simulated martian conditions: Implications for the Mars Science Laboratory (MSL) mission

Fifteen organic and three inorganic compounds were tested for methane (CH₄) evolution under simulated martian conditions of 6.9 mbar; UVC (200-280 nm) flux of 4 W m⁻²; 20 °C; simulated optical depth of 0.1; and a Mars gas composition of CO₂ (95.3%), N₂ (2.7%), Ar (1.7%), O₂ (0.13%), and water vapor (0.03%). All three inorganic compounds (i.e., NaCl, CaCO₃, graphite) failed to evolve methane at the minimum detection level 0.5 ppm, or above. In contrast, all organic compounds evolved methane when exposed to UV irradiation under simulated martian conditions. The polycyclic aromatic hydrocarbon, pyrene, released the most methane per unit of time at 0.175 nmol CH₄ g⁻¹ h⁻¹, and a spectral reflectance target material used for the MER rovers and Phoenix lander released the least methane at 0.00065 nmol CH₄ cm⁻² h⁻¹. Methane was also released from UV-killed bacterial endospores of Bacillus subtilis. Although all organic compounds evolved methane when irradiated with UV photons under martian conditions, the concentrations of residual organics, biogenic signature molecules, and dead microbial cells should be relatively low on the exterior surfaces of the MSL rover, and, thus, not significant sources of methane contamination. In contrast, kapton tape was found to evolve methane at the rate of 0.00165 nmol CH₄ cm⁻² h⁻¹ (16.5 nmol m⁻² h⁻¹) under the UV and martian conditions tested. Although the evolution of methane from kapton tape was found to decline over time, the large amount of kapton tape used on the MSL rover (lower bound estimated at 3 m²) is likely to create a significant source of terrestrial methane contamination during the early part of the mission.     

Geochemical evidence of an extraterrestrial component in impact melt breccia from the Paleoproterozoic Dhala impact structure,India

The Paleoproterozoic Dhala structure with an estimated diameter of ~11 km is a confirmed complex impact structure located in the central Indian state of Madhya Pradesh in predominantly granitic basement (2.65 Ga), in the northwestern part of the Archean Bundelkhand craton. The target lithology is granitic in composition but includes a variety of meta‐supracrustal rock types. The impactites and target rocks are overlain by ~1.7 Ga sediments of the Dhala Group and the Vindhyan Supergroup. The area was cored in more than 70 locations and the subsurface lithology shows pseudotachylitic breccia, impact melt breccia, suevite, lithic breccias, and postimpact sediments. Despite extensive erosion, the Dhala structure is well preserved and displays nearly all the diagnostic microscopic shock metamorphic features. This study is aimed at identifying the presence of an impactor component in impact melt rock by analyzing the siderophile element concentrations and rhenium‐osmium isotopic compositions of four samples of impactites (three melt breccias and one lithic breccia) and two samples of target rock (a biotite granite and a mafic intrusive rock). The impact melt breccias are of granitic composition. In some samples, the siderophile elements and HREE enrichment observed are comparable to the target rock abundances. The Cr versus Ir concentrations indicate the probable admixture of approximately 0.3 wt.% of an extraterrestrial component to the impact melt breccia. The Re and Os abundances and the ¹⁸⁷Os/¹⁸⁸Os ratio of 0.133 of one melt breccia specimen confirm the presence of an extraterrestrial component, although the impactor type characterization still remains inconclusive.     

On the occurrence and origin of anthropogenic radionuclides found in a fragment of the Chelyabinsk (LL5) meteorite

A piece of the 2013 Chelyabinsk meteorite was investigated for its content of anthropogenic radionuclides. In addition to traces of cesium‐137 that had been previously reported for this particular fragment, we found an unusually high amount of strontium‐90, which indicates that the source of this contamination was the Kyshtym accident (1957). A high Sr‐90/Cs‐137 activity ratio is characteristic for Kyshtym‐derived contaminations. Based on the cesium‐137 content in the soil from the finding site, it is estimated that the fragment was contaminated with soil particles in the milligram range upon impact. Investigation of the soil revealed very unusual ferromagnetic characteristics and an iron‐rich chemical composition. Mössbauer spectroscopy indicated the presence of steel components in this soil, suggesting that the investigated meteorite fragment was found in an industrial dumping site rather than natural soil.     

The First Solar Seeing Profile Measurement with Two Apertures and Multiple Guide Regions

The sky brightness is a critical parameter for estimating the coronal observation conditions for a solar observatory. As part of a site-survey project in Western China, we measured the sky brightness continuously at the Lijiang Observatory in Yunnan province in 2011. A sky brightness monitor (SBM) was adopted to measure the sky brightness in a region extending from 4.5 to 7.0 apparent solar radii based on the experience of the Daniel K. Inouye Solar Telescope (DKIST) site survey. Every month, the data were collected manually for at least one week. We collected statistics of the sky brightness at four bandpasses located at 450, 530, 890, and 940 nm. The results indicate that aerosol scattering is of great importance for the diurnal variation of the sky brightness. For most of the year, the sky brightness remains under 20 millionths per airmass before local Noon. On average, the sky brightness is less than 20 millionths, which accounts for 40.41% of the total observing time on a clear day. The best observation time is from 9:00 to 13:00 (Beijing time). The Lijiang Observatory is therefore suitable for coronagraphs investigating the structures and dynamics of the corona.     

Lunar intrusive domes: Morphometric analysis and laccolith modelling

This study examines a set of lunar domes with very low flank slopes which differ in several respects from the frequently occurring lunar effusive domes. Some of these domes are exceptionally large, and most of them are associated with faults or linear rilles of presumably tensional origin. Accordingly, they might be interpreted as surface manifestations of laccolithic intrusions formed by flexure-induced vertical uplift of the lunar crust (or, alternatively, as low effusive edifices due to lava mantling of highland terrain, or kipukas, or structural features). All of them are situated near the borders of mare regions or in regions characterised by extensive effusive volcanic activity. Clementine multispectral UVVIS imagery indicates that they do not preferentially occur in specific types of mare basalt. Our determination of their morphometric properties, involving a combined photoclinometry and shape from shading technique applied to telescopic CCD images acquired at oblique illumination, reveals large dome diameters between 10 and more than 30 km, flank slopes below 0.9°, and volumes ranging from 0.5 to 50 km³. We establish three morphometric classes. The first class, In1, comprises large domes with diameters above 25 km and flank slopes of 0.2°-0.6°, class In2 is made up by smaller and slightly steeper domes with diameters of 10-15 km and flank slopes between 0.4° and 0.9°, and domes of class In3 have diameters of 13-20 km and flank slopes below 0.3°. While the morphometric properties of several candidate intrusive domes overlap with those of some classes of effusive domes, we show that a possible distinction criterion are the characteristic elongated outlines of the candidate intrusive domes. We examine how they differ from typical effusive domes of classes 5 and 6 defined by Head and Gifford [Head, J.W., Gifford, A., 1980. Lunar mare domes: classification and modes of origin. Moon Planets 22, 235-257], and show that they are likely no highland kipukas due to the absence of spectral contrast to their surrounding. These considerations serve as a motivation for an analysis of the candidate intrusive domes in terms of the laccolith model by Kerr and Pollard [Kerr, A.D., Pollard, D.D., 1998. Toward more realistic formulations for the analysis of laccoliths. J. Struct. Geol. 20(12), 1783-1793], to estimate the geophysical parameters, especially the intrusion depth and the magma pressure, which would result from the observed morphometric properties. Accordingly, domes of class In1 are characterised by intrusion depths of 2.3-3.5 km and magma pressures between 18 and 29 MPa. For the smaller and steeper domes of class In2 the magma intruded to shallow depths between 0.4 and 1.0 km while the inferred magma pressures range from 3 to 8 MPa. Class In3 domes are similar to those of class In1 with intrusion depths of 1.8-2.7 km and magma pressures of 15-23 MPa. As an extraordinary feature, we describe in some detail the concentric crater Archytas G associated with the intrusive dome Ar1 and discuss possible modes of origin. In comparison to the candidate intrusive domes, terrestrial laccoliths tend to be smaller, but it remains unclear if this observation is merely a selection effect due to the limited resolution of our telescopic CCD images. An elongated outline is common to many terrestrial laccoliths and the putative lunar laccoliths, while the thickness values measured for terrestrial laccoliths are typically higher than those inferred for lunar laccoliths, but the typical intrusion depths are comparable.