Paläoklimatische Information im Isotopengehalt14C-datierter Saharawässer: Kontinentaleffekt in D und18O

Zusammenfassung In den¹⁴C-Altern der Saharawässer spiegelt sich die wechselnde Abfolge von Feucht- und Trockenphasen während des späten Pleistozäns und Holozäns wider. Außerdem zeigt sich ein West-Ost-Gefälle in ihrem D- und¹⁸O-Gehalt, das als Kontinentaleffekt im Grundwasser gedeutet wird. Dieser Kontinentaleffekt setzt voraus, daß das nordafrikanische Klimageschehen vergangener Feuchtphasen von der Westdrift bestimmt wurde, die regenbringende atlantische Luftmassen weit ins Saharainnere getrieben hat. Ein einfaches mathematisches Modell, das den Kontinentaleffekt durch eine Rayleigh-Kondensation beschreibt, ergibt die beste Anpassung an die Meßwerte, wenn für die Sahara (ähnlich wie heute in Europa) ein West-Ost-Gefälle in den Paläo-Winterniederschlagsmengen von –30% pro 1000 km angenommen wird. Unter der Annahme ehemaliger Winterniederschläge (Sept.-März) von 600 mm (entspricht Lissabon heute) für das Gebiet an der nordafrikanischen Atlantikküste ergibt diese Modellrechnung z. B. 250 mm für die Paläo-Winterniederschläge im Gebiet des Murzuk-Beckens.

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The¹⁴C-age distribution of Saharian groundwaters shows the alternating sequence of humid and arid periods in the late Pleistocene and Holocene. The observed west-east decrease of the D- and¹⁸O-content of the Sahara waters is interpreted to be the Continental Effect in rain and groundwater. The paleoclimatic situation during ground-water formation therefore was controlled by the western drift carrying wet Atlantic air masses across the Sahara. The best fit of a simple Rayleigh condensation model of the continental effect to the experimental data is obtained with a west-east decrease of the Saharian paleo-winter precipitation of –30% per 1000 km (similar to the one in Europe today). With an annual winter precipitation rate (Sept.-March) of 600 mm (corresponding to the one of Lisboa today) for the Northafrican coastal area at the Atlantic Ocean a previous winter precipitation rate of 250 mm is obtained for the Murzuq Basin.

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Résumé Une succession de périodes humides et arides à la fin du Pléistocène et à l'Holocène se réflète dans la distribution des âges¹⁴C d'eaux souterraines du Sahara. Les teneurs en D et¹⁸O diminuent d'Ouest en Est, ce qui est interprété comme un effet continental dans l'eau souterraine. Celui-ci signifie que la climatologie des phases pluviales passées, dans l'Afrique du Nord, était déterminée par des vents d'Ouest qui apportaient des masses d'air atlantique humide à l'intérieur du Sahara. Un modèle mathématique simple décrivant l'effet continental par une condensation du type Rayleigh, reproduit avec la meilleure conformité les valeurs expérimentales, pour autant qu'on admette que les pluies hivernales au Sahara diminuaient anciennement d'Ouest en Est de 30% par 1000 km (comme à présent en Europe). En supposant qu'autrefois la quantité de pluie hivernale, de septembre à mars à la côte atlantique de l'Afrique du Nord était de 600 mm (comme aujourd'hui à Lisbonne), on obtient à l'aide de ce modèle une précipitation hivernale ancienne de 250 mm dans le bassin du Mourzouk.

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Modelling of Tsunami Propagation in the Vicinity of the French Coast of the Mediterranean

The problem of tsunami-risk for the French coast of the Mediterraneanis discussed. Historical data of tsunami manifestation on the French coast are described and analysed.Numerical simulation of potential tsunamis in the Ligurian Sea is done and the tsunami wave heightdistribution along the French coast is calculated. For the earthquake magnitude 6.8 (typical value forMediterranean) the tsunami phenomenon has a very local character. It is shown that the tsunami tide-gaugerecords in the vicinity of Cannes–Imperia present irregularoscillations with characteristic periodof 20–30 min and total duration of 10–20h.Tsunami propagating from the Ligurian sea to the west coastof France have significantly lesser amplitudes and they are more low-frequency (period of 40–50min).The effect of far tsunamis generated in the southern Italy and Algerian coast is studied also, thedistribution of the amplitudes along the French coast for far tsunamis is more uniform.     

Europeanizing Timisoara: neoliberal reforms, continuity with the past, and unexpected side effects

This paper analyzes how processes of Europeanization opened up opportunities and generated ideals, which in turn changed the articulation between political and economic powers in the city and county of Timisoara, Western Romania. It builds on case studies of local government agencies and foreign investors from Italy. In doing so, it discusses the circular relationship between the European and the local levels of governance: European governance affected the interactions between firms and institutions in the city, while at the same time city authorities used different understandings of ‘Europe’ to pursue their own agenda. It also shows some of the unexpected side-effects of Europeanization, due to the political activism of Italian investors. Beck and Grande’s concept of ‘reflexive modernization’ and the literature on regional economies frame the discussion.     

Ammonium in aqueous fluids to 600 °C, 1.3 GPa: A spectroscopic study on the effects on fluid properties, silica solubility, and K-feldspar to muscovite reactions

The behavior of ammonium, NH₄⁺, in aqueous systems was studied based on Raman spectroscopic experiments to 600 °C and about 1.3 GPa. Spectra obtained at ambient conditions revealed a strong reduction of the dynamic three-dimensional network of water with addition of ammonium chloride, particularly at small solute concentrations. The differential scattering cross section of the ν₁-NH₄⁺ Raman band in these solutions was found to be similar to that of salammoniac.The Raman band of silica monomers at ∼780 cm⁻¹ was present in all spectra of the fluid at high temperatures in hydrothermal diamond-anvil cell experiments with H₂O ± NH₄Cl and quartz or the assemblage quartz + kyanite + K-feldspar ± muscovite/tobelite. However, these spectra indicated that dissolved silica is less polymerized in ammonium chloride solutions than in comparable experiments with water. Quantification based on the normalized integrated intensity of the H₄SiO₄⁰ band showed that the silica solubility in experiments with H₂O + NH₄Cl was significantly lower than that in equimolal NaCl solutions. This suggests that ammonium causes a stronger decrease in the activity of water in chloridic solutions than sodium.The Raman spectra of the fluid also showed that a significant fraction of ammonium was converted to ammonia, NH₃, in all experiments at temperatures above 300 °C. This indicates a shift towards acidic conditions for experiments without a buffering mineral assemblage. The estimated pH of the fluid was ∼2 at 600 °C, 0.26 GPa, 6.6 m initial NH₄Cl, based on the ratio of the integrated ν₁-NH₃ and ν₁-NH₄⁺ intensities and the HCl⁰ dissociation constant. The NH₃/NH₄⁺ ratio increased with temperature and decreased with pressure. This implies that more ammonium should be retained in K-bearing minerals coexisting with chloridic fluids upon high-P low-T metamorphism. At 500 °C, 0.73 GPa, ammonium partitions preferentially into the fluid, as constrained from infrared spectroscopy on the muscovite and from mass balance.The conversion of K-feldspar to muscovite proceeded much faster in experiments with NH₄Cl solutions than in comparable experiments with water. This is interpreted as being caused by enhancement of the rate-limiting alumina solubility, suggesting complexation of Al with NH₄. Nucleation and growth of mica at the expense of K-feldspar and NH₄⁺/K⁺ exchange between fluid and K-feldspar occurred simultaneously, but incorporation of NH₄⁺ into K-feldspar was distinctly faster than K-feldspar consumption.     

Determination of Total Organic Carbon Content and δ13C in Carbonate-Rich Detrital Sediments

The determination of total organic carbon content and composition in detrital sediments requires careful removal of their carbonate minerals. In detrital sediments containing large amounts of carbonates, including dolomite, this can only be achieved by liquid acid leaching that may solubilise a significant proportion of the organic carbon. For a set of detrital sediments from the Himalayan system and the Amazon River as well as five geological reference materials, we determined the proportion of organic carbon (C_org) solubilised during acid leaching. This proportion is significant for all analysed sediments and generally tends to increase with the organic carbon content. Compared to other types of sediments analysed, clay fractions extracted from river sediments and bed sediments with very low organic carbon content have high and low proportions of acid soluble C_org respectively. In Himalayan and Amazon river sediments, the proportion of C_org solubilised during acid leaching was relatively constant with average values of 14 and 19 % respectively. Thus, it is possible to correct the C_org content for the dissolved organic carbon content measured after decarbonation. Data presented here show that C_org dissolved during liquid acid leaching must be taken into account. After careful calibration, the method presented here should, therefore, be applied to any carbonate-rich detrital sediment.     

A Preliminary Study of the Physiography of the Foochow Basin

正 TOPOGRAPHIC SETTING Foochow City lies about 34 miles above the mouth of the Min River at approximately 119 degrees East Longitude and 26 degrees North Latitude.Foochow Basin(Pl. 1)contains about 150 square miles. It is surrounded on     

Une méthode globale d'estimation des températures des réservoirs alimentant les sources thermales. Exemple du Massif Central Français

A chemical model based on the equilibrium of water with quartz, albite, adularia, calcite, kaolinite or illite, and chlorite can explain the chemical composition of the main groups of hot springs in Massif Central. Temperature is the principal variable for determining this composition. Model temperatures generally agree with those given by classical cation geothermometers (t ? 135–150° C for Vichy. La Bourboule. Evaux and Châteauneuf; t ? 175–180° C for Chaudes Aigues and Saint Nectaire). The model fails to represent the composition of Mont Dore waters: the high temperatures given by classical geothermometers are considered doubtful.     

Post-breakup basaltic magmatism along the East Greenland Tertiary rifted margin

Mafic and ultramafic intrusions in East Greenland adjacent to the offshore Greenland–Iceland ridge were emplaced 5–9 My after continental breakup at 55 Ma [1]. Rare earth element (REE) concentrations determined by secondary ion mass spectrometry are reported for cumulus clinopyroxene from these intrusions, and the data are used to estimate REE abundance in equilibrium melts using available partitioning data. Estimated equilibrium melts from intrusions have strongly fractionated REE patterns with Nd/Dy(N) in the range 2 to 5.6 and Yb/Dy(N) 0.55 to 0.92, similar to values for coeval basalts. These melts have markedly higher Nd/Dy(N) than earlier breakup related flood basalts. The moderately low Yb/Dy(N) for the post-breakup volcanism is indicative of residual garnet in the source, while their high Nd/Dy(N) ratios can best be explained by aggregating low degree melts from a light-REE-enriched garnet- and spinel-bearing mantle source. We also report He, Sr, and Nd isotopic data for the intrusions. The highest ³He/⁴He ratios (>10 R/R_a) are found in the samples whose REE data reflect the largest proportion of melts from a garnet-bearing source, and having Sr and Nd isotopic compositions identical with the radiogenic Sr and unradiogenic Nd isotope end of the Iceland compositional field. There is no indication of a MORB-type mantle in the source of the intrusions. We postulate that post-breakup volcanism along the East Greenland coastline reflects the increasing proximity of the mantle plume to the East Greenland continental margin. The low degree of melting at high mean pressure inferred for the parental melts for the intrusions may reflect re-thickening of the lithosphere, which in turn was caused by the vigorous volcanism during breakup, with accompanying depletion of upper mantle and underplating of the crust at the continental margin.     

Solute and Heat Transport Model of the Henry and Hilleke Laboratory Experiment

SEAWAT is a coupled version of MODFLOW and MT3DMS designed to simulate variable-density ground water flow and solute transport. The most recent version of SEAWAT, called SEAWAT Version 4, includes new capabilities to represent simultaneous multispecies solute and heat transport. To test the new features in SEAWAT, the laboratory experiment of Henry and Hilleke (1972) was simulated. Henry and Hilleke used warm fresh water to recharge a large sand-filled glass tank. A cold salt water boundary was represented on one side. Adjustable heating pads were used to heat the bottom and left sides of the tank. In the laboratory experiment, Henry and Hilleke observed both salt water and fresh water flow systems separated by a narrow transition zone. After minor tuning of several input parameters with a parameter estimation program, results from the SEAWAT simulation show good agreement with the experiment. SEAWAT results suggest that heat loss to the room was more than expected by Henry and Hilleke, and that multiple thermal convection cells are the likely cause of the widened transition zone near the hot end of the tank. Other computer programs with similar capabilities may benefit from benchmark testing with the Henry and Hilleke laboratory experiment.