Pedogenic factors affecting magnetic susceptibility of the last interglacial palaeosol S1 in the Chinese Loess Plateau

The magnetic susceptibility has been used as a quantitative or semi‐quantitative proxy for reconstructing the summer monsoon intensity in the Chinese Loess Plateau based on extensive studies on climatic or/and environmental mechanisms producing the magnetic susceptibility signatures. However, the precise nature of the link between past climates and the susceptibility signatures has remained uncertain primarily due to lack of our understanding in the ?nalizing and preserving processes of the signatures. This paper attempts to examine the reliability or acceptability of this summer monsoon proxy from non‐magnetic perspectives of soil‐forming processes. We chose nine sections along two transects: one across the western part of the Chinese Loess Plateau and another across the eastern part. Several conclusions can be drawn from our analytical data. First, clay translocation within the S1 palaeosol pro?les, as indicated by ?eld‐observed clay coatings on ped faces in Bt and Bk horizons and demonstrated by laboratory‐analysed clay contents, must have moved some of the magnetic minerals downward so that the susceptibility re?ects only the post‐translocation distribution of the magnetic‐susceptibility‐producing minerals. Second, the best‐developed palaeosol S1S3 at most of the sections studied is not expressed by the magnetic susceptibility because this palaeosol developed in underlying coarse loess (L2) and coarse textures tend to lower the susceptibility. Third, carbonate concentration is normally negatively correlated with the magnetic susceptibility or simply suppresses the magnetic susceptibility peak when the susceptibility enhancement exceeds the carbonate dilution effect. To conclude, extreme caution must be observed when using magnetic susceptibility signatures to retrieve high‐resolution records of the last interglacial palaeoclimate in the Chinese Loess Plateau. Copyright © 2004 John Wiley & Sons, Ltd.     

Optimal design of viscoelastic dampers using eigenvalue assignment

In this study a procedure for determining the optimum size and location of viscoelastic dampers is proposed using the eigenvalue assignment technique. Natural frequencies and modal damping ratios, required to realize a given target response, are determined first by the convex model. Then the desired dynamic structural properties are realized by optimally distributing the damping and stiffness coefficients of viscoelastic dampers using non‐linear programming based on the gradient of eigenvalues. This optimization method provides information on the optimal location as well as the magnitude of the damper parameters. The proposed procedure is applied to the retrofit of a 10‐story shear frame, and to a three‐dimensional structure with an asymmetric plan. The analysis results confirm that the responses of model structures retrofitted by the proposed method correspond well with the given target response. Copyright © 2003 John Wiley & Sons, Ltd.     

Seismic structural control using an electric servomotor active mass driver system

This study investigates an electric‐type active mass driver (AMD) system for structural vibration control. Composed primarily of an electric servomotor and a ball screw, the electrical AMD system is free from noise problems, oil leakage, and labor‐intensive maintenance that commonly are associated with hydraulic AMD systems. The desired stroke amplification of the mass and the power demand of the servomotor can be adjusted via the ball screw pitch, which in turn affects the effectiveness and efficiency of the system. Meanwhile, an instantaneous optimal direct output feedback control algorithm is adopted. Numerical simulation is performed using a five‐story steel frame as the object structure under the conditions of the 1940 El Centro earthquake. The AMD system proves to be effective and efficient within a certain range of the ball screw pitch. The reductions of the peak responses can reach as high as 70% if properly designed. Requiring only the velocity measurement of the top floor for on‐line feedback control, the proposed control algorithm is recommended for practical implementation. Copyright © 2004 John Wiley & Sons, Ltd.     

The effect of dissolved barium on biogeochemical processes at cold seeps

A numerical model was applied to investigate and quantify the biogeochemical processes fueled by the expulsion of barium and methane-rich fluids in the sediments of a giant cold-seep area in the Derugin Basin (Sea of Okhotsk). Geochemical profiles of dissolved Ba²⁺, Sr²⁺, Ca²⁺, SO₄²⁻, HS⁻, DIC, I⁻ and of calcium carbonate (CaCO₃) were fitted numerically to constrain the transport processes and the kinetics of biogeochemical reactions. The model results indicate that the anaerobic oxidation of methane (AOM) is the major process proceeding at a depth-integrated rate of 4.9 μmol cm⁻² a⁻¹, followed by calcium carbonate and strontian barite precipitation/dissolution processes having a total depth-integrated rate of 2.1 μmol cm⁻² a⁻¹. At the low seepage rate prevailing at our study site (0.14 cm a⁻¹) all of the rising barium is consumed by precipitation of barite in the sedimentary column and no benthic barium flux is produced. Numerical experiments were run to investigate the response of this diagenetic environment to variations of hydrological and biogeochemical conditions. Our results show that relatively low rates of fluid flow (<∼5 cm a⁻¹) promote the dispersed precipitation of up to 26 wt% of barite and calcium carbonate throughout the uppermost few meters of the sedimentary column. Distinct and persistent events (several hundreds of years long) of more vigorous fluid flow (from 20-110 cm a⁻¹), instead, result in the formation of barite-carbonate crusts near the sediment surface. Competition between barium and methane for sulfate controls the mineralogy of these sediment precipitates such that at low dissolved methane/barium ratios (<4-11) barite precipitation dominates, while at higher methane/barium ratios sulfate availability is limited by AOM and calcium carbonate prevails. When seepage rates exceed 110 cm a⁻¹, barite precipitation occurs at the seafloor and is so rapid that barite chimneys form in the water column. In the Derugin Basin, spectacular barite constructions up to 20 m high, which cover an area of roughly 22 km² and contain in excess of 5 million tons of barite, are built through this process. In these conditions, our model calculates a flux of barium to the water column of at least 20 μmol cm⁻² a⁻¹. We estimate that a minimum of 0.44 × 10⁶ mol a⁻¹ are added to the bottom waters of the Derugin Basin by cold seep processes, likely affecting the barium cycle in the Sea of Okhotsk.     

Chemical and isotopic equilibrium between CO2 and CH4 in fumarolic gas discharges: Generation of CH4 in arc magmatic-hydrothermal systems

The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece, and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH₄) within two subduction-related magmatic-hydrothermal environments.Apparent temperatures derived from carbon isotope partitioning between CH₄ and CO₂ of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H₂O-H₂-CO₂-CO-CH₄ geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH₄, CO₂ and H₂O implying that carbon isotope partitioning between CO₂ and CH₄ in both systems is controlled by aquifer temperature.N₂/³He and CH₄/³He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH₄ may have been primarily generated through the reduction of CO₂ by H₂ in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH₄ and subsequent re-equilibration with co-existing CO₂ cannot be ruled out entirely. CO₂/³He ratios and δ¹³C_CO2 values imply that the evolved CO₂ either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH₄ during thermometamorphism.     

Researching the South African tourism and development nexus

Under apartheid, tourism was essentially anti-developmental in focus and tourism research largely centred on the recreation of white South Africans. Since the 1994 democratic transition tourism has become recognised as an increasingly important sector for South Africa's economy and for achieving the government's goals for reconstruction and development. In this paper a review and critical analysis is presented of the changing directions and foci of tourism scholarship in South Africa. It is shown that South African scholars are beginning to respond to the challenges posed by tourism as a developmental focus. This revised version was published online in August 2006 with corrections to the Cover Date.     

L'accident du Toulourenc : une limite tectonique entre la plate-forme provençale et le Bassin vocontien à l'Aptien–Albien (SE France)

The WNW–ESE trending Toulourenc Fault Zone (TFZ) is the western segment of the major Ventoux–Lure Fault Zone, which separates the Provençal platform from the Baronnies Vocontian Basin. The TFZ was subject to polyphased Mid-Cretaceous movements, during the Early Aptian and Middle–Late Albian times. The latter faulting episode generated conglomerates and olistoliths resulting from dismantled faultscarps cutting Barremian–Bedoulian limestones. The deformation is related to compressional wrench faulting (NE–SW sinistral faults; dextral component for the TFZ). It induced the uplift of the northwestern corner of the platform, as indicated by a mid-Cretaceous hiatus (Early Aptian pro parte to Early Albian) narrowly delimited in space. The opening of submeridian grabens within the platform favoured the northward transit of channelised coarse-grained Albian sands originating from a southern area. To cite this article: C. Montenat et al., C. R. Geoscience 336 (2004).