Petrogenesis of extension-related alkaline volcanism in Karaburhan (Sivrihisar–Eskisehir), NW Anatolia, Turkey

Alkaline lavas were erupted as phonolites and trachytes around Karaburhan (Sivrihisar–Eskisehir, NW Anatolia) within the Izmir–Ankara–Erzincan suture zone. These volcanic rocks were emplaced as domes, close and parallel to the ophiolite thrust line. According to ⁴⁰Ar/³⁹Ar geochronological analyses of sanidine crystals from the phonolites, the age of the alkaline volcanics is 25 Ma (Late Oligocene–Early Miocene).The flow-textured phonolites are porphyritic and consist mainly of sanidine, clinopyroxene, and feldspathoid crystals. The clinopyroxenes show compositional zoning, with aegirine (Na_0.82–0.96Fe⁺³_0.68–0.83) rims and aegirine–augite cores (containing calcium, magnesium, and Fe⁺²). Some aegirine–augites are replaced with sodium-, calcium-, and magnesium-rich amphibole (hastingsite). Feldspathoid (hauyne) crystals enriched with elemental Na and Ca have been almost completely altered to zeolite and carbonate minerals. The fine-grained trachytes with a trachytic texture consist of feldspar (oligoclase and sanidine) phenocrystals and clinopyroxene microphenocrystals within a groundmass made up largely of alkali feldspar microlites.Although there are some differences in their element patterns, the phonolites and trachytes exhibit enrichment in LILEs (Sr, K, Rb, Ba, Th) and LREEs (La, Ce, Pr, Nd) and negative anomalies in Nb and Ta. These geochemical characteristics indicate a lithospheric mantle enriched by fluids extracted from the subduction component. In addition, the high ⁸⁷Sr/⁸⁶Sr (0.706358–0.708052) and low ¹⁴³Nd/¹⁴⁴Nd (0.512546–0.512646) isotope concentrations of the alkaline lavas reflect a mantle source that has undergone metasomatism by subduction-derived fluids. Petrogenetic modeling indicates that the alkaline lavas generated from the subduction-modified lithospheric mantle have undergone assimilation, fractional crystallization, and crustal contamination, acquiring high Pb, Ba, Rb, and Sr contents and Pb isotopic compositions during their ascent through the thickened crust in an extensional setting.     

The Influence of the “Mixed Pixel” Problem on the Detection of Analogous Forest Communities Between Presettlement and Present in Western New York∗

We conducted a land change analysis to determine if the forest communities of presettlement and present contain areas that are analogous in composition, using surveys of the Holland Land Company (1797–1799) and U.S. Forest Service (1991–1993) from western New York. Gridded forest-type maps are produced from each survey using two models: a uniform model that assumes each data grid cell is occupied by a single forest type, and a mixture model in which grid cells are assumed to be occupied by multiple forest types in different proportions. The mixture model consistently detects a larger area of analogous communities in the two time periods at both global and local scales.     

Further comments concerning “geographic” and “economic” economic geography

This article considers whether the growing theoretical and methodological diversity or pluralistic nature of economic geography contributes to its lack of engagement outside the discipline and academy. Although we are enthusiastic about the vibrancy this pluralism brings, we also speculate that it contributes to the discipline's tendency to fall short of significantly impacting key debates in the social sciences. In particular, we consider the disciplinary challenges to influencing mainstream debates over financialization and the recent financial crisis and the recurring lament that economic geography “misses the boat” by failing to significantly impact key scholarly and policy issues. Specifically, we suggest that methodological and theoretical diversity, local contextualization, and relational analysis, all of which we support as vital to the discipline, make it difficult to isolate a disciplinary core. We conclude that pluralism produces a vibrant discipline with unique explanatory power but that it also has important impacts on the design, execution, and influence of geographers’ research outside the discipline.     

Some thoughts on inference in the analysis of spatial data

Statistical inference is important for all those who engage in the analysis of spatial data. The issue is becoming increasingly important given the explosion in the availability of spatial data and the proliferation of Geographic Information Systems (GIS) across different academic disciplines and application areas. The aim of this paper is to provide a brief overview of some of the concepts and controversies inherent in statistical inference in the hope of raising the level of awareness within the geographic information science community that different points of view exist when it comes to inference. We argue that the concept of statistical inference in spatial data analysis and spatial modelling is perhaps broader than many GIS users imagine. In particular, we argue that different types of inference exist and that process inference is just as valid as sample inference, even though the latter appears to dominate the GIS literature.     

A local stability analysis of astronomical disks

Abstract

A fifth-order dispersion relation describing the local stability of a differentially rotating flow against small perturbations is derived. Finite viscosity and conductivity and both vertical (parallel to the rotation axis) and radial gradients in density, temperature and pressure are included. A general form is assumed for the equation of state, although this is not exploited in the paper. A number of special cases are studied: with negligible viscosity and conductivity, it is shown that modes can often be separated into two high frequency (modified acoustic), two intermediate frequency (combined inertial and internal waves) and a low frequency mode. In convectively unstable situations the intermediate frequency modes may be replaced by a damped/growing pair of instablities. Various criteria for mode excitation are given. It is shown that viscosity always inhibits instability at very short wavelengths, while non-zero conductivity may destabilize the flow. At intermediate wavelengths viscosity could also play a destabilizing role. A parameter study of the effects of fluctuations in the conductivity shows that it could cause mode excitation under certain circumstances.     

Climate change and the oceans – What does the future hold?

The ocean has been shielding the earth from the worst effects of rapid climate change by absorbing excess carbon dioxide from the atmosphere. This absorption of CO₂ is driving the ocean along the pH gradient towards more acidic conditions. At the same time ocean warming is having pronounced impacts on the composition, structure and functions of marine ecosystems. Warming, freshening (in some areas) and associated stratification are driving a trend in ocean deoxygenation, which is being enhanced in parts of the coastal zone by upwelling of hypoxic deep water. The combined impact of warming, acidification and deoxygenation are already having a dramatic effect on the flora and fauna of the oceans with significant changes in distribution of populations, and decline of sensitive species. In many cases, the impacts of warming, acidification and deoxygenation are increased by the effects of other human impacts, such as pollution, eutrophication and overfishing.     

Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.     

面理弯切轴测量技术在造山带研究中的应用——以美国阿肯色河地区为例

基于变形分解理论提出的面理弯切轴测量技术,通过对变斑晶中多期面理的测定分析,为厘定造山运动中的变形过程提供了新的精确定量研究手段。面理弯切轴数据已经被用于解决地质领域多种问题,例如:研究造山运动过程中变形变质历史以及在区域和造山带尺度对比多期变质作用;论证变斑晶生长过程是否发生旋转;变斑晶成核生长与区域变形过程之间的关系;重建板块运动历史过程;约束不同地质事件的发生时限;划分复杂变形分解类型以及岩浆侵位机制及时限研究。本文主要介绍面理弯切轴测量方法的原理、具体测定方法、研究意义及应用范围,并以美国阿肯色地区为例,详细介绍了面理弯切轴测量技术在造山运动过程区域变形历史重建中的应用。     

A simple model illustrating the virtue of replication for long-term information preservation

Each year destructive events might cause loss of data in members of an archival federation. This paper provides a ‘back-of-the-envelope’ model for the fraction of the federated data collection that survives after a certain number of years. It also discusses some simple parameterizations of factors that contribute to the trade offs between cost and survival of information.