Seismic refraction studies of the upper igneous crust in the North Atlantic and porosity estimates for Layer 2

A number of unreversed refraction profiles up to 40 km long and with closely spaced shots has been interpreted to provide the structure of oceanic Layer 2. Different velocity/depth models based on a homogeneous layered structure and on a gradient structure have been obtained for each profile. The gradient models are believed to be a better representation of the real earth. They are all remarkably similar with a predominant velocity gradient of 0.85–1.35 km s^?1 km^?1 ending with a slowly downward increasing velocity of about 6 km s^?1 at about 2 km depth. The positive gradient can be reasonably explained by the reduction downwards of bulk porosity, particularly due to the closure of cracks, in a simple two-component, basalt plus voids, model. The model takes account of weathering but not of metamorphism. A theory, based on oversimplified assumptions about the rocks in Layer 2, allows rough estimates of porosity at different depths to be made.     

Illite/smectite transformation in detrital glaucony during burial diagenesis of sandstone: A study from Siri Canyon – Danish North Sea

Detrital glaucony in the Palaeogene glauconitic sandstones in Siri Canyon, Danish North Sea, has been analysed from 15 exploration wells by X‐ray diffraction, electron microprobe and scanning electron microscopy. These sandstones consist of mixed‐layer illite/smectite and have a large variability in chemical composition and structure. In the most shallow wells (ca 1700 m), the glaucony is rich in Fe and consists of mixed‐layer illite/smectite with random‐interstratification (R = 0). In the depth interval from 1700 to 2000 m, the composition changes as Si is incorporated. The structure changes to ordered R = 1. Further increase in burial leads to the loss of Fe. Ordered R = 3 mixed‐layer illite/smectite is recognized from burial depths of 2200 m. The proportion of illite in illite/smectite mixed layers increases only slightly with depth and temperature. Although the structural changes generally are associated with chemical changes, they can also take place isochemically when the detrital glaucony is tightly embedded in earlier cement, which prevented chemical exchange. The glaucony transformation in the Siri Canyon sandstones partly reflects a supply of Si and partly significant loss of Fe. Thus, the glaucony transformation relates to the general diagenesis of the host sandstone. These sandstones are cemented by microquartz at an early stage, followed by precipitation of Fe‐rich grain‐coating berthierine or chlorite.     

Three caldera-shaped accidents: Volcanic calderas,meteoric scars and lunar cirques

A caldera is a large volcanic depression, more or less circular, the diameter of which is many times greater than those of the included volcanic vents. Calderas must be separated from feetono-volcanic depressions, which have an irregular shape. Volcanic calderas are produced by engulfment. The scars, produced by the impact of meteorites on the earth, are circular or elliptical depressions. Lunar cirques are nearly all circular; some of them have a polygonal, and then sometimes an hexagonal shape. On the surface of the moon elliptical depressions are wholly absent. Moreover, on the moon it is a rigid law that when intersections of ring plains do occur, the smaller cirque is entire, the rim of the middlemost being interrupted by the smallest, whereas the biggest is interrupted by the middle one. This phenomenon would be in accordance with a volcanic origin and a decreasing volcanic activity whereas it is incompatible with an impact of meteorites.     

Development dynamics of intense solar proton flares

We consider the relationship of electromagnetic radiation in the three most intense flares of solar cycle 23, more specifically, those of October 28, 2003, January 20, 2005, and September 7, 2005, to the acceleration and release of protons into interplanetary space. The impulsive phase of these flares lasted ～ 20 min and consisted of at least three energy release episodes, which differed by their manifestation in the soft (1–8 Å, GOES) and hard (>150 keV, INTEGRAL) X-ray ranges as well as at radio frequencies of 245 MHz and 8.8 GHz. The protons and electrons were accelerated in each episode, but with a different efficiency; the relativistic protons were accelerated only after 5–6min of impulsive-phase development after the onset of a coronal mass ejection. It is at this time that maximum hard X-ray fluxes were observed in the September 7, 2005 event, which exceeded severalfold those for the other two flares considered. We associate the record fluxes of protons with energies > 200MeV observed in the heliosphere in the September 7, 2005 event with the dynamics of the impulsive phase. The extreme intensities of the microwave emission in the October 28, 2003 and January 20, 2005 events were probably attributable to the high-energy electron trapping conditions and did not reflect the acceleration process.     

Biogeochemical and hydrographic controls on chromophoric dissolved organic matter distribution in the Pacific Ocean

Recent in situ observations of chromophoric dissolved organic material (CDOM) in the Pacific Ocean reveal the biogeochemical controls on CDOM and indicate predictive potential for open-ocean CDOM in diagnosing particulate organic matter (POM) remineralization rates within ocean basins. Relationships between CDOM and concentrations of dissolved oxygen, nutrients and inorganic carbon in the subthermocline waters of the Pacific reflect the relative influences of water mass ventilation and water-column oxidative remineralization. Apparent in situ oxygen utilization (AOU) accounts for 86% and 61% of variance in CDOM abundance, respectively, in Antarctic Intermediate Water and North Pacific Intermediate Water. In the deep waters of the Pacific below the zone of remineralization, AOU explains 26% of CDOM variability. The AOU–CDOM relationship results from competing biogeochemical and advective processes within the ocean interior. Dissolved organic carbon (DOC) is not statistically linked to the CDOM or AOU distributions, indicating that the majority of CDOM production occurs during the remineralization of sinking POM and thus potentially provides key information about carbon export. Once formed in the ocean interior, CDOM is relatively stable until it reaches the surface ocean where it is destroyed by solar bleaching. Susceptibility to bleaching confers an additional tracer-like quality for CDOM in water masses with active convection, such as mode waters that appear as subsurface CDOM minima. In the surface ocean, atypically low CDOM abundance highlights a region of unusually extreme oligotrophy: the subtropical South Pacific gyre. For these hyper-oligotrophic waters, the present CDOM observations are consistent with analysis of in situ radiometric observations of light attenuation and reflectance, demonstrating the accuracy of the CDOM spectrophotometric observations. Overall, we illustrate how CDOM abundance in the ocean interior can potentially diagnose rates of thermohaline overturning as they affect regional biogeochemistry and export. We further show how relative surface ocean CDOM abundances are driven in large part by processes occurring in the deep layers of the ocean. This is particularly significant for the interpretation of the global surface distribution of CDOM using satellite remote sensing.     

Comparison of the orientation of small-scale electron density irregularities and F region plasma flow direction

Results are shown from an experimental campaign where satellite scintillation was observed at three sites at high latitudes and, simultaneously, the F region plasma flow was measured by the nearby EISCAT incoherent scatter radar. The anisotropy parameters of field-aligned irregularities are determined from amplitude scintillation using a method based on the variance of the relative logarithmic amplitude. The orientation of the anisotropy in a plane perpendicular to the geomagnetic field is compared with the direction of F region plasma flow. The results indicate that in most cases a good agreement between the two directions is obtained.     

The isotopic composition of oxygen and carbon in the hyaloclastites from the Mt. Iblei volcanic area,Eastern Sicily: A preliminary study

Oxygen and carbon isotopic analyses were carried out for some typical submarine volcanic products (a lava flow, a pillow fragment and four hyaloclastite breccias) from the northwestern zone of the Mt. Iblei volcanic complex, eastern Sicily. The δ¹⁸O value of the perental basaltic magma (6.0 ± 0.2‰), estimated from the analyses of some fresh unaltered glassy samples of various type, lies in the values range of primary basalts. Appreciably higher δ¹⁸O values, probably due to low-temperature exchanges with sea water, have been found for lava samples and the interior of the pillow fragment. The δ¹⁸O and δ¹³C of the calcites of the groundmass of the hyaloclastite samples, ranging from 30.59 to 33.65 and from ?2.99 to 0.46‰ respectively, are typical of low-temperature marine carbonates. Because calcite is one of the last minerals to form. these results suggest that the hyaloclastites studied formed entirely in a submarine environment. The¹⁸O/¹⁶O ratios recorded in the silicate portions of the matrices of the hyaloclasites (δ¹⁸O=13.99 to 16.61) are interpreted as the result of halmyrolytic processes occurring at temperatures somewhat higher than that of the sea floor.     

Adsorption of copper (II) on mesoporous silica: the effect of nano-scale confinement

Nano-scale spatial confinement can alter chemistry at mineral–water interfaces. These nano-scale confinement effects can lead to anomalous fate and transport behavior of aqueous metal species. When a fluid resides in a nanoporous environments (pore size under 100 nm), the observed density, surface tension, and dielectric constant diverge from those measured in the bulk. To evaluate the impact of nano-scale confinement on the adsorption of copper (Cu²⁺), we performed batch adsorption studies using mesoporous silica. Mesoporous silica with the narrow distribution of pore diameters (SBA-15; 8, 6, and 4 nm pore diameters) was chosen since the silanol functional groups are typical to surface environments. Batch adsorption isotherms were fit with adsorption models (Langmuir, Freundlich, and Dubinin–Radushkevich) and adsorption kinetic data were fit to a pseudo-first-order reaction model. We found that with decreasing pore size, the maximum surface area-normalized uptake of Cu²⁺ increased. The pseudo-first-order kinetic model demonstrates that the adsorption is faster as the pore size decreases from 8 to 4 nm. We attribute these effects to the deviations in fundamental water properties as pore diameter decreases. In particular, these effects are most notable in SBA-15 with a 4-nm pore where the changes in water properties may be responsible for the enhanced Cu mobility, and therefore, faster Cu adsorption kinetics.     

Biomonitoring past salinity changes in an athalassic subarctic lake

A short sediment core was taken from a small saline lake located on an intermontane plateau in the central Yukon Territory, Canada. In July 1990, chemical analyses indicated that, although the lake was shallow (Z_max=1.1 m), it was also chemically stratified, with hyposaline (9.9 to 10.0 g L⁻¹) surface waters and slightly mesosaline (22.0 g L⁻¹) deeper waters. The surface water was dominated by Na⁺ and HCO ₃ ⁻ . To our knowledge, this is the northernmost athalassic saline lake yet recorded. Quantification of algal (diatom, chrysophyte, and pigment) and invertebrate (chironomid, ceratopogonid, andChaoborus) fossils at four stratigraphic levels indicated that the lake sediments preserved numerous biological indicators that could be used to infer recent lake development. Many of the taxa are found in other athalassic salt lakes. The most striking stratigraphic change was a remarkable drop in the species richness of diatoms and invertebrates in the recent sediments, which parallels the elimination of species characteristic of less saline conditions. Halophilous taxa dominate the most recent sediments, indicating the development of more saline conditions. At the same time, a significant shift in chrysophyte cyst composition was observed. Fossil carotenoids and chlorophylls indicated a decrease in total algal abundance in recent sediments, as green and blue-green algae replaced diatoms and chrysophytes. Together, these paleolimnological data suggest a recent shift to drier conditions or increased evaporation in the central Yukon Territory.