Synthesis and stability of iron nanoparticles for lunar environment studies

Abstract– Simulants of lunar dust are needed when researching the lunar environment. However, unlike the true lunar dust, today’s simulants do not contain nanophase iron. Two different processes have been developed to fabricate nanophase iron to be used as part of a lunar dust simulant. (1) The first is to sequentially treat a mixture of ferric chloride, fluorinated carbon, and soda lime glass beads at about 300 °C in nitrogen, at room temperature in air, and then at 1050 °C in nitrogen. The product includes glass beads that are gray in color, can be attracted by a magnet, and contains α‐iron nanoparticles (which seem to slowly lose their lattice structure in ambient air during a period of 12 months). This product may have some similarity to the lunar glassy agglutinate, which contains FeO. (2) The second is to heat a mixture of carbon black and a lunar simulant (a mixed metal oxide that includes iron oxide) at 1050 °C in nitrogen. This process simulates lunar dust reactions with the carbon in a micrometeorite at the time of impact. The product contains a chemically modified simulant that can be attracted by a magnet and has a surface layer whose iron concentration increased during the reaction. The iron was found to be α‐iron and Fe₃O₄ nanoparticles, which appear to grow after the fabrication process. This growth became undetectable after 6 months of ambient air storage, but may last for several years or longer.     

Interaction of a negatively buoyant line plume with a density interface

Laboratory experiments were carried out to investigate the interaction between turbulent line buoyant plumes and sharp density interfaces, with the aim of using the results to interpret oceanic observations pertinent to crack openings in the polar ice-cap (leads). These openings take the form of long narrow channels, and are often modeled as line bouyant plumes. The plumes descend as in a homogenoous fluid, impinge on the density interface, and then spread horizontally as gravity currents. Depending on the Richardson number , where Δb is the buoyancy jump across the interface, l_D is the half-width of the plume before the impingement and q₀is the buoyancy flux per unit length of the source, different flow patterns were identified. When Ri < 0.5, the plumes penetrate deep into the bottom layer, deflect horizontally and then spread while showing little vertical rise. When 0.6 < Ri < 5, the penetration is significant, but the fluid bounces back after entraining heavy fluid from the lower layer and then spreads horizontally above the interface as a gravity current. Appreciable mixing between this current and the lower layer was detected when Ri <1. When Ri > 10, the penetration was small and a sharp-nosed gravity current emerged some time after the impact. Measurements were made on the penetration depth, the velocities of the gravity current and the subsurface flow towards the plume, the entrainment rate and other wave parameters. Possible implications of the results for oceanic cases are also discussed.     

Computer simulation and modelling of mechanical properties of particulates

The mechanical properties of particulate systems are studied from a micromechanics point of view. Two approaches, namely, computer simulation and micro-structural continuum modelling are used. The computer simulation method is used to study the uniformity of the strain field and effect of particle rotations. These results are then used to evaluate the applicability of the micro-structural continuum model. Potential applications of the micro-structural continuum model in the study of mechanical properties of soils are discussed.     

Spatial variation of the evolution and structure of the urban boundary layer

The spatial variation of the nocturnal urban boundary-layer structure is described and the time variation of the mixing height, and the nocturnal inversion top and strength after sunrise is presented for urban sites located upwind, downwind, and near the center of the heat island, and at an upwind rural site. Observations were derived from high resolution temperature profiles obtained by a helicopter during 35 intensive morning experiments in St. Louis, Missouri.The nocturnal urban boundary layer increased in depth from the upwind edge of the urban area. Far downwind, in suburban and rural areas, a remnant of the urban boundary layer existed between a stable surface-based layer and an upper inversion that resembled the upwind rural inversion.The mixing height (base of the inversion) evolved in a parabolic manner after sunrise at the urban locations. A rise in the inversion top after sunrise at the urban locations is believed to be due to low-level convergence which caused the entire inversion layer to be lifted. Due to large horizontal temperature gradients associated with the urban heat island, cold air advection tended to counteract the urban-induced lifting effect by inhibiting mixing-height growth at urban locations upwind of the heat-island center. Advection also caused the maximum height and fastest growth rate of the urban mixed layer to be shifted downwind of the urban area with time. However, mean mixing-height growth rates at various urban locations did not differ significantly. The rural mixing-height growth rate was about twice as large as urban values for up to 3 hr after sunrise. Spatial differences in the mixing height became small near the time of inversion dissipation, which appeared to occur at about the same time at all locations.On assignment from the National Oceanic and Atmospheric Administration, U.S. Department of Commerce.     

Cyclic tests of steel plate shear walls using box‐shape vertical boundary elements with or without infill concrete

The steel plate shear wall (SPSW) is an effective lateral force resisting system in which unstiffened steel infill plates are connected to the horizontal and vertical boundary elements (VBEs) on all sides of the plates. The boundary elements must be designed to resist the tension field force of the infill panels. When the VBEs are made from a steel box section, the flange of each box VBE connected with the infill panels can be pulled out‐of‐plane by significant panel forces, called pull‐out action. This study investigates capacity design methods for box VBEs in SPSWs. Simplified fixed beam and portal frame models aim to estimate the pull‐out responses of the flange of the box sections with and without infill concrete, respectively. In this study, cyclic tests of three full‐scale two‐story SPSWs using box VBEs with or without the infill concrete are conducted. Inelastic pushover analyses of the finite element models are conducted. The tests and analytical results confirm that the proposed design methods, which aimed to prevent the full yield of the flange under the pull‐out action, are applicable. Furthermore, the test and analytical results suggest that the initial yielding of the flange of box VBEs under the collective effects of the pull‐out action on the flange, the gravity load, and the sway action on the SPSW represents a local yielding. A strict prohibition of the initial yielding on the flange under the aforementioned collective effects is not recommended for pursuing a cost‐effective design. Copyright © 2017 John Wiley & Sons, Ltd.     

Non‐uniqueness of critical state line in compression and extension conditions

Experimental evidence has indicated that the critical state line determined from undrained compression tests is not identical to that determined from undrained extension tests. The purpose of this paper is to investigate a modelling method that accounts for the non‐uniqueness of critical state lines in the compression and the extension testing conditions. Conventional elastic–plastic cap models can predict only a unique critical state line for the compression and the extension tests. A new micromechanical stress–strain model is developed considering explicitly the location of critical state line. The model is then used to simulate undrained triaxial compression and extension tests performed on isotropically consolidated samples with different over‐consolidated ratios. The predictions are compared with experimental results as well as that predicted by models with kinematic hardening of yield surface. All simulations demonstrate that the proposed micromechanical approach is capable of modelling the undrained compression and the undrained extension tests. Copyright © 2009 John Wiley & Sons, Ltd.     

Estimating inelastic sediment deformation from local site response simulations

Significant insight into the dynamic local site response of a horizontally layered sediment deposit to seismic excitation can be gained from numerical simulations. In this paper we use a nonlinear local site response analysis code SPECTRA to estimate the coseismic sediment deformation at a seismically active site in Lotung, Taiwan. We address some basic issues relevant for interpreting the simulation results, including the impact of noise and baseline offsets present in the input ground motion. We also consider the sensitivity of the predicted deformation responses to statistical variations of sediment constitutive properties. Finally, we apply a suite of hypothetical strong ground motions to the base of the sediment deposit to better understand the pattern of inelastic deformation likely to result from strong seismic shaking.     

DNA adduct formation and DNA strand breaks in green-lipped mussels (Perna viridis) exposed to benzo[a]pyrene: dose- and time-dependent relationships

Green-lipped mussels, Perna viridis, were exposed to 0, 0.3, 3 and 30 micrograms l-1 (nominal concentrations) B[a]P under laboratory conditions over a period of 24 days. Mussels were collected on day 0, 1, 3, 6, 12, 18 and 24, and the levels of DNA adducts and DNA strand breaks in their hepatopancreas tissues monitored. Mussels exposed to 0.3 and 3 micrograms l-1 B[a]P showed marked increases in strand breaks after 1 day of exposure. DNA strand break levels in these mussels remained high and significantly different from the control values until day 3 for the 0.3 microgram l-1 treatment group, and day 6 for the 3 micrograms l-1 treatment group. This was followed by a gradual reduction in strand breaks. After 12 days, the levels of both groups had returned to the same level as that of the control. No increase in DNA strand breaks was observable in mussels exposed to 30 micrograms l-1 B[a]P in the first 12 days of exposure, but a significant increase was observed from day 12 to day 24. Increasing B[a]P concentrations resulted in elevated DNA adduct levels after 3-6 days of exposure, but this pattern of dose-related increase disappeared after 12 days. These results indicate that a better understanding of the complex interactions between exposure levels and durations is crucially important before DNA adduct levels and DNA strand breaks in P. viridis can be used as effective biomarkers for monitoring genotoxicants in marine waters.     

Dating palaeo‐seismic faulting in the Taiwan Mountain Belt

In‐situ ⁴⁰Ar/³⁹Ar laser microprobe dating was carried out on the Hoping pseudotachylite from a mylonite‐fault zone in the metamorphosed basement complex of the active Taiwan Mountain Belt to determine the timing of the responsible earthquake(s). The dating results, distributed from 3.2 to 1.6 Ma with errors ranging from 0.2 to 1.1 Ma, were derived from a combination of two Ar isotopic system end‐members with inverse isochron ages of 1.55 ± 0.05 and 2.87 ± 0.07 Ma, respectively. Petrographical observations reveal fault melt containing ultracataclasites, therefore the older inverse isochron end‐member may be attributed to the relic wall rock Ar isotopic system contained in micro‐breccia. Without significant Ar loss expected, the ~1.6 Ma for the young end‐member defines the exact time of the pseudotachylite formation. Seismic faulting therefore occurred during basement rock exhumation in the Taiwanese hinterland.     

Estimating anisotropic aquifer parameters by artificial neural networks

In recent years, many approaches have been developed using the artificial neural networks (ANN) model incorporated with the Theis analytical solution to estimate the effective hydrological parameters for homogeneous and isotropic porous media, such as the Lin and Chen approach (ANN approach) and the principal component analysis (PCA)‐ANN approach. The above methods assume a full superimposition of the type curve and the observed drawdown and try to use the first time‐drawdown data as a match point to make a fine approximation of the effective parameters. However, using first time‐drawdown data or early time‐drawdown data does not always allow for an accurate estimation of the hydrological parameters, especially for heterogeneous and anisotropic aquifers. Therefore, this article corrects the concept of the superimposed plot by modifying the ANN approach and the PCA‐ANN approach, as well as incorporating the Papadopoulos analytical solution, to estimate the transmissivities and storage coefficient for anisotropic, homogeneous aquifers. The ANN model is trained with 4000 training sets of the well function, and tested with 1000 sets and 300 sets of synthetic time‐drawdown generated from the homogeneous and heterogeneous parameters, respectively. In situ observation data from the time‐drawdown at station Shi‐Chou on the Choushui River alluvial fan, Taiwan, is further adopted to test the applicability and reliability of the proposed methods, as well as provide a basis for comparison with the Straight‐line method and the Type‐curve method. Results suggest that both of the modified methods perform better than the original ones, and using late time‐drawdown to optimize the effective parameters is shown to be better than using early time‐drawdown. Additionally, results indicate that the modified ANN approach is better than the modified PCA‐ANN approach in terms of precision, while the efficiency of the modified PCA‐ANN approach is approximately three times better than that of the modified ANN approach. Copyright © 2010 John Wiley & Sons, Ltd.