Analysis of Karst Tufa from Guangxi, China

The paper presents an analysis of characteristic karst tufa from Guangxi, China, which has not been studied before. A comparison with tufa from Dinaric Karst of Croatia is discussed in view of the C-type climate. The major mineral is calcite. Minor minerals are quartz and dolomite, depending on location. The content of calcium carbonate varies from 65% to 92%, and that of magnesium carbonate from 0.03% to 1.77%. Among other elements, the most abundant are Fe, from 0.02% to 1.50%, and Ti, from 0.15% to 0.27%. Many other trace elements (V, Cr, Mn, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Hg and Pb) are also present. Specific activity of radionuclides 40K, 232Th, 137Cs, 226Ra and 238U varies from sample to sample. Concentration of U in tufa is close to that reported for sedimentary carbonate. Low concentration of 137Cs indicates that this part of the world was not exposed to nuclear explosions. The concentration of 226Ra is the highest in Mashan County. The ratio 238U/226Ra (0.21-0.71) in tufa from Mashan Co     

大别造山带地壳泊松比结构与超高压变质带—来自宽角反射与近垂直反射剖面的启示

综合宽角反射、近垂直反射的探测结果和有关地质资料，对大别造山带地壳结构和超高压变质带研究显示：大别造山带地壳具有层块结构特征。沿安义－庄墓剖面，上地壳有7个弹性块体，中地壳有5个，下地壳有4个。扬子与华北地块的主缝合带是超高压变质带，扬子地块与大别造山带的现今分界线是与郯庐断裂相交的太湖－马庙断裂，磨子潭－晓天断裂是大别造山带的北界，北淮阳构造带呈楔状向下插入，它与华北地块的分界是肥中断裂。郯庐断裂在中、上地壳近于直立，下地壳向西倾斜。超高压变质带的厚度为5－7km，产状向北插入到北大别块体之下，折返过程是构造就位，不是大别山的均匀抬升，折返的主运动面是水吼－五河高温剪切带。     

乐平统底界定义和点位的争论

有关乐平统底界定义和点位的争论涉及到有关建立界线层型的一些基本原则。本文作者确信,乐平统的底界不可能建立在小间断上或层序界面上;不能被证实的点断成种事件也不能用来建立界线层型;定义种在连续演化谱系中首现的点位是确定的不是任意的;必须考虑定义种的首现时期的居群特征,不能用定义种晚期的居群特征来确定GSSP的点位;定义种的定义不能任意改动,要保持分类的稳定。不能过高估计或只认为齿脊特征是区别晚二叠世舟刺分子的唯一标准。梅仕龙有关C. postbitteri和C. dukouensis两个种区别特征的争辩是无用的,因为本文作者所使用的区别这两个种的标准正是梅仕龙等(Mei et al, 1994)所提出的。现在没有必要为维护自己的界线定义或点位而修改有关种的定义。原来有关这两个种的定义和区别特征是科学的。本文作者鉴定的C. dukouensis (Wang, 2000a, p1. 2, figs. 1～8)是正确的,符合原来的定义。乐平统底界定义应当是严格的科学的。金玉玕等(Jin et al, 1994, 1998)从来没有提到更谈不上“反复讨论”了C. doukouensis的“首现”(梅仕龙,本期)。虽然提到(C. postbitteri的首现,但由于C. postbitteri的先驱种不清,这个定义是不科学的。乐平统底界的科学而严格的定义应是:在Clarkikina postbitteri—C. duk     

CO_2 Density-Raman Shift Relation Derived from Synthetic Inclusions in Fused Silica Capillaries and Its Application

Abstract: The densities of CO2 inclusions in minerals are commonly used to determine the crystallizing conditions of the host minerals. However, conventional microthermometry is difficult to apply for inclusions of small size (< 5–10 μm) or low density. Raman analysis is an alternative method for determining CO2 density, provided that the CO2 density–Raman shift relation is known. This study aims to establish this CO2 density–Raman shift relation by using CO2 inclusions synthesized in fused silica capillaries. By using this newly-developed synthetic technique, we formed pure CO2 inclusions, and their densities were determined by microthermometry. The Raman analysis showed that the relation between CO2 density (D in g/cm3) and the separations (Δ in cm?1) between the two main bands (i.e. Fermi diad bands) in CO2 Raman spectra can be represented by a cubic equation: D (g/cm3)=0.74203(?0.019Δ3+5.90332Δ2?610.79472Δ+21050.30165)?3.54278 (r2=0.99920). Our calculated D value for a given Δ is between those obtained from two previously-reported equations, which were derived from different experimental methods. An example was given in this study to demonstrate that the densities of natural CO2 inclusions that could not be derived from microthermometry could be determined by using our method.     

西太平洋海山磷酸盐的常量、微量和稀土元素地球化学研究

本文对主要取自于西太平洋我国调查区内不同海山、不同水深、不同产状的13个磷酸盐样品进行了常量、微量和稀土元素测定,以探讨与大洋富钴结壳密切伴生的磷酸盐的常、微量和稀土元素地球化学的特征。分析结果表明,调查区磷酸盐中主要氧化物的平均值与赤道太平洋的相近,暗示两者可能有相似的形成环境和形成机制。磷酸盐中微量元素Sr、Ba、Co、Cu、Ni及U丰度分别变化于862×10~(-6)～2181×10~(-6)、29×10~(-6)～3429×10~(-6)、6.3×10~(-6)～115×10~(-6)、23×10~(-6)～263×10~(-6)、12×10~(-6)～825×10~(-6)及4×10~(-6)～11×10~(-6),丰度多数低于泥质岩平均值,其CaO/P_2O_5、F/CO_2、Sr/P_2O_5值及常量、微量元素间的相关关系,清晰地显示了磷酸盐的种类、成分与结构、形成的地质背景和元素的主要组合特征。磷酸盐的稀土丰度为136.50×10~(-6)～853.70×10~(-6);Ce~*变化于0.01～0.18之间;(Ce/Yb)_N值变化于0.01～0.21之间。研究证实,不同产状磷酸盐的稀土元素配分模式基本一致,曲线相互平行,基本不呈现交叉现象,均呈Ce强烈亏损,轻、重稀土分馏程度大及重稀土富集的型式。调查区、赤道太平洋、中太平洋磷酸盐的稀土元素丰度、Ce~*、Ce/Yb值以及它们与海水稀土元素配分模式相似的特征,也进一步显     

水泥—丙烯酸盐复合浆液的实验性研究

水泥-丙烯酸盐复合浆液是在丙烯酸盐浆液的基础上研制出来的一种复合浆液，它既保留了丙烯酸盐浆液流动性好，固结体弹性好的优点，又大幅度地提高了浆液的抗压强度和粘结强度，因此在注浆时可以带来良好的综合灌注效果，还对复合浆液的粘度和强度进行了试验性研究。     

Researches on Plants from the Lower Devonian Xujiachong Formation in the Qujing District, Eastern Yunnan

Fossil plants Hedeia sinica Hao et Gensel 1998, Huia gracilis Wang et Hao 2001 and Guangnania cuneata Wang et Hao are described from the Lower Devonian Xujiachong Formation, the Qujing district, eastern Yunnan, China. They contribute to our knowledge of the flora in this district. Based on the occurrence of common plants (Hedeia, Huia, Guangnania and Zosterophyllum australianum) and their horizons, it is proved for the first time that the mid-lower assemblage of the Xujiachong flora is comparable with the Early Devonian ((late) Pragian) Posongchong flora of southeastern Yunnan and the upper Baragwanathia flora of Australia. In view of this fact and the stratigraphic sequence, the mid-lower part of the Xujiachong Formation is considered to be of (late) Pragian age. Through comprehensive analyses of plant, bivalve and fish assemblages and the lithology, the upper part of the Xujiachong Formation is dated to be of early Emsian age. The Xujiachong flora belonged to the northeastern Gondwana palaeophytogeogr     

柴达木北缘超高压变质带中的岛弧火山岩

青藏高原北部柴北缘发育一套与超高压变质带并行的早古生代岛弧火山岩带,岛弧火山岩以玄武岩类为主,包括一些中酸性岩类,岩石以普遍遭受绿片岩相蚀变为特征,区别于该地区普遍遭受角闪岩相区域变质的元古代的基性火山岩。该早古生代的岛孤火山岩显示三组地球化学特征:①VTG-Ⅰ,岛弧拉斑玄武岩(IAT);②VTG-Ⅱ,高Al次钙碱性-碱性过渡型玄武岩;③VTG-Ⅲ,较N-MORB更亏损的拉斑玄武岩(异常MORB)。研究认为前两组火山岩是成熟岛弧两个发育阶段的特征性产物:洋壳俯冲到陆壳的初用,由俯冲洋壳和地幔楔的部分熔融形成岛弧拉斑玄武岩(IAT),随着俯冲板块的速度加快和岛弧周围地壳的加厚,则形成钙碱性玄武岩(CA)、高Al玄武岩。第三组火山岩形成于弧间盆地,由亏损的地幔楔高度部分熔融形成比N-MORB亏损的的火山岩(异常MORB)。岛弧火山岩的锆石LA-ICP-MS法U-Pb年龄为514.2±8.5 Ma,说明柴北缘在早古生代发生过洋壳向陆壳的俯冲作用。鉴于该地区代表陆-陆俯冲作用的柴北缘超高压变质岩石也是形成于早古生代(494Ma),认为陆-陆俯冲作用发生在洋-陆俯冲作用之后,二者时间和空间相伴随。     

鄂尔多斯盆地奥陶系海相碳酸盐岩生烃性能与中部长庆气田气源成因研究

用激光 -荧光显微镜等有机岩石学方法 ,挑选样品中有明显生、排烃现象的碳酸盐岩 ,再以测定的这类碳酸盐岩的有机碳含量为依据 ,确定本区高成熟碳酸盐气源岩残余有机碳的下限指标用 0 .13%～ 0 .14 %比较合理。根据碳酸盐岩储层孔隙中充填沥青和皮膜状残余沥青的分布和含量 ,论证了陕参 1井等奥陶系碳酸盐岩地层在地质历史中 ,存在若干油气有效储层。采用连续升温 ,步进取样的热模拟实验方法 ,揭示了本区煤与碳酸盐岩干酪根随热演化作用增强 ,烃类气体产物的干燥系数增大 ,δ1 3C1 、δ1 3C2 明显变重的规律 ,并根据样品实验结果推算 ,本区石炭系—二叠系煤最大生气阶段的δ1 3C1 应为 - 2 7‰～ - 2 8‰ ,碳酸盐岩最大生气阶段的δ1 3C1 应为- 31.7‰～ - 33‰。在气源成因判识中 ,根据主生气期阶段对天然气成藏储聚的贡献最大、甲烷碳同位素较重以及长庆气田风化壳气藏天然气δ1 3C1 重值区并不与石炭系—二叠系煤的镜质组反射率高值区匹配的现象等进行气源判识 ,认为长庆奥陶系风化壳气藏 ,具有下古生界海相碳酸盐岩气与上古生界石炭系—二叠系煤成气的混源成因