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991.
Y. Hou X. Liu X. Zhang X. Chen K. Tao 《International Journal of Environmental Science and Technology》2016,13(3):887-896
The key components of S. triqueter root exudates involved 4-oxo-pentanoic acid, succinic acid, glutaric acid, phthalate acid, citric acid, vanillic acid, myristic acid, pentadecanoic acid, decanoic acid, 14-methyl-pentadecanoic acid, hexadecanoic acid, octadecanoic acid and oleic acid, and the content of the water-soluble organic acids (citric acid, succinic acid and glutaric acid) significantly increased in pyrene and lead co-contaminated rhizosphere soil. These three water-soluble organic acids including citric acid, succinic acid and glutaric acid were detected as the specific root exudates of S. triqueter under stress of pollutants for pyrene and lead, so they were chosen as the research objects, and they were added into the bioremediation systems of pyrene and lead co-contaminated wetland soils. Compared with the control, the treatments added the three organic acids always improved the quantity of the bioavailable fraction of pyrene and lead in wetland soils and greatly influenced other chemical states of pyrene and lead fractions in the test concentration range. Under the 50 g kg?1 of organic acids concentration, the amount of the bioavailable fraction of pyrene and lead increased 41.0 and 872.7 % by citric acid, respectively. The enhancement of bioavailability of pyrene and lead in the wetland soil by adding organic acids generally decreased in the following order: citric acid > succinic acid > glutaric acid. Enhancing effects of organic acids on the bioavailability improvement of pyrene and lead is remarkable. 相似文献
992.
C. Zhu X. Dong Z. Chen R. Naidu 《International Journal of Environmental Science and Technology》2016,13(5):1257-1268
Amorphous tin(VI) hydrogen phosphate (ATHP) was synthesized using the liquid phase precipitation method and served as an adsorbent to remove Pb(II), Cu(II), and Zn(II) from aqueous solutions. The ATHP was characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption–desorption techniques. Adsorption properties were evaluated as a function of pH, reaction time, concentration of reactants, and salinity. Their equilibrium adsorption data were modeled using Freundlich, Langmuir, and Dubinin–Kaganer–Radushkevich isotherms, respectively. The results revealed that adsorption equilibrium reached within 180 min. ATHP indicated good adsorption even below the pHZPC, and best adsorption at pH 5 for Pb(II) and Cu(II) and at pH 5.5 for Zn(II) was observed. Equilibrium data fitted better to the Langmuir model for Pb(II) and Cu(II) and fitted better to the Freundlich model for Zn(II). The saturated adsorption capacities deduced from the Langmuir model were 2.425, 1.801, and 0.600 mmol/g for Cu(II), Pb(II), and Zn(II), respectively, indicating an adsorption affinity order of Cu > Pb > Zn. There is a negative correlation between the concentration of NaCl and adsorption capacity of ATHP, yet ATHP still exhibited excellent adsorption having an adsorption capacity of 19.35, 15.16, 6.425 mg/g when the concentration of NaCl was 0.6 mol/L. The free energy (E) was 12.33, 10.70, and 14.74 kJ/mol for Pb(II), Cu(II), and Zn(II), respectively. An adsorption mechanism based on ion exchange between heavy metal ions and H+ in the ATHP is proposed. Furthermore, the used ATHP was regenerated by HCl solution and the adsorbent was used repeatedly. 相似文献
993.
Human-machine interactive visiting and fixed-route visiting are currently the main roaming modes in digital three-dimensional (3D) scenes. However, in general, when a person visits an attraction area, s/he does not follow a fixed path, but instead wander about according to his/her interests. Here, we propose a new roaming mode, called autonomic visiting. That is, in a digital 3D scene, a user selects several interest spots, then a route connecting these spots can be automatically determined and 3D scene can be seen along this route. This study presents a technical approach that enables the realization of autonomic visiting in 3D scenes. Firstly, Delaunay triangular meshes for the terrain in 3D scene are established. Secondly, a plane-growth algorithm and a line-connection algorithm are introduced to automatically mend the broken parts of these triangular meshes. Thirdly, the triangular meshes are then merged and differently weighted according to different layers. Finally, a progress-zone transmission algorithm is presented to optimal the shortest route, which is derived from A-Star (A*) algorithm. Digital 3D campus of Nanjing University, China, is taken as the experimental materials. The experimental results prove the effect of the proposed approach. 相似文献
994.
The cyclic tilt of a retaining wall induces a peculiar motion in the backfill (sand), which exhibits closed trajectories (eddies). In this paper, the motion of the backfill has been optically traced and analyzed by means of particle image velocimetry, also known as digital image correlation. The results are of importance for cyclically loaded structures (e.g, piles for off-shore structures) and can also serve to test numerical simulations of large deformation. 相似文献
995.
Yan Yang Tianhu Chen Ping Li Chengsong Qing Qiaoqin Xie Xinmin Zhan 《Environmental Earth Sciences》2016,75(3):205
Colloidal pyrite waste rocks (CPWR) which are mainly composed of colloidal pyrite and siderite widely deposit in sulfide mines in the middle and lower reaches of the Yangtze River belt, China, especially in Tongling City, Anhui Province, China. In this paper, a fixed-bed column was used to investigate the weathering and oxidation of CPWR and its role in immobilizing low-concentration Cu (10 mg L?1) under weakly acidic leach (pH = 5.0). The experimental results indicated that the breakthrough capacity was around 14.0 mg Cu g?1 CPWR when Cu2+ breakthrough concentration was 0.5 mg L?1. Sequential extraction of Cu and dithionite–citrate–bicarbonate extraction of free iron in the used CPWR after the column breakthrough indicated that Cu removal by CPWR consisted of the following processes: oxidation of pyrite and dissolution of siderite in CPWR, ferrous oxidation, and adsorption of Cu on ferric (hydr)oxides. This study shows the potential application of CPWR as an effective sorbent for the removal of low-concentration Cu from acid mine drainage. 相似文献
996.
997.
998.
Hongguang Jiang Xuecheng Bian Chong Cheng Yunmin Chen Renpeng Chen 《Acta Geotechnica》2016,11(2):231-242
Ballastless high-speed railways have dynamic performances that are quite different from those of conventional ballasted railways. The essential dynamic characteristics of high-speed railways due to passing train wheels, such as the cyclic effect, moving effect, and speed effect, were put forward and discussed. A full-scale accelerated railway testing platform for ballastless high-speed railways was proposed in this study. The feasibility of the sequential loading method in simulating train moving loads, and the boundary effect of the proposed physical model of ballastless railways, was investigated using three-dimensional finite element models. A full-scale physical model, 5 m long, 15 m wide, and 6 m high, was then established according to practical engineering design methods. Using a sequential loading system composed of eight high-performance hydraulic actuators, loads of a moving train with highest speed of 360 km/h were simulated. Preliminary experimental results of vibration velocities were presented and compared with field measurements of the Wuguang high-speed railway in China. Results showed that the experimental results coincided with the field measurements, demonstrating that the full-scale accelerated railway testing platform can simulate the process of a moving train and realistically reproduce the dynamic behaviors of ballastless high-speed railways. 相似文献
999.
1000.
Research on land use cover change (LUCC) has reached a mature stage and has formed a relatively complete scientific system. However, most studies analyzed the LUCC process from the view of land use types ignoring the integrality and systematicness of the land use system, which brought certain constraints to understanding the complexity and systematicness of land use process scientifically. Using the Modern Yellow River Delta (MYRD) of China as the study area, this research introduced the complex network analysis method to the study of the LUCC process by using 9 periods of land use data between 1976 and 2014 to build 8 stages of complex networks. The values of node degree, betweenness, changing proportions, and average shortest path in the networks were calculated to identify the key land use types, changing models of land use types, and the stability of land use system. Additionally, main parts of complex networks of the period from 1976 to 1995 and the period from 1995 to 2014 were selected to evaluate the changing characteristics of the LUCC process. The results indicated the area and proportion of natural wetland kept reducing, but the area and proportion of artificial wetland or non-wetland continued rising. The bare land, reed, bush, and cultivated land were the key land use types of the LUCC process. In the past 38 years, beach, bare land, reed and bush had been the output types, and the building land and salt pan had been the input types. The LUCC process has been a transfer process of natural wetland to artificial wetland and non-wetland in the past 38 years, which could be divided into land accretion process (1976 to 1995) and construction process (1995 to 2014). The land ecosystem was unstable for the period from 1990 to 2006. 相似文献