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631.
Geochemistry and occurrence of inorganic gas accumulations in Chinese sedimentary basins 总被引:15,自引:0,他引:15
Inorganic gases are commonly seen in eastern China and occasionally in southern China from the shallow water columns above hot and cold springs. The gases contain 68% to nearly 100% CO2, with δ13CCO2 and δ13C1 values in the range of −1.18‰ to −6.00‰ and −19.48‰ to −24.94‰, respectively. All of the 34 large inorganic CO2 and one inorganic methane accumulations discovered in China are distributed in eastern parts of the country, from both onshore and continental shelf basins. No commercial inorganic gas accumulation has been found in central and western China. This is a review of the occurrence and geochemical characteristics of inorganic gas accumulations in Chinese sedimentary basins. A detailed study of gas samples collected from four representative inorganic CO2 pools and one possible inorganic methane pool indicates that inorganic alkane gases typically show δ13C1 values greater than −10‰ versus PDB (mostly −30‰), with a positive stable carbon isotope sequence of δ13C1 < δ 13C2 < δ13C3 < δ 13C4. In contrast, the δ13C1 values of biogenic alkane gases are lighter than −30‰, with a negative isotope sequence (i.e. δ13C1 > δ13C2 > δ 13C3 > δ13C4). Inorganic gases also tend to show less negative δ13CCO2 values (−10‰) than biogenic gases (<−10‰). 相似文献
632.
Water soluble components of PM10 Chongqing, China 总被引:1,自引:0,他引:1
The concentrations of water soluble ions (Na+, NH4
+, K+, Mg2+, Ca2+, NO3
-, Cl-, and SO
4
2-
) in PM10 samples collected on cellulose filters by a medium-volume cascade impactor were determined, which were obtained from three
kinds of areas in Chongqing: industrial area (Jiulongpo district), commercial and residential area (Jiangbei district) and
background area (Jinyun Mountain in the Beibei district). The results showed that except for the background site, the annual
average values of PM10 are 23% – 61% higher than the national air quality standard (GradeII) (0.1 mg/m3), even that the value of the control site is still 20% higher than American standard (0.05 mg/m3). This implied that serious pollution of fine particles occurred in Chongqing. Nine kinds of soluble ions in water of PM10 were analyzed by ion chromatography (IC) and the annual average concentrations follow the order of [SO
4
2-
] > [NO3
-] > [Cl-] > [F-], and [Ca2+] > [NH4
+] > [K+] > [Na+] > [Mg2+]. Their values were different in these areas: the industrial area > the commercial and living area > the control area. As
for NH4
+, K+, Ca2+, NO3
- and SO
4
2-
, their seasonal average concentrations show a similar variation trend: the values in spring and fall were higher than those
in summer and winter. The seasonal average concentrations of [Cl-], [F-], [Na+] and [Mg2+] are much lower than those of other ions. However, the concentrations of [Na+] changed more greatly in different seasons than those of the other three ions. Correlation coefficients showed that the three
areas have been polluted by coal smoke and dust to different extents, while some local resources of pollution should be taken
into consideration as well. 相似文献
633.
Statistical and geostatistical features of streambed hydraulic conductivities in the Platte River, Nebraska 总被引:1,自引:0,他引:1
Xunhong Chen 《Environmental Geology》2005,48(6):693-701
This paper presents streambed hydraulic conductivities of the Platte River from south-central to eastern Nebraska. The hydraulic
conductivities were determined from river channels using permeameter tests. The vertical hydraulic conductivities (K
v
) from seven test sites along this river in south-central Nebraska belong to one statistical population. Its mean value is
40.2 m/d. However, the vertical hydraulic conductivities along four transects of the Ashland test site in eastern Nebraska
have lower mean values, are statistically different from the K
v
values in south-central Nebraska, and belong to two different populations with mean values of 20.7 and 9.1 m/d, respectively.
Finer sediments carried from the Loup River and Elkhorn River watersheds to the eastern reach of the Platte River lowers the
vertical hydraulic conductivity of the streambed. Correlation coefficients between water depth and K
v
values along a test transect indicates a positive correlation – a larger K
v
usually occurs in the part of channel with deeper water. Experimental variograms derived from the vertical hydraulic conductivities
for several transects across the channels of the Platte River show periodicity of spatial correlation, which likely result
from periodic variation of water depth across the channels. The sandy to gravelly streambed contains very local silt and clay
layers; spatially continuous low-permeability streambed was not observed in the river channels. The horizontal hydraulic conductivities
were larger than the vertical hydraulic conductivities for the same test locations. 相似文献
634.
Element mobility during pyrite weathering: implications for acid and heavy metal pollution at mining-impacted sites 总被引:1,自引:0,他引:1
Long Lu Rucheng Wang Fanrong Chen Jiyue Xue Peihua Zhang Jianjun Lu 《Environmental Geology》2005,49(1):82-89
Based on back scattered electron images and electron micro-probe analysis results, four alteration layers, including a transition layer, a reticulated ferric oxide layer, a nubby ferric oxide layer and a cellular ferric oxide layer, were identified in the naturally weathering products of pyrite. These layers represent a progressive alteration sequence of pyrite under weathering conditions. The cellular ferric oxide layer correlates with the strongest weathering phase and results from the dissolution of nubby ferric oxide by acidic porewater. Leaching coefficient was introduced to better express the response of element mobility to the degree of pyrite weathering. Its variation shows that the mobility of S, Co and Bi is stronger than As, Cu and Zn. Sulfur in pyrite is oxidized to sulfuric acid and sulfate that are basically released into to porewater, and heavy metals Co and Bi are evidently released by acid dissolution. As, Cu and Zn are enriched in ferric oxide by adsorption and by co-precipitation, but they would re-release to the environment via desorption or dissolution when porewater pH becomes low enough. Consequently, Co, Bi, As, Cu and Zn may pose a substantial impact on water quality. Considering that metal mobility and its concentration in mine waste are two important factors influencing heavy metal pollution at mining-impacted sites, Bi and Co are more important pollutants in this case. 相似文献
635.
Stacin Martin Chen Zhu Joseph Rule Robert Ford Yee Soong 《Geochimica et cosmochimica acta》2005,69(6):1543-1553
Experiments of Zn2+ and Fe3+ coprecipitation as a function of pH were conducted in the laboratory at ambient temperature and pressure. X-ray diffraction patterns of the coprecipitates show two broad peaks at 0.149 and 0.258 nm, which is consistent with published patterns for pure 2-line ferrihydrite. Zn2+ uptake occurred at pH ≥5 while Fe3+ precipitation occurred between pH 3 and 4, although both Zn2+ and Fe3+ were present in the same solution during the entire range of pH titration. High-resolution transmission electron microscopy shows that the coprecipitates are 2 to 6 nm sized single crystalline particles but aggregated to 50 to 400 nm sized clusters. Analytical electron microscopy indicated that the 5% atomic Zn with respect to Fe was homogeneously distributed. No segregated phases were found in the clusters or at single crystal edges, which is consistent with published extended X-ray absorption fine structure (EXAFS) results at similar Zn/(Zn + Fe) ratios. Hence, occlusion and surface precipitation may be excluded as possible coprecipitation mechanisms. The bulk solution Zn2+ sorption edge was fitted to both solid solution and generalized diffuse layer surface complexation models. However, a solid solution model is inconsistent with published EXAFS results that show tetrahedral polydentate Zn2+ complexes sharing apices with Fe3+octahedra. 相似文献
636.
In situ feldspar dissolution rates in an aquifer 总被引:1,自引:0,他引:1
Chen Zhu 《Geochimica et cosmochimica acta》2005,69(6):1435-1453
In situ silicate dissolution rates within the saturated Navajo sandstone, at Black Mesa, Arizona were determined from elemental fluxes in the aquifer. The mass transfer between groundwater and mineral matrix along flow paths was calculated from inverse mass balance modeling. The reaction time is bound by 14C-based travel time. BET surface areas were measured with N2 gas adsorption. Dissolution rates for K-feldspar and plagioclase are 10−19 and 10−16 mol (feldspar) m−2 s−1, respectively, which are ∼105 times slower than laboratory experiment-derived rates under similar pH and temperature but at far from equilibrium conditions. The rates obtained in this study are consistent with the slower field rates found in numerous watershed and soil profile studies. However, these rates are from saturated aquifers, overcoming some concerns on estimated rates from unsaturated systems. The Navajo sandstone is a quartz-sandstone with a relatively simple and well-studied hydrogeology, groundwater geochemistry, and lithology, a large number of groundwater analyses and 14C groundwater ages, groundwater residence times up to ∼37 ky, groundwater pH from ∼8 to 10, and temperature from ∼15 to 35°C. 相似文献
637.
Bin Chen 《Geochimica et cosmochimica acta》2005,69(22):5387-5388
638.
本文利用2001-2003年南极中山站175天全天空摄像机观测,对午后多重极光弧的出现率及其与Kp指数的关系进行了统计分析,结果表明午后多重极光弧出现率呈一单峰分布,最大发生率出现在1445UT(1645MLT),其位置在1500MLT极光热点(1300-1700MLT)近夜侧的部分。与地磁活动指数Kp的相关统计分析表明,Kp值为2-3之间时多重极光弧有较大的出现率,这说明中等地磁活动情形下午后多重极光弧有较高的出现率。事件分析表明多重极光弧的强度变化与地磁Pc5脉动具有较高的相关性,并且有类似的频谱特征,这说明午后多重极光弧可能与同时出现的Pc5地磁脉动有关。 相似文献
639.
640.
This paper presents a single‐domain boundary element method (BEM) for linear elastic fracture mechanics analysis in the two‐dimensional anisotropic material. In this formulation, the displacement integral equation is collocated on the un‐cracked boundary only, and the traction integral equation is collocated on one side of the crack surface only. A special crack‐tip element was introduced to capture exactly the crack‐tip behavior. A computer program with the FORTRAN language has been developed to effectively calculate the stress intensity factors of an anisotropic material. This BEM program has been verified having a good accuracy with the previous researches. Furthermore, by analyzing the different anisotropic degree cracks in a finite plate, we found that the stress intensity factors of crack tips had apparent influence by the geometry forms of cracks and media with different anisotropic degrees. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献