Evolution of a post-batholith dike swarm in central coastal Queensland, Australia: arc-front to backarc?

A swarm of felsic and mafic dikes cuts a Late Carboniferous–Permian batholith called the Urannah Suite in central coastal Queensland. Late Permian–Triassic westward thrusting (Hunter–Bowen Orogeny) exposed this mid-crustal Suite and the crosscutting dikes, thus enabling examination of dikes that range in age from syn- to post-batholithic. Although both mafic and felsic dikes have the same dominant northerly strike, field, geochronologic and geochemical examination reveal that the swarm is composite; felsic dikes are older (285 Ma) and geochemically and isotopically distinct from mafic dikes (273–229 Ma). Dike compositions are compared to those of the host plutonic rocks, and to volcanic rocks the same age as the dikes. Whereas the felsic (older) dikes are compositionally similar to their host granites (initial ⁸⁷Sr/⁸⁶Sr>0.7045), the mafic (younger) dikes are isotopically (Sr, Nd, Pb) less radiogenic. Moreover, several different types of mafic dikes are evident based on geochemistry; most of these have mixed characteristics in terms of tectonic classification. All but two dikes of basalt and basaltic andesite composition classify as ‘with-in plate' on Ti–Zr–Y tectonic classification plots. Many of the basalts have high TiO₂ contents (1.5–3.0 wt.%). Most of these have REE and spider diagram patterns like calc-alkaline tholeiites, the exceptions being a few alkali basalts recognized by their alkali content, and high Ti, Ce, Nb and Zr contents. When put into the context of all plutonic rocks in the area (late Paleozoic and Mesozoic), these dikes record a transition at 280 Ma, after which time, all magmatism in the region is less isotopically evolved (initial ⁸⁷Sr/⁸⁶Sr=0.7033–0.7044). A model of slab retreat and hinge movement to the east in the latest Permian explains the change of geochemical signature from arc-front to backarc at about 280 Ma.     

The PSCz catalogue

We present the catalogue, mask, redshift data and selection function for the PSC z survey of 15 411 IRAS galaxies across 84 per cent of the sky. Most of the IRAS data are taken from the Point Source Catalog, but this has been supplemented and corrected in various ways to improve the completeness and uniformity. We quantify the known imperfections in the catalogue, and we assess the overall uniformity, completeness and data quality. We find that overall the catalogue is complete and uniform to within a few per cent at high latitudes and 10 per cent at low latitudes. Ancillary information, access details, guidelines and caveats for using the catalogue are given.     

Paleokarst system development in the San Andres Formation, Permian Basin, revealed by seismic characterization

Paleokarst systems are one of the major factors resulting in carbonate reservoir heterogeneity and compartmentalization. Nevertheless, few effective workflows have been proposed to map the 3D distribution of such systems. We describe a detailed seismic characterization approach integrating core, well log and rock physics analysis, to reveal a complex subsurface paleokarst system in the San Andres Formation, Permian basin, West Texas. In the area of high volume production, the collapsed paleokarst system is characterized by irregularly developed crackle and fracture breccias, mosaic breccias and cave fillings in the Upper San Andres Formation, which are delineated using seismic acoustic impedance. Along the transition from platform to basin, the paleokarst system is marked by a linear collapse including sags and small vertical faults that are recognizable in seismic imaging. Production data indicates that tight paleokarst zones cause reservoir compartmentalization and influence fluid communication between wells. The complex paleokarst system development is explained using a carbonate platform hydrological model, an outcrop analogue similar to modern marine hydrological environments within carbonate islands. Our method of model development for complex subsurface paleokarst systems may be applicable to other paleoenvironments.     

Regional Be production rate calibration for the past 12 ka deduced from the radiocarbon-dated Grøtlandsura and Russenes rock avalanches at 69° N, Norway

Two rock avalanches in Troms County – the Grøtlandsura and Russenes – were selected as CRONUS-EU natural cosmogenic ¹⁰Be production-rate calibration sites because they (a) preserve large boulders that have been continuously exposed to cosmic irradiation since their emplacement; (b) contain boulders with abundant quartz phenocrysts and veins with low concentrations of naturally-occurring ⁹Be (typically < 1.5 ppb); and (c) have reliable minimum radiocarbon ages of 11,424 ± 108 cal yr BP and 10,942 ± 77 cal yr BP (1σ), respectively. Quartz samples (n = 6) from these two sites contained between 4.28 × 10⁴ and 5.06 × 10⁴ at ¹⁰Be/g using the 1.387 Myr ¹⁰Be half-life. Determination of these concentrations accounts for topographic and self-shielding, and effects on nuclide production due to isostatic rebound are shown to be negligible. Persistent, constant snow and moss cover cannot be proven, but if taken into consideration they may have reduced ¹⁰Be concentrations by 10%. Using the ¹⁰Be half-life of 1.387 Myr and the Stone scaling scheme, and accounting for snow- and moss-cover, we calculate an error-weighted mean total ¹⁰Be production rate of 4.12 ± 0.19 at/g/yr (1σ). A corresponding error-weighted mean spallogenic ¹⁰Be production rate is 3.96 ± 0.16 at/g/yr (1σ), respectively. These are in agreement within uncertainty with other ¹⁰Be production rates in the literature, but are significantly, statistically lower than the global average ¹⁰Be production rate. This research indicates, like other recent studies, that the production of cosmogenic ¹⁰Be in quartz is lower than previously established by other production-rate calibration projects. Similarly, our findings indicate that regional cosmogenic production rates should be used for determining exposure ages of landforms in order to increase the accuracy of those ages. As such, using the total ¹⁰Be production rate from our study, we determine an error-weighted mean surface-exposure age of a third rock avalanche in Troms County (the Hølen avalanche) to be 7.5 ± 0.3 kyr (1σ). This age suggests that the rock avalanche occurred shortly after the 8.2 kyr cooling event, just as the radiocarbon ages of the Grøtlandsura and Russenes avalanches confirm field evidence that those rock-slope failures occurred shortly after deglaciation.     

Timing and source constraints on the relationship between mafic and felsic intrusions in the Emeishan large igneous province

Several I- and A-type granite, syenite plutons and spatially associated, giant Fe-Ti-V deposit-bearing mafic-ultramafic layered intrusions occur in the Pan-Xi (Panzhihua-Xichang) area within the inner zone of the Emeishan large igneous province (ELIP). These complexes are interpreted to be related to the Emeishan mantle plume. We present LA-ICP-MS and SIMS zircon U-Pb ages and Hf-Nd isotopic compositions for the gabbros, syenites and granites from these complexes. The dating shows that the age of the felsic intrusive magmatism (256.2 ± 3.0-259.8 ± 1.6 Ma) is indistinguishable from that of the mafic intrusive magmatism (255.4 ± 3.1-259.5 ± 2.7 Ma) and represents the final phase of a continuous magmatic episode that lasted no more than 10 Myr. The upper gabbros in the mafic-ultramafic intrusions are generally more isotopically enriched (lower ε_Nd and ε_Hf) than the middle and lower gabbros, suggesting that the upper gabbros have experienced a higher level of crustal contamination than the lower gabbros. The significantly positive ε_Hf(t) values of the A-type granites and syenites (+4.9 to +10.8) are higher than those of the upper gabbros of the associated mafic intrusion, which shows that they cannot be derived by fractional crystallization of these bodies. They are however identical to those of the mafic enclaves (+7.0 to +11.4) and middle and lower gabbros, implying that they are cogenetic. We suggest that they were generated by fractionation of large-volume, plume-related basaltic magmas that ponded deep in the crust. The deep-seated magma chamber erupted in two stages: the first near a density minimum in the basaltic fractionation trend and the second during the final stage of fractionation when the magma was a low density Fe-poor, Si-rich felsic magma. The basaltic magmas emplaced in the shallow-level magma chambers differentiated to form mafic-ultramafic layered intrusions accompanied by a small amount of crustal assimilation through roof melting. Evolved A-type granites (synenites and syenodiorites) were produced dominantly by crystallization in the deep crustal magma chamber. In contrast, the I-type granites have negative ε_Nd(t) [−6.3 to −7.5] and ε_Hf(t) [−1.3 to −6.7] values, with the Nd model ages () of 1.63−1.67 Ga and Hf model ages () of 1.56−1.58 Ga, suggesting that they were mainly derived from partial melting of Mesoproterozoic crust. In combination with previous studies, this study also shows that plume activity not only gave rise to reworking of ancient crust, but also significant growth of juvenile crust in the center of the ELIP.     

Mechanisms controlling silicon isotope distribution in the Eastern Equatorial Pacific

The distribution of silicon isotopes along a meridional transect at 140°W longitude in the Eastern Equatorial Pacific was used to test the hypothesis that δ³⁰Si of silicic acid in surface waters should correlate with net silica production rates (gross silica production minus silica dissolution) rather than rates of gross silica production due to the opposing Si isotope fractionations associated with silica production and silica dissolution. Variations in δ³⁰Si appeared significantly correlated with net silica production rates in equatorial surface waters and not with gross production rates. Around the Equator, values of δ³⁰Si as low as deep water values occurred in the upper mesopelagic in a zone of net silica dissolution and high detrital biogenic silica content, where the release of low δ³⁰Si silicic acid from opal dissolution would be expected to decrease δ³⁰Si. The δ³⁰Si of the deep water at 140°W appears constant for depths >2000 m and is similar to the deep water at 110°W. This study brings to light the importance of considering Si fractionation during diatom silica dissolution, the biological fractionation during silica production and physical factors such as currents and mixing with adjacent water masses when interpreting silicon isotope distributions.     

Tectonostratigraphic evolution of the Labrador margin, Atlantic Canada

The Labrador continental margin provides a rich source of data with which to study the relationships between stratigraphy, tectonics and paleoenvironment. We have completed a regional seismic interpretation and integrated this with new biostratigraphic data, based on analyses of palynomorphs from wells in the Hopedale and Saglek Basins which occur on this margin. Our results are summarized in a tectonostratigraphic chart, which displays new and consistent age control for the major lithostratigraphic units and provides more precise evaluation of their depositional and paleoenvironmental history. We have identified and dated six regional unconformities in the wells and we can recognize several others on the seismic data. The older unconformities (Cretaceous) are related to the tectonics of rifting and seafloor spreading, and may delineate the onset of different stages of the rift process. In the Paleocene-Early Eocene, unconformity development was influenced by episodic volcanism due to the passage of the proto-Iceland hotspot to the north and to a major change in spreading direction in the Labrador Sea. Many of these unconformities are also identified in offshore southwest Greenland and the Grand Banks, suggesting widespread controlling mechanisms. During the post-seafloor spreading stage the effects of mass wasting and slumping, and of paleoenvironmental controls on the stratigraphy, were more pronounced. We discuss the petroleum potential of the Hopedale Basin in terms of the structures we see on the seismic data, and highlight the Bjarni Formation, which likely contains the most prospective source and reservoir rocks in this Basin.     

Regions of Potential Existence of Free Water (Ice) in the Near-Surface Martian Ground: Results from theMars OdysseyHigh-Energy Neutron Detector (HEND)

We report results of the analysis of the data on global mapping of neutron fluxes from the Martian surface, which have been obtained during the first ten months of measurements carried out by the Russian high-energy neutron detector HEND mounted aboard the AmericanMars Odysseyorbiter. This analysis allowed us to separate regions where free water (in ice form) prevailed in the surface layer (with a thickness of up to 2 m) of the Martian ground from regions where physically and chemically bound ground water was most likely to be the dominant form of water. The global mapping of regions with increased ice content in the ground-surface layer revealed a direct correlation with regions of polygonal terrains morphologically similar to terrestrial polygonal forms of permafrost origin. The potential content of bound water forms in the ground of circumpolar areas of the planet is also estimated.     

Search for Traces of Chemically Bound Water in the Martian Surface Layer Based on HEND Measurements onboard the 2001 Mars Odyssey Spacecraft

Analysis of the distribution of the epithermal and fast neutron fluxes from the Martian surface within the ±60° latitude zone measured by the High-Energy Neutron Detector (HEND) from mid-February through mid-June 2002 has revealed regional neutron-flux variations outside the zones of climatic effects, which appear to be attributable to the presence of chemically bound water. With the exception of the epithermal neutron fluxes in Arabia and southwest of Olympus Mons (Medusae Fossae), these variations show no correlation with the geologic structure of the terrain at the level of global geologic maps. The lack of such a correlation probably implies that to the formation depth of the epithermal neutron flux (1–2 m), let alone the fast neutron flux (20–30 cm), much of Mars is covered by a surface material that bears little relation in composition to local bedrocks. Clearly, this is an aeolian cover whose fine-grain component was mixed by dust storms in the geologic time on the scale of large regions. The decrease in the flux of epithermal neutrons in Arabia and southwest of Olympus Mons (Medusae Fossae) appears to be attributable to an enhanced concentration of materials containing chemically bound water (clay minerals, palagonite, hydroxides, and hydrosalts) in the surface layers of these regions.