Response of surface water chemistry to reduced levels of acid precipitation: comparison of trends in two regions of New York,USA

In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984–2001 and 1992–2001) and surface water chemistry (1992–2001) were determined in two of the most acid‐sensitive regions of North America, i.e. the Catskill and Adirondack Mountains of New York. Precipitation chemistry data from six sites located near these regions showed decreasing sulphate (SO₄^2?), nitrate (NO₃^?), and base cation (C_B) concentrations and increasing pH during 1984–2001, but few significant trends during 1992–2001. Data from five Catskill streams and 12 Adirondack lakes showed decreasing trends in SO₄^2? concentrations at all sites, and decreasing trends in NO₃^?, C_B, and H⁺ concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid‐neutralizing capacity (ANC) increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO₄^2? trends, but it caused several significant non‐flow‐corrected trends in NO₃^? and ANC to become non‐significant, suggesting that trend results for flow‐sensitive constituents are affected by flow‐related climate variation. SO₄^2? concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation–surface water comparisons, reflecting a strong link between S emissions, precipitation SO₄^2? concentrations, and the processes that affect S cycling within these regions. NO₃^? and H⁺ concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation–surface water comparisons, indicating that variation in local‐scale processes driven by factors such as climate are affecting trends in acid–base chemistry in these two regions. Copyright © 2005 John Wiley & Sons, Ltd.     

Impact‐induced microbial endolithic habitats

Abstract— Asteroid and comet impacts on Earth are commonly viewed as agents of ecosystem destruction, be it on local or global scales. However, for some microbial communities, impacts may represent an opportunity for habitat formation as some substrates are rendered more suitable for colonization when processed by impacts. We describe how heavily shocked gneissic crystalline basement rocks exposed at the Haughton impact structure, Devon Island, Nunavut, Arctic Canada, are hosts to endolithic photosynthetic microorganisms in significantly greater abundance than lesser‐shocked or unshocked gneisses. Two factors contribute to this enhancement: (a) increased porosity due to impact fracturing and differential mineral vaporization, and (b) increased translucence due to the selective vaporization of opaque mineral phases. Using biological ultraviolet radiation dosimetry, and by measuring the concentrations of photoprotective compounds, we demonstrate that a covering of 0.8 mm of shocked gneiss can provide substantial protection from ultraviolet radiation, reducing the inactivation of Bacillus subtilis spores by 2 orders of magnitude. The colonisation of the shocked habitat represents a potential mechanism for pioneer microorganisms to invade an impact structure in the earliest stages of post‐impact primary succession. The communities are analogous to the endolithic communities associated with sedimentary rocks in Antarctica, but because they occur in shocked crystalline rocks, they illustrate a mechanism for the creation of microbial habitats on planetary surfaces that do not have exposed sedimentary units. This might have been the case on early Earth. The data have implications for the microhabitats in which biological signatures might be sought on Mars.     

Geological overview and cratering model for the Haughton impact structure,Devon Island,Canadian High Arctic

Abstract— The Haughton impact structure has been the focus of systematic, multi‐disciplinary field and laboratory research activities over the past several years. Regional geological mapping has refined the sedimentary target stratigraphy and constrained the thickness of the sedimentary sequence at the time of impact to ?1880 m. New ⁴⁰Ar–³⁹Ar dates place the impact event at ?39 Ma, in the late Eocene. Haughton has an apparent crater diameter of ?23 km, with an estimated rim (final crater) diameter of ?16 km. The structure lacks a central topographic peak or peak ring, which is unusual for craters of this size. Geological mapping and sampling reveals that a series of different impactites are present at Haughton. The volumetrically dominant crater‐fill impact melt breccias contain a calcite‐anhydrite‐silicate glass groundmass, all of which have been shown to represent impact‐generated melt phases. These impactites are, therefore, stratigraphically and genetically equivalent to coherent impact melt rocks present in craters developed in crystalline targets. The crater‐fill impactites provided a heat source that drove a post‐impact hydrothermal system. During this time, Haughton would have represented a transient, warm, wet microbial oasis. A subsequent episode of erosion, during which time substantial amounts of impactites were removed, was followed by the deposition of intra‐crater lacustrine sediments of the Haughton Formation during the Miocene. Present‐day intra‐crater lakes and ponds preserve a detailed paleoenvironmental record dating back to the last glaciation in the High Arctic. Modern modification of the landscape is dominated by seasonal regional glacial and niveal melting, and local periglacial processes. The impact processing of target materials improved the opportunities for colonization and has provided several present‐day habitats suitable for microbial life that otherwise do not exist in the surrounding terrain.     

The Convergence of Newton–Raphson Iteration with Kepler's Equation

Conway (Celest. Mech. 39, 199–211, 1986) drew attention to the circumstance that when the Newton–Raphson algorithm is applied to Kepler's equation for very high eccentricities there are certain apparently capricious and random values of the eccentricity and mean anomaly for which convergence seems not to be easily reached when the starting guess for the eccentric anomaly is taken to be equal to the mean anomaly. We examine this chaotic behavior and show that rapid convergence is always reached if the first guess for the eccentric anomaly is π. We present graphs and an empirical formula for obtaining an even better first guess. We also examine an unstable situation where iterations oscillate between two in correct results until the instability results in sudden convergence to the unique correct solution. This revised version was published online in July 2006 with corrections to the Cover Date.     

XMM–Newton observations of UW CrB: detection of X-ray bursts and evidence for accretion disc evolution

UW CrB (MS 1603+2600) is a peculiar short-period X-ray binary that exhibits extraordinary optical behaviour. The shape of the optical light curve of the system changes drastically from night to night, without any changes in overall brightness. Here we report X-ray observations of UW CrB obtained with XMM–Newton . We find evidence for several X-ray bursts, confirming a neutron star primary. This considerably strengthens the case that UW CrB is an accretion disc corona system located at a distance of at least 5–7 kpc (3–5 kpc above the Galactic plane). The X-ray and Optical Monitor (ultraviolet–optical) light curves show remarkable shape variation from one observing run to another, which we suggest are due to large-scale variations in the accretion disc shape resulting from a warp that periodically obscures the optical and soft X-ray emission. This is also supported by the changes in phase-resolved X-ray spectra.     

Models of Very-High-Energy Gamma-Ray Emission from the Jets of Microquasars: Orbital Modulation

The recent detection of very-high-energy (GeV – TeV) γ-ray emission from the Galactic black-hole candidate and microquasar LS 5039 has sparked renewed interest in jet models for the high-energy emission in those objects. In this work, we have focused on models in which the high-energy emission results from synchrotron and Compton emission by relativistic electrons in the jet (leptonic jet models). Particular attention has been paid to a possible orbital modulation of the high-energy emission due to azimuthal asymmetries caused by the presence of the companion star. Both orbital-phase dependentγγ absorption and Compton scattering of optical/UV photons from the companion star may lead to an orbital modulation of the gamma-ray emission. We make specific predictions which should be testable with refined data from HESS and the upcoming GLAST mission.     

THE IMPORTANCE OF NONEMPLOYMENT SOURCES OF INCOME IN CANADIAN METROPOLITAN AREAS*

The use of nonemployment sources of income as a supplement to labor force data in the determination of the urban economic base was investigated for major Canadian cities. It was found that investment and pension-government, the main nonemployment sources, were of increasing importance and that the cities, with one exception, were differentiated into two groups, one based more strongly on investment and the other on pension-government income.     

Factors affecting the elimination of PCBs in the marine copepod Acartia tonsa

The effects of feeding, egg laying, and fecal pellet production on the elimination of polychlorinated biphenyls (PCBs) from the marine copepod Acartia tonsa were studied in a series of experiments. Copepods were exposed to ¹⁴C-labelled Aroclor 1254 and allowed to depurate in clean seawater. Copepods fed during depuration eliminated PCBs more rapidly than unfed copepods whether or not the original PCB exposure medium had contained food. Both eggs and fecal pellets contained PCBs during depuration, with the weight specific concentration of PCB in the eggs (up to 407 ppm, dry weight) exceeding four times that in the females that produced them. Female copepods eliminated PCBs twice as rapidly as males, indicating that egg production is an important route for PCB elimination.