Comparison between satellite and in situ sea surface temperature data in the Western Mediterranean Sea

A comparison between in situ and satellite sea surface temperature (SST) is presented for the Western Mediterranean Sea during 1999. Several international databases are used to extract in situ data (World Ocean Database, MEDAR/Medatlas, Coriolis Data Center, International Council for the Exploration of the Sea and International Comprehensive Ocean-Atmosphere Data Set). The in situ data are classified into different platforms or sensors (conductivity–temperature–depth, expendable bathythermographs, drifters, bottles, and ships), in order to assess the relative accuracy of these type of data with respect to Advanced Very High Resolution Radiometer SST satellite data. It is shown that the results of the error assessment vary with the sensor type, the depth of the in situ measurements, and the database used. Ship data are the most heterogeneous data set, and therefore present the largest differences with respect to in situ data. A cold bias is detected in drifter data. The differences between satellite and in situ data are not normally distributed. However, several analysis techniques, as merging and data assimilation, usually require Gaussian-distributed errors. The statistics obtained during this study will be used in future work to merge the in situ and satellite data sets into one unique estimation of the SST.     

Geology,geochemistry and mineralogy of the lignite-hosted Ambassador palaeochannel uranium and multi-element deposit,Gunbarrel Basin,Western Australia

The Ambassador U and multi-element deposit occurs on the SW margin of the Gunbarrel Basin, Western Australia. Low-grade, flat-lying U mineralization averaging about 2 m thick at 0.03% U occurs in lignites at the redox front at the base of the weathering profile within a laterally extensive palaeochannel network. Uranium is principally associated with organic matter within the lignitic matrix, although rare discrete U minerals, such as coffinite and uraninite, are also present. The lignite is also enriched in a suite of other elements, principally base metals and sulphur, with concentrations of 0.3 ≥ 1% Cu, Pb, Ni, Co, Zn and total rare earth elements (REE) in some samples. Other element enrichments include: Cr, Cs, Sc, Se, Ta, Ti, Th, V and Zr as detrital heavy minerals of Zr, Ti and REE (oxides and silicates) or authigenic minerals of Cu, Bi, Pb, Zn, Ni, Se, Hg, Ti, Cr, Tl, V, U and REE (sulphides, vanadates, selenides, oxides, chlorides and native metals) and diffuse lignite impregnations. The Ambassador deposit probably formed from the convergence of redox-active weathering processes to unique source/host rocks, constrained within the palaeochannel. A proximal source of U and trace elements of lamproite/carbonatite origin is probable, as constrained by U–Pb isotope and U–Th disequilibria studies. Uranium and other metals were precipitated syngenetically with organic matter as it was deposited during a humid phase in the Late Eocene. Remobilization subsequently concentrated the metals in the upper 2 m of the lignite. This may have occurred during one or more periods of weathering and associated diagenesis, with the latest episode in the last 300,000 years.     

Arsenic and trace metal contents in sediment profiles from the Admiralty Bay, King George Island, Antarctica

Admiralty Bay (Antarctica) hosts three scientific stations (Ferraz, Arctowski and Macchu Picchu), which require the use of fossil fuel as an energy source. Fossil fuels are also considered the main source of pollution in the area, representing important inputs of major pollutants (organic compounds) and trace metals and metalloids of environmental interest. Accordingly, this work presents the results of As, Cd, Cr, Cu, Ni, Pb and Zn in sediment profiles from Admiralty Bay. The sediment results from Ferraz station were slightly higher than the other sampling sites. The highest contents were observed for Cu and Zn (from 44 to 89 mg kg⁻¹). Otherwise, by using enrichment factors and geochronology analysis, the most relevant enrichment was observed for As in the samples collected close to the Ferraz station, indicating that increasing As content may be associated with the activities associated with this site.     

Harmful algal bloom species and phosphate-processing effluent: field and laboratory studies

In 2002, the Florida Department of Environmental Protection began discharging phosphate-processing effluent into Bishop Harbor, an estuary within Tampa Bay. Because of concerns that the effluent would serve as a nutrient source for blooms of the toxic dinoflagellate Karenia brevis, a field monitoring program was established and laboratory bioassays were conducted. Several harmful algal bloom (HAB) species, including Prorocentrum minimum and Heterosigma akashiwo, were observed in bloom concentrations adjacent to the effluent discharge site. Blooms of diatoms were widespread throughout Bishop Harbor. K. brevis was observed with cell concentrations decreasing with increasing proximity to the effluent discharge site. Bioassays using effluent as a nutrient source for K. brevis resulted in decreased cell yields, increased growth rates, and increased time to log-phase growth. The responses of HAB species within Bishop Harbor and of K. brevis to effluent in bioassays suggested that HAB species differ in their response to phosphate-processing effluent.     

大地震与全球地震台网

引言 地震学家经常开玩笑说,＂阻止地震的最好办法就是布设地震台站。＂为了记录地震信号或开展有针对性的有关地球结构的研究就需要布设地震仪,而地震的发生往往是变幻莫测的,在时间和空间上都绝对是非均匀的,所以安装地震仪的辛苦有时会徒劳无功。     

A fast algorithm for finding the first intersection with a non-convex yield surface

A major task in the numerical modelling of soils using complex elastoplastic material models is stress updating. This paper proposes a fast and robust numerical algorithm for locating the first intersection between a non-convex yield surface and an elastic trial stress path. The intersection problem is cast into a problem of finding the smallest positive root of a nonlinear function. Such a function may have multiple roots within the interval of interest. The method is based on the modified Steffensen method, with important modifications to address the issues arising from the non-convexity. Numerical examples demonstrate that the proposed M² Steffensen method is indeed computationally efficient and robust.     

Tephrochronology,magnetostratigraphy and mammalian faunas of Middle and Early Pleistocene sediments at two sites on the Old Crow River,northern Yukon Territory,Canada

Alluvial and lacustrine sediments exposed beneath late Pleistocene glaciolacustrine silt and clay at two sites along the Old Crow River, northern Yukon Territory, are rich in fossils and contain tephra beds. Surprise Creek tephra (SZt) occurs in the lower part of the alluvial sequence at CRH47 and Little Timber tephra (LTt) is present near the base of the exposure at CRH94. Surprise Creek tephra has a glass fission-track age of 0.17 ± 0.07 Ma and Little Timber tephra is 1.37 ± 0.12 Ma. All sediments at CRH47 have a normal remanent magnetic polarity and those near LTt at CRH94 have a reversed polarity — in agreement with the geomagnetic time scale. Small mammal remains from sediments near LTt support an Early Pleistocene age but the chronology is not so clear at CRH47 because of the large error associated with the SZt age determination. Tephrochronological and paleomagnetic considerations point to an MIS 7 age for the interglacial beds just below SZt at CRH47 and at Chester Bluffs in east-central Alaska, but mammalian fossils recovered from sediments close to SZt suggest a late Irvingtonian age, therefore older than MIS 7. Further studies are needed to resolve this problem.     

Nature and degree of aqueous alteration in CM and CI carbonaceous chondrites

We investigated the petrologic, geochemical, and spectral parameters that relate to the type and degree of aqueous alteration in nine CM chondrites and one CI (Ivuna) carbonaceous chondrite. Our underlying hypothesis is that the position and shape of the 3 μm band is diagnostic of phyllosilicate mineralogy. We measured reflectance spectra of the chondrites under dry conditions (elevated temperatures) and vacuum (10^?8 to 10^?7 torr) to minimize adsorbed water and mimic the space environment, for subsequent comparison with reflectance spectra of asteroids. We have identified three spectral CM groups in addition to Ivuna. “Group 1,” the least altered group as determined from various alteration indices, is characterized by 3 μm band centers at longer wavelengths, and is consistent with cronstedtite (Fe‐serpentine). “Group 3,” the most altered group, is characterized by 3 μm band centers at shorter wavelengths and is consistent with antigorite (serpentine). “Group 2” is an intermediate group between group 1 and 3. Ivuna exhibits a unique spectrum that is distinct from the CM meteorites and is consistent with lizardite and chrysotile (serpentine). The petrologic and geochemical parameters, which were determined using electron microprobe analyses and microscopic observations, are found to be consistent with the three spectral groups. These results indicate that the distinct parent body aqueous alteration environments experienced by these carbonaceous chondrites can be distinguished using reflectance spectroscopy. High‐quality ground‐based telescopic observations of Main Belt asteroids can be expected to reveal not just whether an asteroid is hydrated, but also details of the alteration state.     

A petrogenetic model for the comagmatic origin of chassignites and nakhlites: Inferences from chlorine‐rich minerals,petrology, and geochemistry

Twelve samples belonging to the chassignite and nakhlite subgroups of Martian meteorites were investigated using a variety of micro‐beam analytical techniques to gain insight into the petrogenesis of these two meteorite classes. There are a striking number of geochemical similarities between the chassignites and nakhlites, including mineralogy and petrology, crystallization age, cosmic‐ray exposure age, and radiogenic isotopic compositions. However, there are also geochemical differences, namely in trace element systematics of pyroxenes, that have led some authors to conclude that the nakhlites are comagmatic with each other, but not comagmatic with the chassignites. On the basis of data presented here, we propose a model in which these differences can be reconciled by the addition of an exogenous Cl‐rich fluid to the chassignite‐nakhlite magma body shortly after the formation of the cumulate horizon that was sampled by the Chassigny meteorite. This model is supported by the textural and chemical associations of the volatile‐bearing minerals apatite, amphibole, and biotite, which record a history starting with the addition of a Cl‐ and LREE‐enriched fluid to the magma body. As the magma continued to crystallize, it eventually reached chloride saturation and degassed a Cl‐rich fluid phase. Depending on the provenance of the Cl‐rich fluid, this model could explain how the chassignites and nakhlites originated from an LREE‐depleted source, yet all exhibit LREE‐enriched bulk‐rock patterns. Additionally, the model explains the range in oxygen fugacity that is recorded by the chassignites and nakhlites because eventual exsolution and loss of Cl‐rich fluid phases near the end of crystallization of the nakhlite sequence leads to auto‐oxidation of the magma body due to the preferential partitioning of Fe²⁺ into the fluid phase.