Abundance and Chemical Speciation of Phosphorus in Sediments of the Mackenzie River Delta, the Chukchi Sea and the Bering Sea: Importance of Detrital Apatite

Utilizing a sequential extraction technique this study provides the first quantitative analysis on the abundance of sedimentary phosphorus and its partitioning between chemically distinguishable phases in sediments of the Bering Sea, the Chukchi Sea and the Mackenzie River Delta in the western Arctic Ocean. Total sedimentary phosphorus (TSP) was fractionated into five operationally defined phases: (1) adsorbed inorganic and exchangeable organic phosphorus, (2) Fe-bound inorganic phosphorus, (3) authigenic carbonate fluorapatite, biogenic apatite and calcium carbonate-bound inorganic and organic phosphorus, (4) detrital apatite, and (5) refractory organic phosphorus. TSP concentrations in surface sediments increased from the Chukchi Sea (18 μmol g⁻¹ of dried sediments) to the Bering Sea (22 μmol g⁻¹) and to the Mackenzie River Delta (29 μmol g⁻¹). Among the five pools, detrital apatite phosphorus of igneous or metamorphic origin represents the largest fraction (~43%) of TSP. The second largest pool is the authigenic carbonate fluorapatite, biogenic apatite as well as CaCO₃ associated phosphorus (~24% of TSP), followed by the Fe-bound inorganic phosphorus, representing ~20% of TSP. The refractory organic P accounts for ~10% of TSP and the readily exchangeable adsorbed P accounts for only 3.5% of TSP. Inorganic phosphorus dominates all of phosphorus pools, accounting for an average of 87% of the TSP. Relatively high sedimentary organic carbon and total nitrogen contents and low δ¹³C values in the Mackenzie River Delta together with the dominance of detrital apatite in the TSP demonstrate the importance of riverine inputs in governing the abundance and speciation of sedimentary phosphorus in the Arctic coastal sediments.     

Blue Crab (<Emphasis Type="Italic">Callinectes sapidus</Emphasis> Rathbun, 1896) Settlement at Three Georgia (USA) Estuarine Sites

The blue crab, Callinectes sapidus Rathbun, 1896, represents the second most important fishery for coastal Georgia; yet, little is known about environmental forces that affect planktonic postlarval settlement in the region. Here, we describe a study to examine the physical mechanisms responsible for blue crab settlement in the extensive salt marsh system of coastal Georgia. Bottom and surface samplers were placed at three sites along a salinity gradient from a low-salinity site in the Altamaha River to a high-salinity area of the Duplin River, Sapelo Island, GA, USA during 2005. Megalopae and juvenile monitoring occurred from July through December. The majority of both megalopae (86.8%) and juvenile (89.3%) blue crabs were recovered in bottom samplers at the low-salinity Altamaha River site during August and early September. Few megalopae were collected at the surface of the Altamaha River or at the two higher-salinity sites in the Duplin and North Rivers. Downwelling winds were unable to explain all settlement events; however, winds with an onshore component regularly preceded settlement events. The use of a multiple-regression model revealed a lagged relationship (r = 0.5461, $ lag = 0–2 days $ lag = 0–2 days ) between wind events, temperature, salinity, maximum tidal height, and settlement.     

Effects of Shoreline Modifications on Supratidal Macroinvertebrate Fauna on Puget Sound,Washington Beaches

In coastal environments, the supratidal zone bridges marine and terrestrial ecosystems and is important for energy exchange. However, it is also subject to extensive anthropogenic disturbance, such as armoring of shorelines. Shoreline armoring is extensive along many coasts, but the impacts on biota are comparatively unknown. Between 2000 and 2002, paired and synoptic sampling regimes were employed to assess armoring effects on insects and benthic macroinvertebrates in the supratidal zone of Puget Sound beaches. Paired sampling showed natural beach sites had significantly more deposited wrack. Infauna was dominated by oligochaetes and nematodes; talitrid amphipods, insects, and collembolans were significantly more numerous at natural beaches, and crustaceans were more abundant at altered beaches. Insect assemblages were diverse, with taxon richness higher at natural beach sites. In the synoptic sampling, where sites with higher elevation modifications were used, there were fewer differences in invertebrate assemblages between armored and nonarmored sites. The results show that, where shoreline armoring lowers the land–sea interface, benthic infauna and insect assemblages are disrupted. Widespread shoreline modifications may decrease the availability of prey resources for fish and wildlife and decrease the contribution of organic material entering the nearshore ecosystem.     

Red Mangrove Seedling Survival, Growth, and Reproduction: Effects of Environment and Maternal Genotype

An adequate understanding of the nature and extent of response to stressors and resources by marine foundation plant species requires study of local adaptation and plasticity in traits. Analyses of variation among genotypes in growth and morphology and genotype × environment interactions are necessary for restoration in, for example, different combinations of tide, soil, and salinity regimes, and for assessing how foundation plant species will respond to global climate change. We conducted a field experiment to assess differences in responses among 86 half-sibling (same maternal tree) seedling families of the red mangrove (Rhizophora mangle) to different environmental conditions of hydrology imposed at low- and high-intertidal settings. At 3 years, Rhizophora survival and growth varied with maternal tree genotype, elevation, and genotype × elevation. This effect was independent of size of propagules at planting. Growth also differed among the five islands planted, a main effect that is a composite of a number of microenvironmental differences stemming from island size and shape, proximity to passes (and thus fetch), and island slope. Significant genotype × island interactions for some response variables further support the hypothesis that seedlings of different maternal genotypes can perform very differently under various suites of environmental conditions. Planted seedlings reproduced at an early age, and at 3 years there were differences in reproductive output among genotypes but not an overall mean difference between plants at low or high elevation. Whether our results show adaptation to local conditions or differences in plasticity among genotypes will require further study as the plants mature further to demonstrate fitness differences. However, either adaptation or plasticity provides a basis for maintenance of Rhizophora dominance over a wider range of environmental conditions and may be important for adaptation to conditions that will vary with global climate change.     

Decoupling of deformation in the Upper Rhine Graben sediments. Seismic reflection and diffraction on 3-component Vertical Seismic Profiling (Soultz-sous-Forêts area)

A contribution to the definition of the structural pattern of the Soultz-sous-Forêts EGS (Enhanced Geothermal System) is presented here. After reprocessing, the PHN84J seismic reflection profile highlights the tilted blocks of the Merkwiller-Péchelbronn oilfield. In the Soultz-sous-Forêts horst, complex fault patterns are observed: the Hermerswiller normal fault flattens at depth and is rooted in decollements occurring in Triassic salt or clay series, while other steep normal faults affect underlying sedimentary formations and basement. Some methods for the exploitation of a seismic diffraction recorded by multi-component Vertical Seismic Profiling (VSP) are also illustrated to locate the diffractor without specific data processing. Polarisation and travel time analysis of a diffraction event recorded in the GPK1 borehole are analysed, and its exploitation combined with seismic reflection helps defining a tilted block geometry.     

Thermal histories of angrite meteorites: Trace element partitioning among silicate minerals in Angra dos Reis,Lewis Cliff 86010, and experimental analogs

Abstract— We measured rare earth element (REE) abundances in selected silicate phases in the angrites Angra dos Reis (AdoR) and Lewis Cliff (LEW) 86010 in order to further clarify the thermal history of AdoR. We also carried out a preliminary experimental study designed to examine apparent REE partitioning between silicates (fassaite, olivine, kirschsteinite, and melt) in synthetic analogs of angrites under disequilibrium conditions at liquidus temperatures. Silicates in AdoR are homogeneous with respect to major, minor, and trace elements, which is consistent with the interpretation that AdoR underwent extensive subsolidus equilibration. REE distributions in olivine and kirschsteinite in AdoR are similar to those in LEW 86010 and are consistent with the formation of kirschsteinite by exsolution from olivine during cooling and/or annealing. There is no evidence for a disequilibrium trace element signature that could have been inherited from rapid cooling at liquidus temperatures. This is supported by our petrographic observations of the occurrence of kirschsteinite within olivine aggregates in AdoR. Olivine/kirschsteinite pairs in AdoR record closure temperatures around 600–650 °C.     

ULTRACAM observations of the black hole X-ray transient XTE J1118+480 in quiescence

We present 450- and 850-μm maps of R Coronae Australis. We compare the maps with previous surveys of the region, and shed new light on the previously unknown nature of the protostellar sources at the centre of the cloud. We clarify the nature of two millimetre sources previously discovered in lower-resolution data. We identify one new Class 0 protostar, which we label SMM 1B, and we measure the envelope masses of a number of more evolved protostars. We identify two new pre-stellar cores, which we call SMM 1A and SMM 6.     

Petrographic studies of the impact melts from Meteor Crater,Arizona, USA

Abstract— We investigated the ballistically dispersed melts from Meteor Crater, Arizona, USA to determine the stratigraphic extent of its melt zone from the compositional relationship of melts and target rocks. Most melt particles are crystallized, hydrated, and oxidized; pristine glasses are rare. Hydration and oxidation occurred at ambient temperatures long after the impact. The preserved glasses are generally clear and texturally homogeneous, but unlike typical impact melts, they have unusually heterogeneous compositions, both within individual particles and from sample to sample. For example, the average SiO₂ for individual particles ranges from 43 to 65%. The projectile content is unusually high and it is distributed bimodally, with specific samples containing either 5–10% or 20–30% FeO. These compositional heterogeneities most likely reflect the high carbonate content of the target rocks and the release of copious CO₂ that dispersed the melts, thereby terminating melt flow and mixing. The high projectile content and the CO₂ depleted residue of purely sedimentary rocks produced mafic melts that crystallized fine‐grained olivine and pyroxene. The melts fall into three compositional groups reflecting variable proportions of the major target formations, Moenkopi, Kaibab, and Coconino. Least‐square mixing calculations revealed one group to contain 55% Moenkopi, 40% quartz‐rich, upper Kaibab, and 5% meteorite, suggesting a source depth of <30 m from the pre‐impact surface. The other two melt groups have higher contents of meteorite (15–20%) and Kaibab (50–70%) and contain more SiO₂ than average Kaibab. The additional quartz may have been derived from Coconino or the upper Kaibab, implying melt depths >90 m or <30 m, respectively. Additional studies, especially hydrocode calculations, are needed to better understand the source depth of these melts and their exceptionally high projectile content.     

Mobile element analysis by secondary ion mass spectrometry (SIMS) of impactite matrix samples from the Yaxcopoil‐1 drill core in the Chicxulub impact structure

Abstract— The concentrations of the fluid mobile trace elements lithium, beryllium, boron, and barium were measured in samples of the altered matrix of several impactite breccias of the Yaxcopoil‐1 drill core using secondary ion mass spectrometry (SIMS) to determine the extent of transport due to aqueous or hydrothermal processes. Three of the elements, Li, Be, and B, have higher concentrations in the upper suevite impact breccias than in the lower impact melt deposits by factors of 3.5, 2.2, and 1.5, respectively. Lithium and B are the most enriched elements up section, and appear to have had the greatest mobility. The similar fractionation of Li and B is consistent with fluid transport and alteration under low‐temperature conditions of less than 150 °C based on published experimental studies. In contrast to Li, Be, and B, the concentration of Ba in the altered matrix materials decreases upward in the section, and the concentration of Ba in the matrix is an order of magnitude less than the bulk concentrations, likely due to the presence of barite. The origin of the elemental variations with depth may be related to different protolith compositions in the upper versus the lower impactite units. A different protolith in the altered matrix is suggested by the Mg‐rich composition of the lower units versus the Al‐rich composition of the upper units, which largely correlates with the mobile element variations. The possibility that vertical transport of mobile elements is due to a postimpact hydrothermal system is supported by published data showing that the sediments immediately overlying the impactites are enriched in mobile elements derived from a hydrothermal system. However, the mobile elements in the sediments do not have to originate from the underlying impactites. In conclusion, our data suggests that the impactites at this location did not experience extensive high‐temperature hydrothermal processing, and that only limited transport of some elements, including Li, Be, and B, occurred.