Seasonal movement and groundwater flow mechanism in an unsaturated saprolitic hillslope

Numerous field monitoring programs have been conducted to investigate the performance of an unsaturated soil slope subjected to rainfalls in wet seasons. Most case histories focus on the response of matric suction, which is one of the two stress-state variables governing unsaturated soil behaviour. However, effects due to another variable, net normal stress, are often ignored. Also, slope performance under alternative wet and dry seasons is rarely reported and analysed. In this study, a saprolitic hillslope situated in Hong Kong was instrumented heavily to investigate its seasonal movement due to changes of the two variables and also groundwater flow mechanism. Two-year seasonal variations of matric suction and net normal stress were monitored by tensiometers together with heat dissipation matric water potential sensors and earth pressure cells, respectively. During heavy rainstorms in wet season, there was a substantial recharge of the main groundwater table, causing a significant increase of positive pore-water pressure in deeper depths. Rupture surface likely developed at depths between 5.5 and 6 m, hence resulting in a “deep-seated” mode of downslope movement. The downslope movement resulted in a peak increase of horizontal stress. In dry seasons, matric suction of up to 190 kPa was recorded, and the associated soil shrinkage led to substantial upslope rebounds. The stress built up in wet seasons hence reduced. After monitoring period of 2 years, downslope ratcheting is identified. Up to 40 % of the downslope displacements were recovered by the upslope rebounds.     

A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.     

Radiative transfer analyses of Titan’s tropical atmosphere

Titan’s optical and near-IR spectra result primarily from the scattering of sunlight by haze and its absorption by methane. With a column abundance of 92 km amagat (11 times that of Earth), Titan’s atmosphere is optically thick and only ～10% of the incident solar radiation reaches the surface, compared to 57% on Earth. Such a formidable atmosphere obstructs investigations of the moon’s lower troposphere and surface, which are highly sensitive to the radiative transfer treatment of methane absorption and haze scattering. The absorption and scattering characteristics of Titan’s atmosphere have been constrained by the Huygens Probe Descent Imager/Spectral Radiometer (DISR) experiment for conditions at the probe landing site (Tomasko, M.G., Bézard, B., Doose, L., Engel, S., Karkoschka, E. [2008a]. Planet. Space Sci. 56, 624–247; Tomasko, M.G. et al. [2008b]. Planet. Space Sci. 56, 669–707). Cassini’s Visual and Infrared Mapping Spectrometer (VIMS) data indicate that the rest of the atmosphere (except for the polar regions) can be understood with small perturbations in the high haze structure determined at the landing site (Penteado, P.F., Griffith, C.A., Tomasko, M.G., Engel, S., See, C., Doose, L., Baines, K.H., Brown, R.H., Buratti, B.J., Clark, R., Nicholson, P., Sotin, C. [2010]. Icarus 206, 352–365). However the in situ measurements were analyzed with a doubling and adding radiative transfer calculation that differs considerably from the discrete ordinates codes used to interpret remote data from Cassini and ground-based measurements. In addition, the calibration of the VIMS data with respect to the DISR data has not yet been tested. Here, VIMS data of the probe landing site are analyzed with the DISR radiative transfer method and the faster discrete ordinates radiative transfer calculation; both models are consistent (to within 0.3%) and reproduce the scattering and absorption characteristics derived from in situ measurements. Constraints on the atmospheric opacity at wavelengths outside those measured by DISR, that is from 1.6 to 5.0 μm, are derived using clouds as diffuse reflectors in order to derive Titan’s surface albedo to within a few percent error and cloud altitudes to within 5 km error. VIMS spectra of Titan at 2.6–3.2 μm indicate not only spectral features due to CH₄ and CH₃D (Rannou, P., Cours, T., Le Mouélic, S., Rodriguez, S., Sotin, C., Drossart, P., Brown, R. [2010]. Icarus 208, 850–867), but also a fairly uniform absorption of unknown source, equivalent to the effects of a darkening of the haze to a single scattering albedo of 0.63 ± 0.05. Titan’s 4.8 μm spectrum point to a haze optical depth of 0.2 at that wavelength. Cloud spectra at 2 μm indicate that the far wings of the Voigt profile extend 460 cm^?1 from methane line centers. This paper releases the doubling and adding radiative transfer code developed by the DISR team, so that future studies of Titan’s atmosphere and surface are consistent with the findings by the Huygens Probe. We derive the surface albedo at eight spectral regions of the 8 × 12 km² area surrounding the Huygens landing site. Within the 0.4–1.6 μm spectral region our surface albedos match DISR measurements, indicating that DISR and VIMS measurements are consistently calibrated. These values together with albedos at longer 1.9–5.0 μm wavelengths, not sampled by DISR, resemble a dark version of the spectrum of Ganymede’s icy leading hemisphere. The eight surface albedos of the landing site are consistent with, but not deterministic of, exposed water ice with dark impurities.     

The effects of meteorite impacts on the availability of bioessential elements for endolithic organisms

Abstract– Meteorite impacts, one of the most ubiquitous processes in the solar system, have the ability to destroy as well as create habitats for life. The impact process can increase the translucency and porosity of the target substrate, as well as mobilize biologically relevant elements within the substrate. For endolithic organisms, this process has important implications, especially in extreme environments where they are forced to seek refuge in the interior of rocks. Here, we show that unshocked target rocks and rocks that have experienced pressures up to about 80 GPa from the Haughton impact structure, Devon Island, Canada, possess a small, but discernible change in bulk chemistry within the major oxide analysis. However, changes in the distribution of elements did occur with increasing shock level for both the sedimentary and crystalline target. Both the crystalline and sedimentary target rocks contain significant amounts of glasses at higher shock levels (up to about 95% by volume), which would improve the availability of these elements to potential microbial endoliths as glasses are more easily dissolved by organic acids. The implication that impact events do not impoverish their capacity to serve as a “substrate” through volatilization is important with respect to analogous impact structures on Mars. After the deleterious effects of the direct meteorite impact, any microorganisms on Mars would have benefited from the input of heat, the mobilization of a possible frozen groundwater system, as well as increased translucency, porosity, and trace nutrient availability of the target substrate.     

Spatial variation in elephant impact on the Zambezi teak forest in the Chobe national park,Botswana

Abstract

Tectonic mapping and geologic evolution of a region were historically conducted on the basis of field observations. After the advent of remote sensing technology, tectonic mapping became much easier and structural mapping through imagery has gained credibility and suitability in regional mapping, tectonic evolution and modeling. In this regard, an attempt has been made to make use of the satellite technology to bring out the structural trends and the fracture/lineament pattern in Biligirirangan region of Northern Tamil Nadu through satellite remote sensing. The folded architecture in Biligirirangan region has evolved from structural trends. The subsurface structures of the region were derived through resistivity contours and resistivity images created by GIS software.

The surficial information derived from the satellite imagery and subsurface structures derived from the resistivity contours and images were integrated with field observations. This integration has given a clear tectonic picture of the Biligirirangan region and the tectonic structures were then analysed for tectonic forces, evolution and modeling.

The study determined that the Structural trends were mostly in a N‐S direction and the folds were of isoclinal type with alternating synclinal and anticlinal folds of an easterly dipping nature. These folds in conjunction with the lineaments have brought out the palaeostress pattern of the Biligirirangan region. The study further suggests that the regional compressive force trending in ENE‐WSW direction was responsible for the present configuration of folds. In addition, the study also focuses the efficacy of the satellite imagery in tectonic analysis and the resistivity contours and images for the subsurface structural analysis.     

Empirical statistical characterization and regionalization of amplitude–duration–frequency curves for extreme peak flows in the Lake Victoria Basin,East Africa

Abstract

This paper focuses on a regionalization attempt to partly solve data limitation problems in statistical analysis of high flows to derive discharge–duration–frequency (QDF) relationships. The analysis is based on 24 selected catchments in the Lake Victoria Basin (LVB) in East Africa. Characteristics of the theoretical QDF relationships were parameterized to capture their slopes of extreme value distributions (evd), tail behaviour and scaling measures. To enable QDF estimates to be obtained for ungauged catchments, interdependence relationships between the QDF parameters were identified, and regional regression models were developed to explain the regional difference in these parameters from physiographic characteristics. In validation of the regression models, from the lowest (5 years) to the highest (25 years) return periods considered, the percentage bias in the QDF estimates ranged from –2% for the 5-year return period to 27% for 25-year return period.

Editor D. Koutsoyiannis     

MOISTURE TRAJECTORIES ASSOCIATED WITH HEAVY RAINFALL IN THE APPALACHIAN REGION OF THE UNITED STATES

Synoptic data associated with a sample of 554 heavy rainfall events is utilized to carry out a trajectory analysis that identifies the movements of moisture towards regions of heavy rain. Both seasonal and regional variations are found in the moisture trajectories associated with heavy rain events occurring in three regions in the Appalachian study area. Numerous events in the region west of the mountain range are tied to westerly and south-southwesterly circulations that bring moisture from the Mississippi River Valley and the Gulf of Mexico during the warm and cool seasons, respectively. Many events southeast of the mountain range are associated with southerly to southeasterly circulations that advect moisture from the Atlantic Ocean. Because of orographic precipitation enhancement and a good exposure to the Gulf of Mexico and the Atlantic Ocean, the southern and southeastern slopes of the Appalachian mountains display high frequencies of heavy rainfall, particularly during the cool season. The interior portions of the mountain range and the adjacent plateau to the northwest, on the other hand, are sheltered from moisture source regions and, therefore, exhibit low heavy rain frequencies. [Key words: precipitation, synoptic climatology, Appalachia.]     

Variation of illite/muscovite <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar age spectra during progressive low-grade metamorphism: an example from the US Cordillera

⁴⁰Ar/³⁹Ar step-heating data were collected from micron to submicron grain-sizes of correlative illite- and muscovite-rich Cambrian pelitic rocks from the western United States that range in metamorphic grade from the shallow diagenetic zone (zeolite facies) to the epizone (greenschist facies). With increasing metamorphic grade, maximum ages from ⁴⁰Ar/³⁹Ar release spectra decrease, as do total gas ages and retention ages. Previous studies have explained similar results as arising dominantly or entirely from the dissolution of detrital muscovite and precipitation/recrystallization of neo-formed illite. While recognizing the importance of these processes in evaluating our results, we suggest that the inverse correlation between apparent age and metamorphic grade is controlled, primarily, by thermally activated volume diffusion, analogous to the decrease in apparent ages with depth observed for many thermochronometers in borehole experiments. Our results suggest that complete resetting of the illite/muscovite Ar thermochronometer occurs between the high anchizone and epizone, or at roughly 300 °C. This empirical result is in agreement with previous calculations based on muscovite diffusion parameters, which indicate that muscovite grains with radii of 0.05–2 μm should have closure temperatures between 250 and 350 °C. At high anchizone conditions, we observe a reversal in the age/grain-size relationship (the finest grain-size produces the oldest apparent age), which may mark the stage in prograde subgreenschist facies metamorphism of pelitic rocks at which neo-formed illite/muscovite crystallites typically surpass the size of detrital muscovite grains. It is also approximately the stage at which neo-formed illite/muscovite crystallites develop sufficient Ar retentivity to produce geologically meaningful ⁴⁰Ar/³⁹Ar ages. Results from our sampling transect of Cambrian strata establish a framework for interpreting illite/muscovite ⁴⁰Ar/³⁹Ar age spectra at different stages of low-grade metamorphism and also illuminate the transformation of illite to muscovite. At Frenchman Mtn., NV, where the Cambrian Bright Angel Formation is at zeolite facies conditions, illite/muscovite ⁴⁰Ar/³⁹Ar data suggest a detrital muscovite component with an apparent age ≥967 Ma. The correlative Carrara Fm. is at anchizone conditions in the Panamint and Resting Spring Ranges of eastern California, and in these locations, illite/muscovite ⁴⁰Ar/³⁹Ar data suggest an early Permian episode of subgreenschist facies metamorphism. The same type of data from equivalent strata at epizone conditions (greenschist facies) in the footwall of the Bullfrog/Fluorspar Canyon detachment in southern Nevada reveals a period of slow-to-moderate Late Cretaceous cooling.     

Late Occupation of the High‐Elevation Northern Tibetan Plateau Based on Cosmogenic,Luminescence, and Radiocarbon Ages

¹⁰Be‐²⁶Al cosmogenic surface exposure, optically stimulated luminescence, and radiocarbon dates from the site of Xidatan 2 (∼4300 m above sea level [asl] in the Kunlun Pass, northern Tibetan Plateau) suggest the site was intermittently and briefly occupied approximately 9200–6400 yr B.P. This age is substantially younger than expected given the late Upper Paleolithic character of the lithic assemblage, which is dominated by microlithic and unique discoidal prepared core technologies. Comparisons between Xidatan 2 and known surface lithic assemblages in the Kekexili and Chang Tang regions of the central high Plateau show not only that the latter are technologically similar to Xidatan 2, but also that they are demonstrably connected to Xidatan 2 through utilization of the same stone raw materials, which includes a chemically distinctive obsidian. Contrary to most accounts of Tibetan Plateau colonization, our results suggest that the earliest substantial occupations on the interior Tibetan Plateau above 4000 m asl may date to the Pleistocene/Holocene transition.