Stratigraphic control of hot fluids on anthracitization, Lackawanna synclinorium, Pennsylvania

The Lackawanna synclinorium of Pennsylvania contains abundant coal that was altered to anthracite rank during the Late Paleozoic Alleghanian orogeny. Why did the coal in the synclinorium undergo anthracitization? Two alternatives have been suggested. (1) The region was buried deeply during and/or after the Alleghanian orogeny and thus became hot in response to Earth's geothermal gradient; and (2) hot fluids migrating from the orogen toward the foreland carried heat into the coal and caused anthracitization. If the second hypothesis is correct, the region should contain evidence that hot fluids passed through the coal. Field observations, illite-crystallinity studies and fluid-inclusion analyses indicate that the coal-bearing Pottsville and Llewellyn Formations, and an underlying detachment fault, called the Pottchunk fault (at or slightly below the base of the Pottsville Formation), acted as a regional aquifer for the migration of hot fluids during the Alleghanian orogeny. The presence of quartz veins and the hydrothermal minerals tosudite and pyrophyllite in strata above the Pottchunk fault, and the apparent absence of an illite-crystallinity burial gradient in the underlying strata, suggest that fluids migrated through large pores in coarse-grained sandstones, through abundant fractures that developed in response to Alleghanian deformation, and along the Pottchunk fault. The quartz veins, tosudite and pyrophyllite mineralization do not occur below the Pottchunk fault (except at one locality), suggesting that fluid flow was greater above the fault, perhaps because fracturing accompanying deformation increased permeability of the fault's hanging wall. Fluid inclusions in the Pottsville and Llewellyn Formations indicate fluids achieved a minimum temperature of 270 °C at a depth of 3.1–8.5 km. Heat-flow calculations constrained by fluid-inclusion data show the heat carried by the migrating fluids through the coal-bearing strata was sufficient to elevate the rock temperature to anthracite-grade conditions (250 °C), assuming that the fluid event lasted about 1 year. Thus, deep burial (6–9 km) of the coal-bearing strata in the Lackawanna synclinorium was not required for anthracitization. Anthracitization was likely the result of stratigraphically controlled hot fluid migration through the coal-bearing strata at shallow depths (≤5 km).     

Revisiting the Tidal Activation of Seismicity with a Damage Mechanics and Friction Point of View

— The Load Unload Response Ratio theory (LURR) puts forward the idea that the ratio of seismicity during times of increased tidal loading to times of decreased tidal loading takes on anomalously large values as the preparatory region of the earthquake approaches a critical state. We repeated the calculations of LURR for several earthquakes in California, for which results had been published, using estimates of the parameters which could be determined from the published work. We were unable to confirm any LURR ratio predictive significance. We test an alternative method of evaluating the influence of tidal stresses on earthquakes based on damage mechanics. As in rock mechanics experiments, it may be that anomalous activation of seismicity prior to large earthquakes occurs only during those time intervals when the applied stress exceeds values previously attained. We applied this approach to analyze the same data set used to test the LURR hypothesis, and it also failed to reveal any significant precursory indications. It may be that time-dependent failure processes such as self-driven nucleation occur on a time scale longer than the diurnal tide, thus destroying the expected synchronization.     

Modeling diagenesis of lead in sediments of a Canadian Shield lake

Triplicate porewater lead concentration profiles were determined on six occasions in a Canadian Shield lake. Total Pb concentrations were also measured in a dated core obtained at the same site. This information, as well as an extensive dataset comprising ancillary geochemical measurements on porewaters and sediment and the population densities of benthic animals, is used in a one-dimensional transport-reaction diagenetic model to investigate the transport and mobilization of Pb in these sediments. Application of the model consistently indicates the presence of a zone of Pb production to the porewaters that lies above a zone of Pb consumption. The profiles of various porewater constituents and thermodynamic calculations indicate that Pb is mobilized in the zone of production by the reductive dissolution of iron oxyhydroxides, whereas it is removed in the zone of consumption by precipitation as a solid sulfide. Rate constants are estimated for reductive iron dissolution (k_d^Fe(III) = 2.0 ± 0.5 × 10⁻¹ cm³ mol⁻¹ s⁻¹), Pb adsorption on iron oxyhydroxides (k_ads^Pb = 98 ± 55 cm³ mol⁻¹ s⁻¹), and Pb precipitation (k_ppt^Pb = 8 × 10⁻²⁰ mol cm⁻³ s⁻¹ to 16 ± 13 × 10⁻²² mol cm⁻³ s⁻¹, depending on the solubility product assumed for the precipitation of PbS). According to model calculations, diagenetic processes, such as remobilization, molecular diffusion, bioturbation, and bioirrigation have a negligible influence on the solid phase Pb profile. In agreement with this finding, the present-day fluxes of dissolved Pb by diffusion (J_D^Pb = −6.5 × 10⁻¹¹ mol cm⁻² yr⁻¹), bioturbation (J_B^Pb = −1.1 × 10⁻¹³ mol cm⁻² yr⁻¹), and bioirrigation (J_I^Pb = −1.5 × 10⁻¹¹ mol cm⁻² yr⁻¹) are small compared to the flux of Pb deposited with settling particles (J_S^Pb = 5.3 × 10⁻⁹ mol cm⁻² yr⁻¹).     

Habitat requirements for submerged aquatic vegetation in Chesapeake Bay: Water quality, light regime, and physical-chemical factors

We developed an algorithm for calculating habitat suitability for seagrasses and related submerged aquatic vegetation (SAV) at coastal sites where monitoring data are available for five water quality variables that govern light availability at the leaf surface. We developed independent estimates of the minimum light required for SAV survival both as a percentage of surface light passing though the water column to the depth of SAV growth (PLW _min) and as a percentage of light reaching reaching leaves through the epiphyte layer (PLL _min). Value were computed by applying, as inputs to this algorithm, statistically dervived values for water quality variables that correspond to thresholds for SAV presence in Chesapeake Bay. These estimates ofPLW _min andPLL _min compared well with the values established from a literature review. Calcultations account for tidal range, and total light attenuation is partitioned into water column and epiphyte contributions. Water column attenuation is further partitioned into effects of chlorophylla (chla), total suspended solids (TSS) and other substances. We used this algorithm to predict potential SAV presence throughout the Bay where calculated light available at plant leaves exceededPLL _min. Predictions closely matched results of aerial photographic monitoring surveys of SAV distribution. Correspondence between predictions and observations was particularly strong in the mesohaline and polythaline regions, which contain 75–80% of all potential SAV sites in this estuary. The method also allows for independent assessment of effects of physical and chemical factors other than light in limiting SAV growth and survival. Although this algorithm was developed with data from Chesapeake Bay, its general structure allows it to be calibrated and used as a quantitative tool for applying water quality data to define suitability of specific sites as habitats for SAV survival in diverse coastal environments worldwide.     

Active sensing using impedance‐based ARX models and extreme value statistics for damage detection

In this paper, the applicability of an auto‐regressive model with exogenous inputs (ARX) in the frequency domain to structural health monitoring (SHM) is established. Damage sensitive features that explicitly consider non‐linear system input/output relationships are extracted from the ARX model. Furthermore, because of the non‐Gaussian nature of the extracted features, Extreme Value Statistics (EVS) is employed to develop a robust damage classifier. EVS provides superior performance to standard statistical methods because the data of interest are in the tails (extremes) of the damage sensitive feature distribution. The suitability of the ARX model, combined with EVS, to non‐linear damage detection is demonstrated using vibration data obtained from a laboratory experiment of a three‐story building model. It is found that the vibration‐based method, while able to discern when damage is present in the structure, is unable to localize the damage to a particular joint. An impedance‐based active sensing method using piezoelectric (PZT) material as both an actuator and a sensor is then investigated as an alternative solution to the problem of damage localization. Copyright © 2005 John Wiley & Sons, Ltd.     

干涉合成孔径雷达及其在火山研究中的应用(第二部分:阿拉斯加火山的InSAR成像)(英文)

干涉合成孔径雷达是一项能够对地表变形进行测量的遥感技术,在一个巨大区域内,它的变形测量精度可达亚厘米级,而其空间分辨率则在数十米以内。本文对我们应用InSAR技术对阿拉斯加火山进行研究的最新成果进行了总结,同时包括火山的喷发和非喷发活动。这些研究成果表明InSAR不仅能够增进我们对阿拉斯加火山活动的理解,而且还能够增强我们对未来火山喷发情况及其灾害的预测能力。     

Petrogenesis and tectonic setting of the peralkaline Pine Canyon caldera, Trans-Pecos Texas, USA

The Pine Canyon caldera is a small (6–7 km diameter) ash-flow caldera that erupted peralkaline quartz trachyte, rhyolite, and high-silica rhyolite lavas and ash-flow tuffs about 33–32 Ma. The Pine Canyon caldera is located in Big Bend National Park, Texas, USA, in the southern part of the Trans-Pecos Magmatic Province (TPMP). The eruptive products of the Pine Canyon caldera are assigned to the South Rim Formation, which represents the silicic end member of a bimodal suite (with a “Daly Gap” between 57 and 62 wt.% SiO₂); the mafic end member consists primarily of alkali basalt to mugearite lavas of the 34–30 Ma Bee Mountain Basalt. Approximately 60–70% crystallization of plagioclase, clinopyroxene, olivine, magnetite, and apatite from alkali basalt coupled with assimilation of shale wall rock (M_a/M_c = 0.3–0.4) produced the quartz trachyte magma. Variation within the quartz trachyte–rhyolite suite was the result of 70% fractional crystallization of an assemblage dominated by alkali feldspar with subordinate clinopyroxene, fayalite, ilmenite, and apatite. High-silica rhyolite is not cogenetic with the quartz trachyte–rhyolite suite, and can be best explained as the result of  5% partial melting of a mafic granulite in the deep crust under the fluxing influence of fluorine. Variation within the high-silica rhyolite is most likely due to fractional crystallization of alkali feldspar, quartz, magnetite, biotite, and monazite. Lavas and tuffs of the South Rim Formation form A-type rhyolite suites, and are broadly similar to rock series described in anorogenic settings both in terms of petrology and petrogenesis. The Pine Canyon caldera is interpreted to have developed in a post-orogenic tectonic setting, or an early stage of continental rifting, and represents the earliest evidence for continental extension in the TPMP.