Municipal wastewater contamination in the southern california bight: Part I—metal and organic contaminants in sediments and organisms

Sediments and organisms were examined for concentrations of organic and metal contaminants from near the Los Angeles County (JWPCP) municipal outfall at Palos Verdes (PV) station 7-3, the Los Angeles City (Hyperion) municipal outfall at Santa Monica Bay (SMB) station 6-4 and reference station SMB 2–3 near Malibu Beach. Flows and mass emission rates of suspended solids, PCBs, Cd and Zn were similar at the two outfalls. Mass emission rate of copper was almost twice as high from Hyperion as from JWPCP, while mass emission rate of DDTs was an order or magnitude higher from JWPCP than from Hyperion.Surficial sediments at PV 7-3 were enriched in most contaminants relative to SMB 6-4 and relative to the mass emission rates of contaminants from the JGVPCP and Hyperion outfalls. Some of this enrichment could be accounted for by the greater accumulation of organic material, measured as total volatile solids, at PV 7-3 relative to SMB 6-4. Some might be accounted for by resurfacing of more contaminated historical deposits buried at PV 7-3. Some of the enrichment of DDTs relative to PCBs could be accounted for by the greater abundance of oxygenated metabolites of PCBs (PCBols) relative to DDTs (DDTols) in sediments.The degree of contamination of organisms by DDTs increased with proximity to PV 7-3 but contamination by PCBs was similar at PV 7-3 and SMB 6-4. DDT concentrations in fish livers ranged from 12 ± 4 ( ) mg/wet kg in longspine combfish from SMB 2–3 to 610 ± 105 (n = 5) mg/wet kg in Pacific sanddab from PV 7-3. DDT concentrations in fish gonads ranged from 0·003 ± 0·003 (n = 5) mg/wet kg in yellowchin sculpin from SMB 6-4 to 1.5 ± 6 (n = 3) mg/wet kg in Pacific sanddabs from PV 7-3. PCB concentrations in fish livers ranged from 1·2 ± 0·4 (n = 4) mg/wet kg in yellowchin sculpin from SMB 2–3 to 16 ± 3 (n = 6) in Pacific Sanddab from SMB 6-4. DDT and PCB concentrations in invertebrate hepatopancreas were only slightly lower than those in fish livers. DDTols and PCBoIs comprised an average of 91 % of the total of parent compounds and oxygenated metabolites in sediments and 66 % in livers and hepatopancreas. Trace metals were frequently decreased in livers and hepatopancreas from near outfalls even though they were highly elevated in sediments.Comparison of sediment and tissue chlorinated hydrocarbon data with that from Elliot and Commencement Bays, Puget Sound, indicated that none of the southern California coastal stations considered in this study were sufficiently lacking contamination to be considered as adequate control sites.     

Spectral distortion inherent in airborne profilometer measurements of ocean wave heights

A theoretical analysis of the performance characteristics of an airborne profilometer is presented. The analytical characteristics are shown to agree with those of the prototype. Results show that both the wave spectra and the dominant wave heading can be determined using the airborne profilometer.     

Gas-charged sediments in the Amazon submarine delta

Seismic profiling with 3.5-kHz and GeoPulse in the Amazon submarine delta indicates that gas-charged sediments cover an area greater than 31,000 km². Gas appears on seismic profiles as gas-brightening reflectors near the river mouth, where mud and sand are well stratified. In fine sediments of the distal portion of the system, gas turbidity zones predominate. Biogenic gas is generated during degradation of terrestrial and marine organic matter by bacteria. The depth of gas in sediment below the seabed depends in part on anaerobic methane oxidation and the base of the sulfate reduction zone and on stratigraphic traps.     

Induction of phenol-type sulfotransferase and glucuronosyltransferase in channel catfish and mummichog

Conjugation of phenolic xenobiotics and metabolites through sulfation and glucuronidation is an important biotransformation pathway. Sulfotransferases (SULT) are generally considered non-inducible, while some UDP-glucuronosyltransferase (UGT) isoenzymes are co-induced with cytochrome P450-1A by Ah-receptor ligands. To test these assumptions for two fish species, we measured sulfation and glucuronidation of 9-hydroxybenzo[a]pyrene in 3-methylcholanthrene (3-MC) treated channel catfish (Ictalurus punctatus) and in mummichog (Fundulus heteroclitus) from the creosote contaminated Atlantic Wood site in the Elizabeth River, VA. The results show a significant induction of both UGT and SULT activity in 3-MC treated catfish, linked to the expected induction of EROD activity. In mummichog, significant induction of UGT was measured at the contaminated site over the reference site (King's Creek, VA), as well as extremely low SULT activities at both sites. Western blots, using a polyclonal antibody for catfish phenol-type SULT, confirmed the absence of phenol-type SULT in mummichog. Residual, though slightly inducible, SULT activity may be attributed to other SULT isoforms.     

An assessment model for the fate and environmental effects of offshore drilling mud discharges

The benthic boundary layer transport (bblt) model was developed to assess potential impact zones from drilling mud discharges from offshore oil and gas drilling. The model focuses on the drift, dispersion and concentration levels of the suspended fraction of the drilling mud fines in the benthic boundary layer with the assumption of a spatially homogeneous environment. The current version of the model includes a wave boundary layer, a breakup module for drilling mud flocs, a dose–response module for scallops, and a graphical user interface (GUI). The GUI was written in Java which makes the code largely platform independent. Simulations of suspended barite concentration near Sable Island on the Scotian Shelf during drilling in the fall of 1999 reproduce the very low concentrations (generally less than 1 μg L⁻¹) observed during the Environmental Effects Monitoring program. However, the simulations also exhibited concentrations in excess of the no-effects concentration for scallops (100 μg L⁻¹) prior to the sampling program. The model estimates that the potential impact on scallops in the vicinity of the drilling is a few days of lost growth over scales of a few kilometers.     

Spatial variability of phytoplankton absorption coefficients and pigments off Baja California during November 2002

We have estimated the spatial variability of phytoplankton specific absorption coefficients (a* _ph ) in the water column of the California Current System during November 2002, taking into account the variability in pigment composition and phytoplankton community structure and size. Oligotrophic conditions (surface Chl < 0.2 mg m⁻³) dominated offshore, while mesotrophic conditions (surface Chl 0.2 to 2.0 mg m⁻³) where found inshore. The specific absorption coefficient at 440 [a* _ph (440)] ranged from 0.025–0.281 m²mg⁻¹ while at 675 nm [a* _ph (675)] it varied between 0.014 and 0.087 m²mg⁻¹. The implementation of a size index based on HPLC data showed the community structure was dominated by picoplankton. This would reduce the package effect in the variability of a* _ph (675). Normalized a _ph curves were classified in two groups according to their shape, separating all spectra with peaks between 440 and 550 nm as the second group. Most samples in the first group were from surface layers, while the second group were from the deep chlorophyll maximum or deeper. Accessory photoprotective pigments (APP) tended to decrease with depth and accessory photosynthetic pigments (APS) to increase, indicating the importance of photoprotective mechanisms in surface layers and adaptation to low light at depth. Samples with higher ratios of APP:APS (>0.4) were considered as phytoplankton adapted to high irradiances, and lower ratios (<0.26) as adapted to low irradiances. We found a good relationship between APP:APS and a* _ph (440) for the deeper layer (DCM and below), but no clear evidence of the factors causing the variability of a* _ph (440) in the upper layer.     

Source parameters of some large earthquakes in Northern Aegean determined by body waveform inversion

Average source parameters for three large North Aegean events are obtained from body wave inversion for the moment tensor. The parameters for the events are as follows: The events exhibit dextral strike-slip faulting with theT axis striking NS and nearly horizontal, implying extension in this direction. The focal mechanisms obtained are in agreement with the seismotectonic regime of the North Aegean. It is known that the region is tectonically controlled by the existence of the strike-slip Anatolian fault and its westward continuation in the Aegean, as well as the NS extension the whole Aegean area undergoes.The components of the moment tensor show that the region is dominated by compression in the EW direction which is encompassed by extension in the NS direction. All the events were found to be shallow (10 km) with a source time function of approximately 8 s duration and small stress drop values.The teleseismic long period verticalP-waves exhibited distortions, that could be attributed to lateral inhomogeneities in the source structure or more probably to a nonflat water-crust interface.     

Comparing various approaches for assessing groundwater recharge at a regional scale in the Canadian Shield

ABSTRACT

Estimating groundwater recharge is crucial to ensuring the proper management of aquifers. In this study, net regional recharge and spatial potential recharge are estimated at four watersheds within the Charlevoix–Haute-Côte-Nord (CHCN) regions, Quebec Province, Canada. Four methods are applied based on available data. The first two approaches are regional water budget methods. These two methods differ in their estimation of vertical inflow (VI), which is estimated from two hydrological models: GR4J and HYDROTEL. The third method estimates potential recharge spatially over the study area. Finally, the streamflow data are analysed using the Eckhardt baseflow separation method to obtain an estimation of recharge, assuming that discharge is equal to recharge. According to the results of all investigated methods, the mean annual recharge for the CHCN region is approximately 183 mm, which is 18% of the total annual precipitation (P). The discussion section highlights uncertainties due to the assumptions of each method and the reliability of the data.     

Instability of planetary waves in a high vertical resolution model

Abstract

A high vertical resolution model is used to examine the instability of a baroclinic zonal flow and a finite amplitude topographically forced wave. Two families of unstable modes are found, consisting of zonally propagating most unstable modes, and stationary unstable modes. The former have time scale and spatial structure similar to baroclinic synoptic disturbances, but are localized in space due to interaction with the zonally asymmetric forcing. These modes transport heat efficiently in both the zonal and meridional directions. The second family of stationary unstable modes has characteristics of modes of low frequency variability of the atmosphere. They have time scales of 10 days and longer, and are of planetary scale with an equivalent barotropic vertical structure. The horizontal structure resembles blocking flows. They are maintained by available potential energy of the basic wave, and have large zonal heat fluxes. The results for both families of modes are interpreted in terms of an interaction between forcing and baroclinic instability to create favoured regions for eddy development. Applications to baroclinic planetary waves are also considered.     

Near-Wake Turbulent Flow Structure and Mixing Length Downstream of a Fractal Tree

In order to study the turbulence structure behind a multiscale tree-like element in a boundary layer, detailed particle image velocimetry measurements are carried out in the near-wake of a fractal-like tree. The tree is a pre-fractal with five generations, each consisting of three branches and a scale-reduction factor of 1/2 between consecutive generations. Detailed mean velocity and turbulence stress profiles are documented, as well as their downstream development. Scatter plots of mean velocity gradient (transverse shear in the wake) and Reynolds shear stress exhibit a good linear relation at all locations in the flow. Therefore, in the transverse direction of the wake evolution, the data support the Boussinesq eddy-viscosity concept. The measured mixing length increases with streamwise distance, in agreement with classic wake expansion rates. Conversely, the measured eddy viscosity and mixing length in the transverse direction decrease with increasing elevation, which differs from the behaviours measured in the vertical direction in traditional boundary layers or in canopy flows studied before. In order to find an appropriate single length scale to describe the wake evolution behind a multiscale object, two models are proposed, based on the notion of superposition of scales. One approach is based on the radial spectrum of the object while the second is based on its length-scale distribution evaluated using fractal geometry tools. Both proposed models agree well with the measured mixing length. The results suggest that information about multiscale clustering of branches must be incorporated into models of the mixing length for flows through single or sparse canopies of multiscale trees.