Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon

Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb²⁺ > Cu²⁺ > Ni²⁺. Langmuir model had higher R² values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.     

Mineral inclusions in diamonds from the Sputnik kimberlite pipe, Yakutia

The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO₂ content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P-T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m² conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle.     

A preliminary case study of potential ceramic raw materials in the Aileu area of Timor Leste

The newly independent country of Timor Leste is located in the eastern half of Timor Island (Indonesian archipelago). Geological studies of the country’s mineral resources and extractive activities are practically non-existent. There is evidence of the exploitation of ceramic raw materials at outcrop level and two small brick kilns, nowadays inactive, in the Dili and Aileu areas. Near Aileu, there are light-coloured silt-rich deposits, interpreted as overbank deposits, interbedded with ancient river terraces (post-Pliocene) overlying metamorphic bedrock. These sediments are the subject of this study, which encompassed geological mapping and preliminary characterisation. Tectonically, the area is a graben, preserving alluvium and colluvium deposits. Five channel samples representative of the silt-rich deposits were collected. Semi-quantitative mineralogical analysis shows that the samples are made of illite, quartz and kaolinite clays, with accessory illite/vermiculite interstratified minerals and K-feldspar. The chemical data show agreement with the estimated mineralogical composition. The grain size distribution points to a silt-dominated assemblage. Most samples have a satisfactory extrudability but deficient moulding properties. After firing, the sampled raw materials form a final product with possible ceramic capability for whiteware production.     

Proterozoic–Paleozoic development of the basement of the Central Andes (18–26°S) — a mobile belt of the South American craton

The Late Precambrian–Early Paleozoic metamorphic basement forms a volumetrically important part of the Andean crust. We investigated its evolution in order to subdivide the area between 18 and 26°S into crustal domains by means of petrological and age data (Sm–Nd isochrons, K–Ar). The metamorphic crystallization ages and t_DM ages are not consistent with growth of the Pacific margin north of the Argentine Precordillera by accretion of exotic terranes, but favor a model of a mobile belt of the Pampean Cycle. Peak metamorphic conditions in all scattered outcrop areas between 18 and 26°S are similar and reached the upper amphibolite facies conditions indicated by mineral paragensis and the occurrence of migmatite. Sm–Nd mineral isochrons yielded 525±10, 505±6 and 509±1 Ma for the Chilean Coast Range, the Chilean Precordillera and the Argentine Puna, and 442±9 and 412±18 Ma for the Sierras Pampeanas. Conventional K–Ar cooling age data of amphibole and mica cluster around 400 Ma, but are frequently reset by Late Paleozoic and Jurassic magmatism. Final exhumation of the Early Paleozoic orogen is confirmed by Devonian erosional unconformities. Sm–Nd depleted mantle model ages of felsic rocks from the metamorphic basement range from 1.4 to 2.2 Ga, in northern Chile the average is 1.65±0.16 Ga (1σ; n=12), average t_DM of both gneiss and metabasite in NW Argentina is 1.76±0.4 Ga (1σ; n=22), and the isotopic composition excludes major addition of juvenile mantle derived material during the Early Paleozoic metamorphic and magmatic cycle. These new data indicate a largely similar development of the metamorphic basement south of the Arequipa Massif at 18°S and north of the Argentine Precordillera at 28°S. Variations of metamorphic grade and of ages of peak metamorphism are of local importance. The protolith was derived from Early to Middle Proterozoic cratonic areas, similar to the Proterozoic rocks from the Arequipa Massif, which had undergone Grenvillian metamorphism at ca. 1.0 Ga.     

Simulating future Caspian sea level changes using regional climate model outputs

We report on simulations of present-day climate (1961–1990) and future climate conditions (2071–2100, Special Report on Emissions Scenario A2) over the Caspian sea basin with a regional climate model (RCM) nested in time-slice general circulation model (GCM) simulations. We also calculate changes (A2 scenario minus present-day) in Caspian sea level (CSL) in response to changes in the simulated hydrologic budget of the basin. For the present-day run, both the GCM and RCM show a good performance in reproducing the water budget of the basin and the magnitude of multi-decadal changes in CSL. Compared to present-day climate, in the A2 scenario experiment we find an increase in cold season precipitation and an increase in temperature and evaporation, both over land and over the Caspian sea. We also find a large decrease of CSL in the A2 scenario run compared to the present-day run. This is due to increased evaporation loss from the basin (particularly over the sea) exceeding increased cold season precipitation over the basin. Our results suggest that the CSL might undergo large changes under future climate change, leading to potentially devastating consequences for the economy and environment of the region.     

Changes in European precipitation seasonality and in drought frequencies revealed by a four-century-long tree-ring isotopic record from Brittany, western France

A new paleoclimatic reconstruction for western France is obtained from tree-ring cellulose stable isotopes. Living trees from Rennes Forest and beams from two ancient buildings in Rennes city have been combined to cover the past four centuries with a gap from 1730 to 1750. The cellulose ¹³C reflects the progressive changes in atmospheric CO₂ isotopic composition. The combined ¹³C and ¹⁸O measurements are used to propose a reconstruction of interannual fluctuations in local summer temperature and water stress. At the decadal time scale, the reconstructed water stress profile exhibits a significant similarity with the historical wine harvest dates, an indicator of warm and dry growth seasons, as well as with the summer central England and central Alps instrumental temperature records and climate model results. Combined with instrumental precipitation records from Paris, these reconstructions suggest a dramatic and widespread change in the seasonality of the precipitation at the beginning of the nineteenth century, with drier winters and wetter summers, which may have contributed to the Alpine glacier decline at the end of the Little Ice Age. The tree-ring isotope records also show a relationship with large-scale North Atlantic circulation changes and the interannual variability is modified between the nineteenth and twentieth centuries (7–8 year periodicities) and the seventeenth century (11–14 year periodicities). By classifying 20-year-long subsets of the reconstructed climatic parameters, we estimate that a decadal mean summer warming of 0.8±0.1°C induced extreme dry years to be 2.2±0.7 times more frequent.     

Object-oriented data modelling for spatial databases

Data modelling is a critical stage of database design. Recent research has focused upon object-oriented data models, which appear more appropriate for certain applications than either the traditional relational model or the entity-relationship approach. The object-oriented approach has proved to be especially fruitful in application areas, such as the design of geographical information systems which have a richly structured knowledge domain and are associated with multimedia databases. This article discusses the key concepts in object-oriented modelling and demonstrates the applicability of an object-oriented design methodology to the design of geographical information systems. In order to show more clearly how this methodology may be applied, the paper considers the specific object-oriented data model IFO. Standard cartographic primitives are represented using IFO, which are then used in the modelling of some standard administrative units in the United Kingdom. The paper concludes by discussing current research issues and directions in this area.     

Evolution of the symbiotic star AS 338 after its strong outburst in 1983

The photometric UBV observations of AS 338 that we began after its outburst in 1983 are presented. They were accompanied by yearly spectroscopic observations and by occasional estimations of the star’s infrared JHKL magnitudes. In June 1993, the star’s optical spectrum was extended to the ultraviolet via IUE observations of AS 338. Collectively, the above observations make it possible to trace the evolution of stellar activity over a period of 15 years in various spectral ranges. In particular, a short-time return of the hot component of AS 338 to the state when He II lines reappeared in the star’s spectrum was noted in 1993. At this time, a blend of the C IV λλ5802 and 5812 lines, which is typical of Wolf-Rayet spectra, was detected in it. In June 1993, the temperature of the hot component was T _h ≈ 8.8 × 10⁴ K, and the ratio of its bolometric flux to that of the red giant was F _{h, bol}/F _{g, bol} ≈ 1.0. In August, its temperature increased to ～1.0×10⁵ K, while the bolometric flux dropped by a factor of ～1.5(F _{h, bol}/F _{g, bol} ≈ 0.7). In the B-V, U diagram, the points referring to this so-called quiescent state form a separate group shifted in B-V from all the remaining ones located in a horizontal strip with $\Delta U \approx 3\mathop .\limits^m 5$ and $\Delta (B - V) \approx 0\mathop .\limits^m 4$ . This allows us to diagnose the state of the hot component without spectroscopic observations of the star. In October 1993, the hot component flared up again. The main brightness rise took no more than 19 days. The outburst occurred shortly before eclipse egress of the hot component, whose duration was ～0.01P _orb. In December 1993, F _{h, bol}/F _{g, bol}≤1.5 at maximum light. During the recurrent, even stronger outburst in April 1995, F _{h, bol}/F _{g, bol}≤3.4. The Hαline during outbursts has a P Cyg profile and broad wings stretching to velocities of ±1500 km s^?1. The color temperature of the active hot component at short optical wavelengths and in the ultraviolet lies in the range of effective temperatures for hot supergiants. Nevertheless, it always produces an H II region in the circumstellar envelope that is larger in size than this binary system.     

Generation of internal waves in the sea by local perturbations of wind and density flows on the surface

On the basis of a nonlinear model taking into account viscosity, density diffusion, and currents, we perform the numerical analysis of propagation of perturbations formed in the abyssal part of the Black Sea as a result of the action of tangential wind stresses or density flows in the form of a strip on the sea surface. It is shown that, in the course of time, in the region of the bottom slope, these perturbations generate a train of waves in the sea, which causes oscillations of the fields of density and currents. There are some differences between the generation of internal waves by the flows of density and the wind. Unlike the wind action, in the presence of flows of density in the upper layer in the region of the strip, the initial period of generation is characterized by the formation of intense perturbations without train structure. Translated by Peter V. Malyshev and Dmitry V. Malyshev