Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.     

Détermination indirecte des limites d'Atterberg par gravimétrie dynamique

This study presents a new method for Atterberg limits measurements using dynamic drying. Indeed, for some polluted clays, or clay mixtures, classical methods cannot be used. The principle of liquid $(W_{\mathrm{L}})$ and plasticity $(W_{\mathrm{P}})$ limits determination by this method is presented. Experimental values for classical clays are close to those obtained with Casagrande's methods, allowing for larger physical mud characterisation. To cite this article: C. Proust et al., C. R. Geoscience 336 (2004).     

Effects of industrial outfalls on tropical macrobenthic sediment communities in Reunion Island (Southwest Indian Ocean)

Temporal changes in the composition of soft bottom macrobenthic assemblages at Reunion Island (Southwest Indian Ocean) were studied in the context of a long-term environmental monitoring programme studying the impacts of effluents of industrial sugar cane refineries that are transferred to shallow and deep coastal environments by different pathways: surface discharge and deep underground injection. Seven stations (between 20 and 160 m depth) were surveyed between 1994 and 2003 on the industrial zone. One additional station was surveyed on a reference site. Spatio-temporal changes in the composition of macrobenthic communities were assessed using several diversity indices, ABC curves, MDS and associated ANOSIM tests and biotic indices. Among the 171 taxa recorded, polychaetes were dominant (89 species), followed by crustaceans and molluscs. The analysis of spatial changes in the composition of macrobenthos showed the existence of distinct benthic communities along the depth gradient. Temporal changes in macrobenthos composition were most prominent at the shallowest station. They mainly corresponded to the decline of several initially dominant taxa and the increase of the Eunicid polychaete Diopatra cuprea. This station further showed increasing macrofaunal abundance, biomass and sediment organic content over time, concomitant with decreasing sediment grain sizes. In deeper environments, temporal changes were much smaller. Macrofaunal abundance and species richness increased progressively, suggesting a moderate impact on benthic ecosystems resulting from slight enrichments due to effluents rich in organic matter. Our results highlight an original response to disturbance pattern involving opportunistic Eunicidae species (D. cuprea) not previously described. Moreover, they allow for the comparison of the impact on macrofauna caused by industrial effluents exported by two distinct and different pathways in a tropical coastal high-energy marine environment.     

Gravity and Inertia-Gravity Internal Waves: Breaking Processes and Induced Mixing

Internal gravity waves, whether influenced or not by the Earths rotation, are ubiquitous dynamical features in the stratosphere and in the interior of the ocean. We review the mechanisms by which such waves may break when propagating in an infinite (possibly moving) fluid with uniform stratification. The methods and models used to quantify mixing in a stably-stratified fluid are next recalled. The mixing properties induced by the breaking waves as obtained from several field, experimental and numerical experiments reported in the literature are presented.     

Nutrient and microbial dynamics in eutrophying shrimp ponds affected or unaffected by vibriosis

A field survey was conducted on two intensive shrimp farms using similar technical practices: one (DF) historically affected by a vibriosis, the other (HC) in which the pathogen has been observed although no mortality event has occurred. Because historical data suggest that eutrophication process may directly or indirectly play a role in the disease outbreak, we focussed our research on its dynamics. A higher variability of the phytoplanktonic compartment linked to an imbalance in the molar N:P ratio was observed in farm DF compared to farm HC, implying a modification on the linkage between the bacteria and phytoplankton compartments at DF. The beginning of the mortality outbreak at DF followed a shift from pico- to nanophytoplankton. The organic matter mineralization process at the water-sediment interface may explain the disturbance observed in the water column during eutrophication. The consequences of this disturbance on shrimps’ health status and pathogen ecology are discussed.     

Incorporating landscape features to obtain an object‐oriented landscape drainage network representing the connectivity of surface flow pathways over rural catchments

A topological representation of a rural catchment is proposed here in addition to the generally used topographic drainage network. This is an object‐oriented representation based on the identification of the inlets and outlets for surface water flow on each farmer's field (or plot) and their respective contributing areas and relationships. It represents the catchment as a set of independent plot outlet trees reaching the stream, while a given plot outlet tree represents the pattern of surface flow relationships between individual plots. In the present study, we propose to implement functions related to linear and surface elements of the landscape, such as hedges or road networks, or land use, to obtain what we call a landscape drainage network which delineates the effective contributing area to the stream, thus characterizing its topological structure. Landscape elements modify flow pathways and/or favour water infiltration, thus reducing the area contributing to the surface yield and modifying the structure of the plot outlet trees. This method is applied to a 4·4‐km² catchment area comprising 43 955 pixels and 312 plots. While the full set of 164 plot outlet trees, with an average of 7 plots per tree, covers 100% of the total surface area of the catchment, the landscape drainage network comprises no more than 37 plot outlet trees with an average of 2 plots per tree, accounting for 52 and 7% of the catchment surface area, when taking account of linear elements and land use, respectively. This topological representation can be easily adapted to changes in land use and land infrastructure, and provides a simple and functional display for intercomparison of catchments and decision support regarding landscape and water management. Copyright © 2011 John Wiley & Sons, Ltd.     

Distribution of petroleum hydrocarbons and organochlorinated contaminants in marine biota and coastal sediments from the ROPME Sea Area during 2005

The composition and spatial distribution of various petroleum hydrocarbons (PHs), comprising both aliphatic and polycyclic aromatic hydrocarbons (PAHs), and selected chlorinated pesticides and PCBs were measured in biota and coastal sediments from seven countries in the Persian Gulf and the Gulf of Oman (Bahrain, Iran, Kuwait, Oman, Qatar, Saudi Arabia and the United Arab Emirates). Evidence of extensive marine contamination with respect to organochlorinated compounds and PHs was not observed. Only one site, namely the BAPCO oil refinery in Bahrain, was considered to be chronically contaminated. Comparison of the results from this survey for Σ DDTs and Σ PCBs in rock oysters from the Gulf of Oman with similar measurements made at the same locations over the past two decades indicates a temporal trend of overall decreasing Σ PCB concentrations in oysters, whereas Σ DDTs levels have little changed during that period.