Major element geochemistry of purple soils/rocks in the red Sichuan Basin, China: implications of their diagenesis and pedogenesis

Major element compositions and chemical weathering features of the purple soils and their corresponding rocks in the Red Sichuan Basin, China were studied in this paper to infer the diagenetic features of the purple rocks and the pedogenetic features of the purple soils. The results showed that all of the rock and soil samples, except those from Yibin, have strongly similar major element compositions and the distribution patterns of their major element compositions are similar to those of the upper continental crust. Chemical index of alteration, chemical index of weathering and Na₂O/K₂O indicate that the purple soils and rocks have similar chemical weathering intensities, whereas the Al₂O₃–CaO* + Na₂O–K₂O (A–CN–K) relationship, suggests that chemical weathering was strong during diagenesis of the purple rocks, but weak during pedogenesis of the purple soils. Variations in major element compositions of the purplish rock samples, except that from Yibin, do not primarily reflect differences in compositions of the sediment source, sediment recycling and potassium metasomatism, and therefore the effects of chemical weathering on the major element compositions were mainly dependent on climate condition and the residence time of material exposed to chemical weathering. Chemical weathering of the purple rocks reached only moderate degrees under the general influence of warm and humid climate during Jurassic and Cretaceous. Warmer and more humid climate conditions partly resulted in stronger chemical weathering of rocks in the southern region of the basin than in the central and western region, whereas shorter residence time of material in upslope position partly resulted in weaker chemical weathering of rocks in the eastern region than in the central and western region. The same climate and stable tectonic setting led to comparable chemical weathering intensities of rocks in the Ziliujing and Jiaguan Formations. Gradually colder and dryer climate from Early Jurassic to Middle Jurassic then to Late Jurassic and shorter residence time in tectonically active setting of Middle Jurassic and late Late Jurassic resulted in the following order of chemical weathering intensity of the purple Jurassic rocks: Ziliujing Formation ? Shaximiao Formation ≈ Suining Formation > Penglaizhen Formation.     

Estimation of the methane flux from mud volcanoes along Chishan Fault,southwestern Taiwan

Because of the increasing public awareness of the greenhouse effect, geological emissions of methane (GEM) have gained more attention. The Intergovernmental Panel on Climate Change included GEM in the natural sources of methane category in the Fourth Assessment Report in 2007. The methane flux from mud volcanoes (MVs) is the second leading source within GEM. However, given that gas flux from MVs has been measured directly only in Sicily and Azerbaijan, the global methane estimation is still a conservative assumption based on limited data. The behavior of MV activities is seldom reported. This study attempts to estimate annual methane emissions through MVs by using a video recorder to record MV activities along the Chishan Fault and determining the bubble size and flux rate of each MV. Observation results, after a 1 year observation period, indicate that the annual emissions of the 19 MVs along the Chishan Fault are 0.1–0.2% of the global methane flux from MVs, highlighting that the methane emission from these MVs should not be neglected. In addition, the continuous monitoring of a particular MV disclosed periodic characteristics of MV activities. These results manifest the spatial and temporal variations of MV activities along the Chishan Fault. The spatial variations are related to the extensional kinematics of the Chishan fault, while the temporal variation relates to the earth-tide-related MV activities. The estimated annual methane emissions from the study are far more than those of previous studies and are still considered conservative. Results of this study may provide valuable information for researchers attempting to estimate the quantity of GEM.     

The magmatic–hydrothermal transition—evidence from quartz phenocryst textures and endoskarn abundance in Cu–Zn skarns at the Empire Mine, Idaho, USA

Information about the magmatic to hydrothermal transition is preserved in late-stage features of quartz phenocrysts and endoskarn alteration in some Cu–Zn skarn deposits such as the Empire Mine in Idaho. Important features include: (1) quartz phenocrysts with strong resorption textures such as vermicular zones of igneous groundmass cutting primary quartz cathodoluminescence banding, (2) anomalous amounts of endoskarn (more than 50% of mineralized rock), (3) high F activities as evidenced by fluorite as an accessory mineral in igneous rocks, in alteration assemblages, and in fluid inclusions and by high F in hydroxyl sites in igneous biotite and amphibole, and (4) direct association of Zn, which normally is deposited distally at low temperature, with Cu in proximal locations and in endoskarn. These features are explained by the following model: (1) F lowers the solidus temperature of the magma, thus changing the timing, temperature, and duration of hydrothermal fluid exsolution. (2) Upon magmatic vapor saturation the F-rich hydrothermal fluids form bubbles that adhere to quartz phenocrysts and chemically corrode/tunnel into the quartz forming vermicular resorption textures. (3) F-rich hydrothermal fluids also promote the formation of endoskarn; silicic rocks are attacked by F-rich fluids in the same sense that carbonate wall rocks are dissolved by weakly to moderately acidic hydrothermal fluids. (4) Low fluid exsolution temperature facilitated by high F activity promotes high Zn/Cu ratios in proximal locations due to the solubility of Zn relative to Cu at lower temperatures. This model may be applicable at other localities such as the world-class Cu–Zn skarn Antamina mine, as well as some tin and rapakivi granites.     

Accurate Determination of Electron Densities in Active and Quiescent Prominences: the Mid-Infrared Advantage

We have analyzed all lines in the MIR (8 to 20 micron) spectra of a quiescent and two time-frames of an active prominence. In the quiescent prominence, in addition to those lines found by Zirker (1985), we have identified a higher excitation hydrogen line and two helium recombination lines. Accounting for instrumental broadening, we can further separate out the Doppler and the Stark contributions to the line width. The former yields maximum temperatures of 6200 K, 34000 K and 12000 K and the latter electric field strengths of 7, 17, and 10 V cm^-1 for the above prominences, respectively. We show that these electric fields when divided by 2.2 are equal to the normal electric field in Holtsmark's quasi-static Stark broadening theory. Hence, we obtain electron densities of N₃=2.4(0.3), 9.1(1.2), and 5.5(0.6) in units of 10¹⁰ cm^-3 respectively. Using the same assumptions as made by Zirker, namely, (1) the strongest line (7-6) is optically thin, (2) the population of the lower level (n=6) is determined by direct radiative recombination and photo-ionization, (3) the equality of proton and electron densities, and (4) the thickness of the prominence is at least 10⁸ cm, we derive a new inequality, N_e 1.83 × 10⁸ T^0.75 e^-2195/T. Substituting our maximum temperatures into the right-hand side, we find upper bound N_e values of 9, 43, and 30 in the same units as above. These upper bound values are comfortably higher than our measurement, unlike those of Zirker's derived from the same set of assumptions. We have also observed the helium recombination spectrum which has been postulated by Tandberg-Hanssen as one of three possible ways of equilibrating the triplet/singlet ratio. Surprisingly, it is present in the quiescent as well as in the active prominence. We show that no meaningful values can be found for the turbulent velocities by combining the helium with the hydrogen line widths.     

泥蚶(Tegillarca granosa)重组铁蛋白富集重金属离子的特性及化学传感器的研究

利用泥蚶(Tegillarca granosa)铁蛋白原核表达工程菌获得的重组铁蛋白,通过圆二色光谱分析蛋白二级结构,扫描电镜和电感耦合等离子质谱研究重组铁蛋白富集Fe~(2+)、Mn~(2+)、Cd~(2+)、Cr~(3+)、Hg~(2+)、Pb~(2+)和As~(3+)等7种重金属离子的特性,同时探索利用重组铁蛋白修饰丝网印刷电极,设计和制备重组铁蛋白检测Pb~(2+)和Cd~(2+)浓度的电化学生物传感器。结果表明复性成功的铁蛋白多为完整的?-螺旋结构,而复性不成功的蛋白聚集体则多为无规卷曲。重组铁蛋白的直径和形态与富集的离子种类有关。泥蚶铁蛋白对单一金属离子Fe~(2+)和Mn~(2+)的富集凸显优势。对两种混合金属离子的富集大多表现为竞争关系。但重组铁蛋白对Hg~(2+)和As~(3+)混合组的富集量明显高于单一金属离子组的富集量,对Hg~(2+)和As~(3+)混合组的富集表现出协同促进作用。重组铁蛋白传感器对Pb~(2+)和Cd~(2+)溶液的最低检测限为10μg/L。     

Optimal seismic retrofit model for steel moment resisting frames with brittle connections

Based on performance-based seismic engineering, this paper proposes an optimal seismic retrofit model for steel moment resisting frames (SMRFs) to generate a retrofit scheme at minimal cost. To satisfy the acceptance criteria for the Basic Safety Objective (BSO) specified in FEMA 356, the minimum number of upgraded connections and their locations in an SMRF with brittle connections are determined by evolutionary computation. The performance of the proposed optimal retrofitting model is evaluated on the basis of the energy dissipation capacities, peak roof drift ratios, and maximum interstory drift ratios of structures before and after retrofitting. In addition, a retrofit efficiency index, which is defined as the ratio of the increment in seismic performance to the required retrofitting cost, is proposed to examine the efficiencies of the retrofit schemes derived from the model. The optimal seismic retrofit model is applied to the SAC benchmark examples for threestory and nine-story SMRFs with brittle connections. Using the retrofit efficiency index proposed in this study, the optimal retrofit schemes obtained from the model are found to be efficient for both examples in terms of energy dissipation capacity, roof drift ratio, and maximum inter-story drift ratio.     

Convection in rotating annular channels heated from below. Part 1. Linear stability and weakly nonlinear mean flows

Convection in a Boussinesq fluid in an annular channel rotating about a vertical axis with lateral rigid sidewalls, stress-free top and bottom, uniformly heated from below is investigated. The sidewalls are assumed to be either perfectly insulating or conducting. Three different types of convection are identified when the channel is rotating sufficiently fast: (i) global oscillatory convection preferred for small Prandtl numbers in channels with intermediate or large aspect ratios (width to height ratio), (ii) wall-localized oscillatory convection representing the most unstable mode for moderate or large Prandtl numbers in channels with intermediate or large aspect ratios and (iii) global stationary convection preferred in channels with sufficiently small aspect ratios regardless of the size of the Prandtl number. The corresponding weakly nonlinear problem describing differential rotation and meridional circulation is also examined, showing that geostrophic, multiple-peaked (two prograde and two retrograde) differential rotation can be maintained by the Reynolds stresses in wall-localized convective eddies in a rapidly rotating channel.     

The Relation Between Humidity and Liquid Water Content in Fog: An Experimental Approach

Microphysical measurements of orographic fog were performed above a montane cloud forest in northeastern Taiwan (Chilan mountain site). The measured parameters include droplet size distribution (DSD), absolute humidity (AH), relative humidity (RH), air temperature, wind speed and direction, visibility, and solar short wave radiation. The scope of this work was to study the short term variations of DSD, temperature, and RH, with a temporal resolution of 3?Hz. The results show that orographic fog is randomly composed of various air volumes that are intrinsically rather homogeneous, but exhibit clear differences between each other with respect to their size, RH, LWC, and DSD. Three general types of air volumes have been identified via the recorded DSD. A statistical analysis of the characteristics of these volumes yielded large variabilities in persistence, RH, and LWC. Further, the data revealed an inverse relation between RH and LWC. In principle, this finding can be explained by the condensational growth theory for droplets containing soluble or insoluble material. Droplets with greater diameters can exist at lower ambient RH than smaller ones. However, condensational growth alone is not capable to explain the large observed differences in DSD and RH because the respective growth speeds are too slow to explain the observed phenomena. Other mechanisms play key roles as well. Possible processes leading to the large observed differences in RH and DSD include turbulence induced collision and coalescence, and heterogeneous mixing. More analyses including fog droplet chemistry and dynamic microphysical modeling are required to further study these processes. To our knowledge, this is the first experimental field observation of the anti-correlation between RH and LWC in fog.     

Geospatial-temporal analysis of land-use changes in the Yellow River Delta during the last 40 years

Research on land use/land cover changes (LUCC)has been the core project of the Global EnvironmentalChanges since the 1990s[1—6]. Scientists at home andabroad have been laying emphasis on integrationstudies on land-use change by “space and process”features[7—10] as researches on LUCC are in a greatdeal. It is of paramount important for us to studyLUCC at various spatial-temporal scales and build aquantitative assessment of land-use conversion by in-tegrated spatial-temporal features. …     

Late Quaternary Activity of the Chuxiong-Nanhua Fault and the 1680 Chuxiong MS6 ¾ Earthquake

In this paper, according to the results of the satellite imagery interpretation and field investigation, we study the active features and the latest active times of the Chuxiong-Nanhua fault, the Quaternary basins formation mechanism, and the relationship between the fault and the 1680 Chuxiong M_S6 ¾ earthquake. Several Quaternary profiles at Lvhe, Nanhua reveal that the fault has offset the late Pleistocene deposits of the T2 and T3 terraces of Longchuan river, indicating that the fault was obviously active in late Quaternary. The Chuxiong-Nanhua fault has been dominated by dextral strike slip motion in the late Quaternary, with an average rate of 1.6-2.0mm/a. Several pull apart Quaternary basins of Chuxiong, Nanhua, and Ziwu etc. have developed along the fault. The 1680 Chuxiong M_S6 ¾ earthquake and several moderate earthquakes have occurred near the fault. The Chuxiong-Nanhua fault are the seismogenic structure of those earthquakes, the latest fault movement was in the late-Pleistocene, and even the Holocene. In large area, the Chuxiong-Nanhua fault and the eastern Qujiang fault and the Shiping fault composed a set of NW-trending oblique orientation active faults, and the motion characteristics are all mainly dextral strike slip. The motion characteristics, like the red river fault of the Sichuan-Yunnan Rhombic Block southwestern boundary, are concerned with the escaping movement of the Sichuan-Yunnan Rhombic Block.