Methylmercury cycling in sediments on the continental shelf of southern New England

Exposure of humans to monomethylmercury (MMHg) occurs primarily through consumption of marine fish, yet there is limited understanding concerning the bioaccumulation and biogeochemistry of MMHg in the biologically productive coastal ocean. We examined the cycling of MMHg in sediments at three locations on the continental shelf of southern New England in September 2003. MMHg in surface sediments is related positively to inorganic Hg (Hg(II) = total Hg − MMHg), the geographical distribution of which is influenced by organic material. Organic matter also largely controls the sediment-water partitioning of Hg species and governs the availability of dissolved Hg(II) for methylation. Potential gross rates of MMHg production, assayed by experimental addition of ²⁰⁰Hg to intact sediment cores, are correlated inversely with the distribution coefficient (K_D) of Hg(II) and positively with the concentration of Hg(II), most probably as HgS⁰, in 0.2-μm filtered pore water of these low-sulfide deposits. Moreover, the efflux of dissolved MMHg to overlying water (i.e., net production at steady state) is correlated with the gross potential rate of MMHg production in surface sediments. These results suggest that the production and efflux of MMHg from coastal marine sediments is limited by Hg(II), loadings of which presumably are principally from atmospheric deposition to this region of the continental shelf. The estimated diffusive flux of MMHg from the shelf sediments averages 9 pmol m⁻² d⁻¹. This flux is comparable to that required to sustain the current rate of MMHg accumulation by marine fish, and may be enhanced by the efflux of MMHg from near-shore deposits contaminated more substantially with anthropogenic Hg. Hence, production and subsequent mobilization of MMHg from sediments in the coastal zone may be a major source of MMHg to the ocean and marine biota, including fishes consumed by humans.     

Observations of coronal disturbances from 1 to 9 R ⊙

Solar Physics - Hα, white-light and radio observations of a coronal disturbance on 1973 January 11 commencing at about 00h36m UT show that a piston-driven shock wave propagated outwards...     

Hormone loads exported by a tile‐drained agroecosystem receiving animal wastes

Little is known regarding hormone export from tile‐drained agricultural fields despite the widespread presence of tile drains in the Midwestern United States. By intensively measuring water flow rates and hormone concentrations in four subsurface tile drains and three receiving ditches at a working Midwest farm, hormone fluxes and loads from the tile‐drained fields were quantified. Before and during the 17‐month study period (January 2009 – May 2010), the associated farm fields received various animal waste applications (beef, dairy, poultry, sheep, and swine). Hormones monitored included the estrogens17β‐ and 17α‐estradiol, estrone, and estriol; the natural androgens testosterone, and androstenedione; and the synthetic androgens 17β‐ and 17α‐trenbolone, and trendione. Hormone loads measured in the ditches for three drainage areas during the entire 17‐month study period were in ranges of 16–58 mg/ha for total estrogens, 6.8–19 mg/ha for natural androgens, and 4.2–44 mg/ha for synthetic androgens. Because higher hormone concentrations generally occurred during discrete periods of increased flow, high flow rates often were associated with a disproportionately high hormone flux. For example, 80% of total estrogens and natural androgens exported into the ditches occurred during only 9–26% of the study period, coinciding with the most significant storm events. In addition, hormone fluxes were highest during storm events that occurred shortly after animal waste applications. Therefore, to effectively reduce hormone loads exported to downstream aquatic ecosystems in the absence of any application reduction, the short periods during which high‐flow events occur must be targeted. Copyright © 2012 John Wiley & Sons, Ltd.     

Petrogenesis of the Dar al Gani (DaG) 1.1 Ma ejection-paired olivine-phyric shergottites and implications for ~470 Ma Martian volcanism

The Dar al Gani (DaG) olivine-phyric shergottites share mineralogical and geochemical characteristics, which confirm that these meteorites are derived from a single source. Bulk trace elements (La/Yb—0.12), in situ maskelynite ⁸⁷Sr/⁸⁶Sr (~0.7014) and redox estimates (FMQ ~ −2) indicate derivation from a depleted, reduced mantle reservoir; identical to all ~470 Ma shergottites ejected at 1.1 Ma. The DaG shergottites have been variably affected by terrestrial alteration, which precipitated carbonate along fractures and modified bulk-rock fluid mobile (e.g., Ba) elements. Nonetheless, sufficient data are available to construct a multi-stage formation model for the DaG shergottites and other 1.1 Ma ejection-paired shergottites that erupted at ~470 Ma. First, partial melting of a depleted mantle source occurred at 1540 ± 20°C and 1.2 ± 0.1 GPa, equivalent to > ~100 km depth. Then, initial crystallization in a staging chamber at ~85 km depth at the crust–mantle boundary took place, followed by magma evolution and variable incorporation of antecrystic olivine ± orthopyroxene. Subsequently, crystallization of olivine phenocrysts and re-equilibration of olivine antecrysts occurred within an ascending magma. Finally, magmas with variable crystal loads erupted at the surface, where varied cooling rates produced a range of groundmass textures. This model is similar to picritic flood basalt magmas erupted on Earth.     

Bridge Monitoring and Performance Evaluation

Over fifty percent of our nation’s 560,000-plus bridges are obsolete or structurally deficient. To upgrade or replace these structures would require a serious budget. In order to shorten this list of bridges and to improve their ratings, state DOTs are investigating new repair techniques and better performance evaluation tools in order to implement the new drive to sustainability within the infrastructure. The research presented herein focused on the evaluation of current US bridge analysis and rating procedures for the North Carolina Department of Transportation (NCDOT). To evaluate these procedures, several bridges were rated with commercially available software and a newly developed spreadsheet program. In parallel, the bridges were also load tested for comparison, from which, it was concluded that the NCDOT’s bridge rating software directly follows the latest AASHTO requirements. The experimental results, however, also proved that the bridges had significant strength reserves associated to several factors, such as, girder/deck composite action, impact and distribution factors, material strength, and contribution of non-structural elements. In this research, a simplified bridge testing protocol was developed from which it was concluded, that a relatively simple instrumentation setup could be effective in the load rating of bridges through testing. The data gathered through these instruments provide vital performance data for normal traffic conditions, as well as during extreme loading conditions and evacuations, which could lead to less restrictive load ratings and removal of the structurally deficient classification, yielding a more sustainable structure.     

Sedimentary stable carbon isotope evidence of late Quaternary vegetation and climate change in highland Costa Rica

Continuous terrestrial records of paleoclimate and paleovegetation that extend to the late Pleistocene are rare for the circum-Caribbean uplands. In this study we analyzed the bulk and compound-specific carbon isotope composition of lake sediments spanning this period from Lago de las Morrenas 1 (LM1), a glacial lake in the highlands of southern Costa Rica, for evidence of climate and vegetation changes that may not have been apparent in previous analyses. The stable carbon isotope ratios of n-alkanes typically derived from terrestrial plants (δ¹³C_C27–C33) indicate an increased abundance of C₄ plant taxa during the late Pleistocene and earliest Holocene that may be related to decreased atmospheric carbon dioxide concentrations, increased aridity, or habitat availability. These n-alkane isotope ratios also provide evidence of more arid conditions during the early and late Holocene, and more mesic conditions during the middle Holocene, a pattern prevalent in other paleoclimate records from the region that is thought to be related to millennial-scale dynamics of the intertropical convergence zone (ITCZ). The sensitivity of the LM1 paleorecord to trade wind dynamics provides further support for the role of millennial-scale shifts in ITCZ dynamics in driving neotropical environmental change, and indicates that the effects of ITCZ migration were not limited to the lowlands.     

X-ray observations of a major eruptive flare behind the limb

We analyze X-ray images and spectra of a coronal structure which extended to altitudes over 130 000 km above an eruptive flare located 20° behind the western solar limb. The images were obtained by the Flat Crystal Spectrometer (FCS) and the spectra were obtained by the Bent Crystal Spectrometer (BCS) aboard the SMM spacecraft. Images in Oviii and Mgxi lines cover the period from before the flare onset (which occurred at 22:31 UT on 16 February, 1986) through 17 UT on 17 February and were used for determination of temperature and emission measure within the structure. BCS obtained Caxix spectra of the coronal event, benefiting from the occultation of the active region behind the solar limb.The BCS data show, and FCS data confirm, that the temperature, after an initial rise and decline, stayed almost constant for many hours after 04:30 UT on 17 February. This may indicate that initially we observed the rise and decay of post-flare loops, but later the X-ray emission came predominantly from a post-flare giant arch that formed above them. This has been observed in many previous cases. However, a comparison with other events characterized by very high post-flare loops, such as those that occurred on 29 July, 1973 (Skylab data) and on 14 February, 1986 (from this same region), suggests that we may be observing the same system of slowly growing groups all the time. Therefore, we suggest a third possibility, i.e., that such anomalously high loop systems first behave like post-flare loops but gradually take over some characteristics of a post-flare giant arch. The Soft X-ray Telescope aboardYohkoh, with spatial resolution improved by nearly an order of magnitude, might be able to check up on the development of such large-scale coronal structures if proper observational modes are applied after the occurrence of major eruptive flares.Deceased 1 June, 1993.     

Radio and visible-light observations of a coronal arcade transient

We discuss simultaneous visible-light and radio observations of a coronal transient that occurred on 9 April, 1980. Visible-light observations of the transient and the associated erupting prominence were available from the Coronagraph/Polarimeter carried aboard SMM, the P78-1 coronagraph, and from the Haleakala Observatory. Radio observations of the related type III-II-IV bursts were available from the Clark Lake and Culgoora Observatories. The transient was extremely complex; we suggest that an entire coronal arcade rather than just a single loop participated in the event. Type III burst sources observed at the beginning of the event were located along a nearby streamer, which was not disrupted, but was displaced by the outmoving loops. The type II burst showed large tangential motion, but unlike such sources usually do, it had no related herringbone structure. A moving type IV burst source can be associated with the most dense feature of the white-light transient.     

Numerical modelling of the improvements to primary and creep settlements offered by granular columns

Analytical vibro-replacement design approaches typically quantify the settlement reduction using a dimensionless settlement improvement factor, defined as the ratio of the settlements without and with treatment. Most approaches do not explicitly consider the improvement to creep settlement. This is unfortunate because the ‘stone column’ technique is being increasingly used to reduce settlement and improve bearing capacity in soft normally consolidated and lightly overconsolidated cohesive soils (in which creep settlement tends to account for a significant proportion of the total settlement). Analytical design approaches typically consider primary settlement only. In this study, two-dimensional axisymmetric analyses have been carried out using PLAXIS 2D to establish the variation of improvement factor with time using different soil models, one of which incorporates creep behaviour. Two different approaches have been used to establish the influence of creep on predicted settlement improvement factors. The first approach is based on a direct comparison of two different soil models (one of which incorporates creep) whereas the second approach is based solely on the model incorporating creep. The settlement improvement factors have been evaluated for different area-replacement ratios, modular ratios and column lengths. The primary settlement improvement factors are in good agreement with some of the more popular analytical design methods while the creep settlement improvement factors are either equivalent or lower (depending on the approach used). The primary settlement improvement factors show a dependence on the modular ratio whereas it appears that the corresponding creep settlement improvement factors are relatively independent of it.     

Changing climate, changing process: implications for salt transportation and weathering within building sandstones in the UK

Salt weathering is a crucial process that brings about a change in stone, from the scale of landscapes to stone outcrops and natural building stone façades. It is acknowledged that salt weathering is controlled by fluctuations in temperature and moisture, where repeated oscillations in these parameters can cause re-crystallisation, hydration/de-hydration of salts, bringing about stone surface loss in the form of, for example, granular disaggregation, scaling, and multiple flaking. However, this ‘traditional’ view of how salt weathering proceeds may need to be re-evaluated in the light of current and future climatic trends. Indeed, there is considerable scope for the investigation of consequences of climate change on geomorphological processes in general. Building on contemporary research on the ‘deep wetting’ of natural building stones, it is proposed that (as stone may be wetter for longer), ion diffusion may become a more prominent mechanism for the mixing of molecular constituents, and a shift in focus from physical damage to chemical change is suggested. Data from ion diffusion cell experiments are presented for three different sandstone types, demonstrating that salts may diffuse through porous stone relatively rapidly (in comparison to, for example, dense concrete). Pore water from stones undergoing diffusion experiments was extracted and analysed. Factors controlling ion diffusion relating to ‘time of wetness’ within stones are discussed, (continued saturation, connectivity of pores, mineralogy, behaviour of salts, sedimentary structure), and potential changes in system dynamics as a result of climate change are addressed. System inputs may change in terms of increased moisture input, translating into a greater depth of wetting front. Salts are likely to be ‘stored’ differently in stones, with salt being in solution for longer periods (during prolonged winter wetness). This has myriad implications in terms of the movement of ions by diffusion and the potential for chemical change in the stone (especially in more mobile constituents), leading to a weakening of the stone matrix/grain boundary cementing. The ‘output’ may be mobilisation and precipitation of elements leading to, for example, uneven cementing in the stone. This reduced strength of the stone, or compromised ability of the stone to absorb stress, is likely to make crystallisation a more efficacious mechanism of decay when it does occur. Thus, a delay in the onset of crystallisation while stonework is wet does not preclude exaggerated or accelerated material loss when it finally happens.