A comparison of ozone and chlorine toxicity to three life stages of the American oyster Crassostrea virginica

The effects of ozone-produced oxidants (OPO) on three developmental stages of the American oyster, Crassostrea virginica, were evaluated. Both straight-hinge (48-h post fertilisation) and setting pediveliger larvae were exposed to a series of OPO concentrations ranging from 0·05 to 0·30 mg/litre OPO (as total residual chlorine) at 25°C for 96 h. Mortality was used as the response parameter and results were quantitatively compared with the effects of chlorine-produced oxidants (CPO) obtained from the literature on these same developmental stages. Adult oysters (2- to 4-year class) were exposed to OPO concentrations ranging from 0·01 to 0·50 mg/litre at 15°C for 5 days and to the same concentration range at 25°C for two consecutive 6-day periods. Shell deposition and faecal matter accumulation were used as the response parameters for this stage.Straight-hinge larvae were significantly more sensitive to OPO than setting pediveliger larvae. Both larval stages were significantly more sensitive to CPO than to OPO. Shell deposition was significantly inhibited at all OPO concentrations for both 15°C and 25°C acclimated adult oysters. No significant differences were found between the shell deposition response of oysters at the two acclimation temperatures. Faecal matter accumulation was significantly reduced at OPO concentrations ≥ 0·05 mg/litre at both 15°C and 25°C. It was significantly (p < 0·05) greater for 25°C acclimated oysters than for 15°C acclimated oysters at OPO concentrations < 0·10 mg/litre but not at higher concentrations.     

The dust distribution within the inner coma of comet P/Halley 1982i: encounter by Giotto's impact detectors

Analysis of the data from Giotto's Dust Impact Detection System experiment (DIDSY) is presented. These data represent measurement of the size of dust grains incident on the Giotto dust shield along its trajectory through the coma of comet P/Halley on 1986 March 13/14. First detection occurred at some 287000 km distance from the nucleus on the inbound leg; the majority of the DIDSY subsystems remained operational after closest approach (604 km) yielding the last detection at about 202000 km from the nucleus. In order to improve the data coverage (and especially for the smallest grains, to approximately 10(-19) kg particle mass), data from the PIA instrument has been combined with DIDSY data. Flux profiles are presented for the various mass channels showing, to a first approximation, a 1/R2 flux dependence, where R is the distance of the detection point from the cometary nucleus, although significant differences are noted. Deviations from this dependence are observed, particularly close to the nucleus. From the flux profiles, mass and geometrical area distributions for the dust grains are derived for the trajectory through the coma. Groundbased CCD imaging of the dust continuum in the inner coma at the time of encounter is also used to derive the area of grains intercepted by Giotto. The results are consistent with the area functions derived by Giotto data and the low albedo of the grains deduced from infrared emission. For the close encounter period (-5 min to +5 min), the cumulative mass distribution function has been investigated, initially in 20 second periods; there is strong evidence from the data for a steepening of the index of the mass distribution for masses greater than 10(-13) kg during passage through dust jets which is not within the error limits of statistical uncertainty. The fluences for dust grains along the entire trajectory is calculated; it is found that extrapolation of the spectrum determined at intermediate masses (cumulative mass index alpha = 0.85) is not able to account for the spacecraft deceleration as observed by the Giotto Radio Science Experiment and by ESOC tracking operations. Data at large masses (>10(-8) kg) recently analysed from the DIDSY data set show clear evidence of a decrease in the mass distribution index at these masses within the coma, and it is shown that such a value of the mass index can provide sufficient mass for consistency with the observed deceleration. The total particulate mass output from the nucleus of comet P/Halley at the time of encounter would be dependent on the maximum mass emitted if this change in slope observed in the coma were also applicable to the emission from the nucleus; this matter is discussed in the text. The flux time profiles have been converted through a simple approach to modeling of the particle trajectories to yield an indication of nucleus surface activity. There is indication of an enhancement in flux at t approximately -29 s corresponding to crossing of the dawn terminator, but the flux detected prior to crossing of the dawn terminator is shown to be higher than predicted by simple modelling. Further enhancements corresponding to jet activity are detected around +190 s and +270 s.     

A search for propylene oxide and glycine in Sagittarius B2 (LMH) and Orion

We have used the Mopra Telescope to search for glycine and the simple chiral molecule propylene oxide in the Sgr B2 (LMH) and Orion KL, in the 3-mm band. We have not detected either species, but have been able to put sensitive upper limits on the abundances of both molecules. The 3σ upper limits derived for glycine conformer I are  3.7 × 10¹⁴ cm⁻²  in both Orion-KL and Sgr B2 (LMH), comparable to the reported detections of conformer I by Kuan et al. However, as our values are 3σ upper limits rather than detections we conclude that this weighs against confirming the detection of Kuan et al. We find upper limits for the glycine II column density of  7.7 × 10¹² cm⁻²  in both Orion-KL and Sgr B2 (LMH), in agreement with the results of Combes et al. The results presented here show that glycine conformer II is not present in the extended gas at the levels detected by Kuan et al. for conformer I. Our ATCA results have ruled out the detection of glycine (both conformers I and II) in the compact hot core of the LMH at the levels reported, so we conclude that it is unlikely that Kuan et al. have detected glycine in either Sgr B2 or Orion-KL. We find upper limits for propylene oxide abundance of  3.0 × 10¹⁴ cm⁻²  in Orion-KL and  6.7 × 10¹⁴ cm⁻²  in Sgr B2 (LMH). We have detected fourteen features in Sgr B2 and four features in Orion-KL which have not previously been reported in the interstellar medium, but have not been able to plausibly assign these transitions to any carrier.     

Survey evaluations to assess marine bioinvasions

Countries need to know what species are present within their waters to effectively manage the issue of non-indigenous marine species. Five survey methods are currently employed to detect introduced marine species: the Hewitt and Martin protocols (66% of effort; 73 ports, 12 countries); Rapid Assessment Surveys (7% of effort; 8 regions, 4 countries); the Bishop Museum protocols (7% of effort; 8 ports, 3 countries); the Chilean aquaculture surveys (1% of effort; numerous regions; 1 country); and Passive Sampling protocols (18% of effort; 20 ports, 2 countries). These methods use either quantitative, qualitative, or a mixture of the two sampling techniques and tend to target locations that are potential inoculation sites (i.e., such as ports, marinas and aquaculture facilities). To date, introduced marine species surveys have been implemented in 19 countries and have detected more than 1185 non-indigenous, 735 cryptogenic and 15,315 native species.     

A place-based model for understanding community resilience to natural disasters

There is considerable research interest on the meaning and measurement of resilience from a variety of research perspectives including those from the hazards/disasters and global change communities. The identification of standards and metrics for measuring disaster resilience is one of the challenges faced by local, state, and federal agencies, especially in the United States. This paper provides a new framework, the disaster resilience of place (DROP) model, designed to improve comparative assessments of disaster resilience at the local or community level. A candidate set of variables for implementing the model are also presented as a first step towards its implementation.     

Abundance and fractionation of Al,Fe and trace metals following tidal inundation of a tropical acid sulfate soil

Tidal inundation was restored to a severely degraded tropical acid sulfate soil landscape and subsequent changes in the abundance and fractionation of Al, Fe and selected trace metals were investigated. After 5 a of regular tidal inundation there were large decreases in water-soluble and exchangeable Al fractions within former sulfuric horizons. This was strongly associated with decreased soil acidity and increases in pH, suggesting pH-dependent immobilisation of Al via precipitation as poorly soluble phases. The water-soluble fractions of Fe, Zn, Ni and Mn also decreased. However, there was substantial enrichment (2–5×) of the reactive Fe fraction (Fe_R; 1 M HCl extractable) near the soil surface, plus a closely corresponding enrichment of 1 M HCl extractable Cr, Zn, Ni and Mn. Surficial accumulations of Fe(III) minerals in the inter-tidal zone were poorly crystalline (up to 38% Fe_R) and comprised mainly of schwertmannite (Fe₈O₈(OH)₆SO₄) with minor quantities of goethite (α-FeOOH) and lepidocrocite (γ-FeOOH). These Fe (III) mineral accumulations provide an effective substrate for the adsorption/co-precipitation and accumulation of trace metals. Arsenic displayed contrary behaviour to trace metals with peak concentrations (∼60 μg g⁻¹) near the redox minima. Changes in the abundance and fractionation of the various metals can be primarily explained by the shift in the geochemical regime from oxic–acidic to reducing-circumneutral conditions, combined with the enrichment of reactive Fe near the soil surface. Whilst increasing sequestration of trace metals via sulfidisation is likely to occur over the long-term, the current abundance of reactive Fe near the sediment–water interface favours a dynamic environment with respect to metals in the tidally inundated areas.     

Paleomagnetic and rock magnetic results from the Twin Creek Formation (Middle Jurassic), Wyoming

A magnetization which passes the fold test has been observed in 73 limestone samples (10 sites) from the Middle Jurassic Twin Creek Formation. The pole calculated from the site mean poles is located at 68.4°N, 145.0°E (K = 31.8,A₉₅ = 8.7°). This pole lies in a segment of the North American apparent polar wander (APW) path for which there are only a few reliable poles in the literature. The results corroborate earlier studies which conclude that the Jurassic segment of the APW path does not include the present north pole. However, the position of the Twin Creek pole suggests that significantly more APW took place prior to the late Jurassic than previous studies indicated.     

The occurrence and distribution of tin with particular reference to marine environments

Concentrations of tin in sea water decreased from estuarine and shelf (0.02-0.04 μg/kg) to surface Atlantic waters (0.009 μg/kg). Mean contents (ppm) in other materials included: ultramafic rocks, 0.8; basalts, 1.7; silicic rocks, 2.5; red clays, 3.4; amphibolites, 1.2. Oceanic ferromanganese deposits contained from 0.2 to 5.8 ppm; tin and cobalt contents were correlated.