A New Natural Secondary Reference Material for Garnet U-Pb Dating by TIMS and LA-ICP-MS

Gem quality andradite-rich garnet (IUC-1), obtained from the Miocene trachyte dome near Ankara city (Turkey), has been identified as a potential natural secondary reference material for U-Pb dating. In this study, U-Pb dating was performed in five different laboratories using isotope dilution TIMS and laser ablation ICP-MS to determine the homogeneity of euhedral garnet crystals. The U-Pb ID-TIMS data for IUC-1 yielded ²⁰⁷Pb/²³⁵U and ²⁰⁶Pb/²³⁸U ages of 20.9 ± 0.4 and 20.6 ± 0.8 Ma respectively, and these values are consistent with U-Pb LA-ICP-MS analyses, in which different garnet crystals yielded ages of 20.8 ± 0.1, 20.7 ± 0.1, 20.7 ± 0.2 and 20.2 ± 0.1 Ma. An andradite (IUC-2) from the Serçeören wollastonite skarn (Turkey) can be used as a secondary reference material provided detailed imaging of the crystals is undertaken. ID-TIMS data yielded ²⁰⁷Pb/²³⁵U and ²⁰⁶Pb/²³⁸U ages of 20.4 ± 0.4 and 20.9 ± 1.0 Ma respectively, and yielded U-Pb ages on different grains of 20.5 ± 0.1, 20.7 ± 1.0, 20.8 ± 1.7 and 20.9 ± 1.6 Ma. The assigned weighted mean age of IUC-1 (20.4 ± 0.5 Ma, 2s) is proposed as a 2023 reference value. IUC-1 garnet is expected to contribute significantly to rapidly developing garnet geochronology in the near future.     

Subduction-related Late Cretaceous high-K volcanism in the Central Pontides orogenic belt: constraints on geodynamic implications

Mineral chemistry, major and trace elements, ⁴⁰Ar/³⁹Ar age and Sr–Nd–Pb isotopic data are presented for the Late Cretaceous Hamsilos volcanic rocks in the Central Pontides, Turkey. The Hamsilos volcanic rocks mainly consist of basalt, andesite and associated pyroclastics (volcanic breccia, vitric tuff and crystal tuff). They display shoshonitic and high-K calc-alkaline affinities. The shoshonitic rocks contain plagioclase, clinopyroxene, alkali feldspar, phlogopite, analcime, sanidine, olivine, apatite and titanomagnetite, whereas the high-K calc-alkaline rocks contain plagioclase, clinopyroxene, orthopyroxene, magnetite / titanomagnetite in microgranular porphyritic, hyalo-microlitic porphyritic and glomeroporphyritic matrix. Mineral chemistry data reveal that the pressure condition of the clinopyroxene crystallisation for the shoshonitic rocks are between 1.4 and 6.3 kbar corresponds to 6–18-km depth and the high-K calc-alkaline rocks are between 5 and 12 km. ⁴⁰Ar/³⁹Ar age data changing between 72 ± .5 Ma and 79.0 ± .3 Ma (Campanian) were determined for the Late Cretaceous Hamsilos volcanic rocks, contemporaneous with the subduction of the Neo-Tethyan Ocean beneath the Pontides. The studied volcanic rocks were enriched in the large-ion lithophile and light rare earth element contents, with pronounced depletion in the contents of high-field-strength elements. Chondrite-normalised rare earth element patterns (La_N/Lu_N = 6–17) show low to medium enrichment, indicating similar sources of the rock suite. Initial ⁸⁷Sr/⁸⁶Sr values vary between .70615 and .70796, whereas initial ¹⁴³Nd/¹⁴⁴Nd values change between .51228 and .51249. Initial ²⁰⁶Pb/²⁰⁴Pb values vary between 18.001 and 18.349, ²⁰⁷Pb/²⁰⁴Pb values between 15.611 and 15.629 and ²⁰⁸Pb/²⁰⁴Pb values between 37.839 and 38.427. The main solidification processes involved in the evolution of the volcanic rocks consist of fractional crystallisation, with minor amounts of crustal contamination ± magma mixing. According to geochemical evidence, the shoshonitic melts in the Hamsilos volcanic rocks were possibly derived from the low degree of partial melting of a subcontinental lithospheric mantle (SCLM), while the high-K calc-alkaline melts were derived from relatively high degree of partial melting of SCLM that was enriched by fluids and/or sediments from a subduction of oceanic crust.     

Significance of the Felsic Sub–Volcanics in Development of Related Au–Ag Deposits at Maden Village (Bolkar Mountain Region), South Turkey: Constraints from Whole–Rock Geochemistry,Geochronology and Pb-S Isotopes

Geotectonics - The Horoz granitoid and related felsic sub–volcanics located in the Inner Tauride Belt are key igneous rocks for understanding and investigating the collision and closure...     

Recycling waste from natural stone processing plants to stabilise clayey soil

For the countries with a developed stone industry the waste generated in the natural stone processing plants pose environmental and economic problems. The utilisation of stone waste in various areas is still under research. In addition, there are only a limited number of studies concerning the use of stone waste obtained from processing plants in the stabilisation of clayey soil. Furthermore, none of the studies in the literature investigated the effect of the characteristics of the stone on the stabilisation of the soil. This is the first study that compares the efficiency of the waste calcitic marble, dolomitic marble and granite powder as additives for the stabilisation of clayey soil. Artificial soil samples were prepared in the laboratory using bentonite and kaolinite. Natural stone waste powder was added to the soil samples at different percentages, and the index and compaction parameters of the stabilised soil were analysed. The results showed that the types of waste powder used in this study, like lime, could be used as stabilisers. As the percentage of additives increased, the plasticity index of the clayey soil decreased and the physical properties of the soil changed from clay to silt. In terms of compaction parameters, the use of all types of natural waste powder in the study resulted in a decrease in the optimum water content and an increase in the maximum dry unit weight. The lowest optimum water content and the highest maximum dry unit weight were obtained from the dolomitic marble powder.     

Assessment of potential seismic hazard and site effect in Antakya (Hatay Province), SE Turkey

Antakya city is at risk because of strong earthquakes occurring in the area, and different soil conditions that can produce variation of the ground motion amplification. Microzonation of cities provides a basis for site-specific hazard analysis in urban settlements. In particular, seismic microzonation can be provided by means of detailed seismic assessment of the area, including earthquake recordings and geological studies. In this paper, we propose a preliminary microzonation map for the city of Antakya, based on the variation of the dominant periods and shear velocities of the sediments covering the area. The periods are retrieved from microtremor measurements conducted at 69 sites, using the horizontal-to-vertical spectral ratio technique. The results of microtremor analysis were compared with data obtained from refraction microtremor (ReMi) measurements at four profiles crossing the studied area. According to the classification of dominant periods, Antakya city can be divided into five zones, probably prone to different levels of seismic hazard. The shorter natural periods are in inner Antakya and both the sides of Asi River (i.e., northern and southern parts). The eastern and western parts of Antakya have maximum dominant periods. The V _s ³⁰ values were calculated by using the ReMi method along the profiles. Antakya city has V _s ³⁰ values in the range of category C of the national earthquake hazard reduction programme site classification.     

A field application for lime stabilization

This study presents the improvements achieved as a result of the lime stabilization application conducted by the joint effort of the Turkish Association of Lime Industrialists and the General Directorate of Rural Services on the 200 m long section of the Ankara Province Yukar? Yurtçu Village road where green and brown clays are dominant. The study also numerically demonstrates the impacts of these improvements on the road section based on the results of various laboratory and field tests. The lime stabilization in field conditions was performed with 5% lime for both clays and was applied as a 30 cm thick single layer. In the soaked California bearing-ratio (CBR) tests conducted in the laboratory, increases that reach up from 16 and 21 times compared to initial soaked CBR values were observed in green and brown clays, respectively, at the end of 28 days. The high increases observed in soaked CBR values would reduce the upper layer thickness of the roads. The similar improvements are also achieved in unconfined compression and plate loading tests. The comparisons performed with the plate loading tests clearly demonstrated the behavior of the surface to lime and its cure impact.     

Diverse tectonic settings of formation of the metaigneous rocks in the Jurassic metamorphic accretionary complexes (Refahiye,NE Turkey) and their geodynamic implications

Two isolated metamorphic accretionary complexes of Jurassic age, the Refahiye and Kurtlutepe metamorphic rocks, crop out as tectonic slices within the coeval suprasubduction-zone ophiolite at the southern margin of the Eastern Pontides (NE Turkey), close to the ?zmir-Ankara-Erzincan suture. The Refahiye metamorphic rocks are made up of greenschist, marble, serpentinite, phyllite and minor garnet amphibolite, garnet micaschist and metachert. The whole unit was metamorphosed under garnet-amphibolite-facies conditions and strongly retrogressed during exhumation. The Kurtlutepe metamorphic rocks consist of subgreenschist-facies metavolcanics, metavolcaniclastics, marble, calc-phyllite, and minor serpentinite and metachert. Metabasites in the Refahiye metamorphic rocks are represented by four distinct geochemical affinities: (i) cumulate “flavor,” (ii) alkaline oceanic island basalt (OIB), (iii) enriched mid-ocean ridge basalt (E-MORB) and (iv) tholeiitic island arc basalt (IAB). On the other hand, the Kurtlutepe metavolcanic rocks display only tholeiitic to calc-alkaline island arc geochemical affinities. The metabasic rocks with OIB affinities were interpreted as parts of the accreted oceanic islands, and those with E-MORB affinities as parts of accreted ridge segments close to oceanic islands and/or plume-distal mid-ocean ridges with a mantle previously metasomatized by plume components. The metabasic rocks with IAB affinities might have been derived from the overlying suprasubduction ophiolite and/or arc domain by a number of tectonic or sedimentary processes including tectonic slicing of accretionary complex and overlying fore-arc ophiolite, juxtaposition of the magmatic arc with subduction zone by strike slip faults, submarine gravity sliding and debris flows or subduction erosion. However, totally recrystallized nature of the metabasic rocks together with field relations does not allow any inference on the processes involved. The Kurtlutepe metavolcanic rocks might represent collided and accreted oceanic island arc with the subduction zone. Attempted subduction of an intraoceanic island arc may also explain the magmatic lull during Late Jurassic–Early Cretaceous in the Eastern Pontides.     

The impact of water resources development projects on water vapor pressure trends in a semi-arid region, Turkey

The aim of this study was to investigate long-term seasonal trends and decadal change patterns of monthly mean water vapor pressure (WVP) observation series at 16 meteorological stations scattered point-wisely over the Southeastern Anatolian Project (GAP) area in Turkey, where large-scale soil and water development projects have been put into practice since the 1970s. The record length of WVP observation series of each station varied between 31- and 41-years between 1962 and 2002. The monthly mean WVP observation series of each station was rearranged on seasonal basis. Sequential Mann–Kendall trend test, Sen’s slope estimator, and Spearman’s rank–order correlation tests were employed for detection of likely trends, and Kruskall–Wallis test was used to detect decadal variations in WVP series of each observation station. A possible area of representation for each meteorological station was determined by using the Thiessen polygons technique in a geographical information systems media. It was found that 15 seasonal WVP series have a positive trend covering 97% of the GAP area in the summer season; although one WVP series has a negative trend direction. However, in the spring season, 33% of the area had a positive trend, and a negative trend did not appear in any stations. WVP records in the winter season showed an increasing trend over 19% of the GAP area, whereas a decreasing trend prevailed in 9% of the area. The study results led us to conclude that the substantial increase of WVP observations in summer season could be attributed to both the shift from rain-fed agriculture to irrigated agriculture being made increasingly spacious year by year and building large water reservoirs in the GAP located in a semi-arid region. The results also indirectly suggested that the historical trends in the WVP parameters might be related to global climate change phenomenon.