Consistency of observed near surface temperature trends with climate change projections over the Mediterranean region

We examine the possibility that anthropogenic forcing (Greenhouse gases and Sulfate aerosols, GS) is a plausible explanation for the observed near-surface temperature trends over the Mediterranean area. For this purpose, we compare annual and seasonal observed trends in near-surface temperature over the period from 1980 to 2009 with the response to GS forcing estimated from 23 models derived from CMIP3 database. We find that there is less than a 5% chance that natural (internal) variability is responsible for the observed annual and seasonal area-mean warming except in winter. Using additionally two pattern similarity statistics, pattern correlation and regression, we find that the large-scale component (spatial-mean) of the GS signal is detectable (at 2.5% level) in all seasons except in winter. In contrast, we fail to detect the small-scale component (spatial anomalies about the mean) of GS signal in observed trend patterns. Further, we find that the recent trends are significantly (at 2.5% level) consistent with all the 23 GS patterns, except in summer and spring, when 9 and 5 models respectively underestimate the observed warming. Thus, we conclude that GS forcing is a plausible explanation for the observed warming in the Mediterranean region. Consistency of observed trends with climate change projections indicates that present trends may be understood of what will come more so in the future, allowing for a better communication of the societal challenges to meet in the future.     

Adsorption as a cause for iron isotope fractionation in reduced groundwater

Iron isotopes were used to investigate iron transformation processes during an in situ field experiment for removal of dissolved Fe from reduced groundwater. This experiment provided a unique setting for exploring Fe isotope fractionation in a natural system. Oxygen-containing water was injected at a test well into an aquifer containing Fe(II)-rich reduced water, leading to oxidation of Fe(II) and precipitation of Fe(III)(hydr)oxides. Subsequently, groundwater was extracted from the same well over a time period much longer than the injection time. Since the surrounding water is rich in Fe(II), the Fe(II) concentration in the extracted water increased over time. The increase was strongly retarded in comparison to a conservative tracer added to the injected solution, indicating that adsorption of Fe(II) onto the newly formed Fe(III)(hydr)oxides occurred. A series of injection-extraction (push-pull) cycles were performed at the same well. The δ⁵⁷Fe/⁵⁴Fe of pre-experiment background groundwater (−0.57 ± 0.17 ‰) was lighter than the sediment leach of Fe(III) (−0.24 ± 0.08 ‰), probably due to slight fractionation (only ∼0.3 ‰) during microbial mediated reductive dissolution of Fe(III)(hydr)oxides present in the aquifer. During the experiment, Fe(II) was adsorbed from native groundwater drawn into the oxidized zone and onto Fe(III)(hydr)oxides producing a very light groundwater component with δ⁵⁷Fe/⁵⁴Fe as low as −4 ‰, indicating that heavier Fe(II) is preferentially adsorbed to the newly formed Fe(III)(hydr)oxides surfaces. Iron concentrations increased with time of extraction, and δ⁵⁷Fe/⁵⁴Fe linearly correlated with Fe concentrations (R² = 0.95). This pattern was reproducible over five individual cycles, indicating that the same process occurs during repeated injection/extraction cycles. We present a reactive transport model to explain the observed abiotic fractionation due to adsorption of Fe(II) on Fe(III)(hydr)oxides. The fractionation is probably caused by isotopic differences in the equilibrium sorption constants of the various isotopes (K_ads) and not by sorption kinetics. A fractionation factor α_57/54 of 1.001 fits the observed fractionation.     

Petrology of potassic alkaline ultramafic and carbonatitic rocks from Planalto da Serra (Mato Grosso State), Brazil

The Planalto da Serra igneous rocks form plugs, necks and dykes of carbonate-rich ultramafic lamprophyres (aillikites and glimmerites with kamafugitic affinity) and carbonatites (alvikites and beforsites). Phlogopite and/or tetraphlogopite, diopside and melanitic garnet are restricted to aillikitic rock-types, whereas pyroclore occurs only in carbonatites. Aillikites and carbonatites are altered to hydrotermalites, having chlorite and serpentine as dominant minerals. Planalto da Serra igneous rock association has kamafugitic affinity (i.e. effusive, ultrapotassic. High LREE/HREE fractionation, incompatible elements data and Sr-Nd isotopes, suggest that the K-ultramafic alkaline and carbonatite rocks originated from a variably metasomatized mantle source enriched in radiogenic Sr. Crustal contamination is negligible or absent. Age values of 600 Ma rule out the geochronological relationship between the investigated intrusions and the Mesozoic alkaline bodies from the Azimuth 125° lineament. The TDM model ages allow to conclude that Planalto da Serra magma is derived from the partial melting of a mantle source metasomatised by K-rich carbonatated melt during the Early to Late Neoproterozoic. On the basis of alkaline magmatism repetitions at 600 Ma and 90–80 Ma we question the subsistence of a stationary mantle plume for so long time.     

On the structure of the low surface brightness dwarf galaxies in the M81 group

A detailed photometry of spheroidal dwarf galaxies in the M81 group has been carried out. The integral characteristics and the structural parameters of the spheroidal dwarfs has been determined. Their luminosity profiles are well fitted to a King law. The investigated spheroidal dwarfs together with the prototypes of the Local Group form a common sequence according to their main parameters. The observational data presented show that dSphs are not linked evolutionary with normal E and dE galaxies, but probably form a separate branch together with irregular low surface brightness dwarfs.