Removal of Volatile Organic Compounds in Vertical Flow Filters: Predictions from Reactive Transport Modeling

Vertical flow filters are containers filled with porous medium that are recharged from top and drained at the bottom, and are operated at partly saturated conditions. They have recently been suggested as treatment technology for groundwater containing volatile organic compounds (VOCs). Numerical reactive transport simulations were performed to investigate the relevance of different filter operation modes on biodegradation and/or volatilization of the contaminants and to evaluate the potential limitation of such remediation mean due to volatile emissions. On the basis of the data from a pilot‐scale vertical flow filter intermittently fed with domestic waste water, model predictions on the system’s performance for the treatment of contaminated groundwater were derived. These simulations considered the transport and aerobic degradation of ammonium and two VOCs, benzene and methyl tertiary butyl ether (MTBE). In addition, the advective‐diffusive gas‐phase transport of volatile compounds as well as oxygen was simulated. Model predictions addressed the influence of depth and frequency of the intermittent groundwater injection, degradation rate kinetics, and the composition of the filter material. Simulation results show that for unfavorable operation conditions significant VOC emissions have to be considered and that operation modes limiting VOC emissions may limit aerobic biodegradation. However, a suitable combination of injection depth and composition of the filter material does facilitate high biodegradation rates while only little VOC emissions take place. Using such optimized operation modes would allow using vertical flow filter systems as remediation technology suitable for groundwater contaminated with volatile compounds.     

Seasonal dynamics of zooplankton in Lake Huetzalin, Xochimilco (Mexico City, Mexico)

We quantified the seasonal changes in the zooplankton abundances collected from the Huetzalin Lake (Mexico City, Mexico) for two years (February 2003–January 2004 and then March 2005–February 2006). Selected physicochemical variables (Secchi depth, temperature, pH, conductivity, dissolved oxygen, phosphorus, nitrogen, carbon and chlorophyll a concentration) were also measured at the time of zooplankton collection. The data on zooplankton abundances and the physicochemical variables were subjected to multiple correlation analysis and we also derived Shannon–Wiener species diversity index. Secchi depth ranged from 9 to 65 cm. Generally the lake was alkaline (pH 7–12). The conductivity ranged from 500–1000 mS cm⁻¹, while the mean water temperature was 20.5 °C. Dissolved oxygen levels were generally >3 mg L⁻¹ and were higher in the winter than warmer months. Nitrates (90–95 μg L⁻¹) and phosphates (.2–.5 mg L⁻¹) indicated that the water was eutrophic. Chlorophyll a levels ranged from 143 to 696 μg L⁻¹ during the study period. The zooplankton community was dominated by rotifers (46 species), followed by cladocerans (9 species) and there were only two copepod species. The dominant rotifer species were Brachionus angularis, Brachionus calyciflorus, Brachionus havanaensis, Brachionus quadridentatus, Lecane bulla and Polyarthra vulgaris. Rare rotifer species in Lake Huetzalin were Lecane ohioensis, Dicranophorus forcipatus, Lecane pyriformis, Lindia torulosa, Pleurotrocha petromyzon and Brachionus durgae. Highest densities (occasional peaks of 400 ind L⁻¹) of B. quadridentatus occurred between April and December, while B. havanaensis reached peak densities, during June to October. B. calyciflorus reached densities higher than 1240 ind L⁻¹ during May–September. Cladoceran and copepod densities in Lake Huetzalin were much lower than that of the rotifers. This study confirmed the earlier findings that Xochimilco system of canals is dominated by rotifers and the crustacean zooplankton have much lower abundances possibly due to predation from fish.     

Growth and deformation mechanisms of talc along a natural fault: a micro/nanostructural investigation

This paper documents the occurrence of large amounts of talc within a continental normal fault. The talc-in reaction is deformation-enhanced and occurs by the interaction between dolostones and silica-rich hydrothermal fluids. In the high-strain, foliated fault core, talc forms an interconnected network of oriented (001) lamellae, 200–300 nm thick, locally associated with minor tremolite fibres, up to 300 nm in diameter. The talc structure is affected by several strain-induced defects, among which (001) interlayer delamination that produces talc “sublamellae” down to 10–30 nm thick. Micro/nanostructural observations definitely point to a predominant deformation mechanism of (001) frictional sliding, further enhanced by pervasive delamination that gives rise to an almost infinite number of possible sliding surfaces. These effects have fundamental implications in fault mechanics, resulting in significant fault weakening.     

First historical evidence of a significant Mt. Etna eruption in 1224

The 1224 Mt. Etna eruption is a significant event both in terms of the mass of erupted materials and because it involved the lower eastern slope of the volcano, reaching down to the sea. Nevertheless, it is unknown to current historical catalogues. According to the historical sources, only two other lava flows actually reached as far as the sea: in 396 BC, just north of the present-day inhabited area of Acireale, according to the geological data alone, and in 1669, when the lava covered the south-eastern flank of Mt. Etna and damaged Catania. We present and discuss the two medieval sources that attest to the eruption of 1224 and make available the original texts. Furthermore, through the close analysis of the historical and topographic context of the Etna area, taking account of the roads and ports in the early 13th century, we have tried to single out the possible area of the lava's outlet into the sea in 1224 on historical grounds. A repeat of an eruption similar to that of 1224 would have a serious impact today as the coast is densely populated.     

Patterns and Levels of Organochlorines (DDTs, PCBs, non-ortho PCBs and PCDD/Fs) in Male Harbour Porpoises (Phocoena phocoena) from the Baltic Sea, the Kattegat-Skagerrak Seas and the West Coast of Norway

Patterns and levels of chlorinated aromatic contaminants (DDTs, PCBs, non-ortho PCBs and PCDD/Fs) in blubber tissue were compared among six sample groups of male harbour porpoises (Phocoena phocoena) from the Baltic Sea, the Kattegat-Skagerrak Seas and the west coast of Norway. A principal component and classification analysis showed that mature harbour porpoises from the Baltic had significantly different contaminant patterns than animals from the Kattegat-Skagerrak and Norway. ANOVAs showed that mature porpoises from the Baltic had higher levels of ΣPCB and several individual PCBs and PCDD/Fs than the Kattegat-Skagerrak and the Norwegian samples and higher ΣDDT than the Norwegian. A comparison between immature porpoises showed that Baltic animals had higher levels of ΣPCDD/F than the corresponding sample from the Kattegat-Skagerrak. The levels of ΣDDT, ΣPCB and Σnon-ortho PCB were significantly higher in animals collected during 1978–81 compared to animals collected in 1988–90 indicating a temporal decline of these organochlorines in the Kattegat-Skagerrak Seas. The contaminant levels recorded in the Baltic Sea are a serious cause for concern and could have management implications for the already threatened harbour porpoises in this area.     

Remote Sensing of Three-dimensional Winds with Elastic Lidar: Explanation of Maximum Cross-correlation Method

Maximum cross-correlation provides a method toremotely de-ter-mine high-lyre-solved three-dimensional fields of horizontalwinds with e-las-tic li-darthrough-out large volumes of the planetaryboundary layer (PBL). This paperdetails the technique and shows comparisonsbetween elastic lidar winds, remotelysensed laser Doppler velocimeter (LDV) windprofiles, and radiosonde winds.Radiosonde wind data were acquired at Barcelona,Spain, during the BarcelonaAir-Quality Initiative (1992), and the LDVwind data were acquired at SunlandPark, New Mexico during the 1994 Border AreaAir-Quality Study. Comparisonsshow good agreement between the differentinstruments, and demonstrate the methoduseful for air pollution management at thelocal/regional scale. Elastic lidar windscould thus offer insight into aerosol andpollution transport within the PBL. Lidarwind fields might also be used to nudge orimprove initialization and evaluation ofatmospheric meteorological models.     

Circulatory Patterns of Air Pollutants within the Barcelona Air Basin in a Summertime situation: Lidar and Numerical Approaches

This work examines circulatory patterns of airpollutants in the area of Barcelona (Spain), a regionwith strong coastal and orographic influences. Thiswas achieved through exploitation ofelastic-backscatter lidar data and by numericalsimulation of the atmosphere with a meteorologicalmesoscale model (MEMO). Lidar data were acquired inJuly 1992 during a collaborative campaign between LosAlamos National Laboratory (LANL) and the PolytechnicUniversity of Catalonia (UPC). The lidar providedinformation about the distribution of aerosols and theprevailing winds, determined by application of amaximum cross-correlation algorithm toelastic-backscatter lidar data. Lidar winds are usedto evaluate high altitude winds simulated by themodel. This study showed that circulatory patterns inBarcelona are correlated with daytime convectivevertical mixing, sea-breeze circulations, and verticalforcing caused by mountain thermal and mechanicaleffects.     

Upper Eocene ejecta of the New Jersey continental margin reveal dynamics of Chesapeake Bay impact

Evidence for the Chesapeake Bay Crater as the source for New Jersey continental margin ejecta is provided by fine-grained tektites and coarse-grained unmelted ejecta. The Upper Eocene ejecta deposit, now demonstrated to be part of the North American strewn field, occurs on the New Jersey continental margin at Ocean Drilling Program (ODP) Sites 904 and 903. The mineralogy, major oxide composition of the ejecta materials, and biostratigraphic age of the enclosing sediments link the origin of these ejecta to the recently recognized Chesapeake Bay impact crater, located only 330 km away. Sediments associated with the ejecta provide information about the dynamics of impact events. The 35-cm-thick ejecta-bearing layer can be subdivided into three subunits that indicate a sequence of events. Bottom subunit III documents sediment failure and deposition of gravel-sized fragments, middle subunit II records deposition of abundant sand-sized ejecta by gravity settling, and upper subunit I contains a 12-cm-thick sedimentary deposit containing rare silt-sized tektites and evidence of waning currents. These events are interpreted by linking sediment deposition to seismic ground motion and subsequent tsunami waves triggered by both the Chesapeake Bay impact and slope failures.     

Nuclear stellar discs in early-type galaxies — II. Photometric properties

Hubble Space Telescope images of two early-type galaxies harbouring both nuclear and outer stellar discs are studied in detail. By means of a photometric decomposition, the images of NGC 4342 and 4570 are analysed and the photometric properties of the nuclear discs investigated. We find a continuity of properties in the parameter space defined by the central surface brightness μ₀ and the scalelength R _d of discs in spirals, S0s and embedded discs in ellipticals, in the sense that the nuclear discs extend the observed disc properties even further towards smaller scalelengths and brighter central surface brightnesses. When including the nuclear discs, disc properties span more than four orders of magnitude in both scalelength and central surface brightness. The nuclear discs studied here are the smallest and brightest stellar discs known, and as such, they are as extreme in their photometric properties as Malin I, when compared with typical galactic discs that obey Freeman's law. We discuss a possible formation scenario in which the double-disc structure observed in these galaxies has been shaped by now dissolved bars. Based on the fact that the black holes known to exist in some of these galaxies have masses comparable to those of the nuclear discs, we explore a possible link between the black holes and the nuclear discs.     

Reconstructing recent environmental changes using non-biting midges (Diptera: Chironomidae) in two high mountain lakes from northern Patagonia,Argentina

Remote lakes of northern Patagonia are ideal sites for examining climate- and non-climate-driven changes in aquatic ecosystems because there is little evidence of human influence and there is no detailed information on recent environmental trends in the region (i.e. the last 200 years). Subfossil chironomids (Diptera: Chironomidae) are useful paleoindicators due to their specific response to numerous environmental factors. Here, we analyze the chironomid subfossil assemblages from two remote lakes located in different environmental settings in Nahuel Huapi National Park of northern Patagonia, Argentina. Chironomids combined with sedimentary pigments (chlorophyll derivatives and total carotenoids) and organic matter provided information on the environmental history of the lakes for the last ca. 200 years. The ²¹⁰Pb chronology and tephra layers are used to establish the chronology of changes in the chironomid assemblages associated to different environmental factors that impacted the area during the period covered by the study. The deposition of volcanic ash affected the abundance and composition of chironomid assemblage throughout the record of both lakes. However, changing climate conditions and human activities are also responsible for chironomid changes in the last 50 years.