Rare earth elements in waters from the albitite-bearing granodiorites of Central Sardinia, Italy

With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO₃.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO₃²⁻ ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE³⁺ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution.     

Exploring determinants of the extent of long distance commuting in Australia: accounting for space

Previous research exploring the impacts of long distance commuting (LDC) or, more generally, mining on host regions, struggles to explain the variability of these impacts over time and across space. This article argues that spatial effects should be accounted for explicitly in order to improve the predictive power of contemporary research. We study the extent of LDC in a region in a spatial model disaggregating Australia into 325 subregions. We find evidence that space is an important factor in explaining the extent of LDC in a region, which challenges the validity of studying LDC impacts on host regions in isolation. With regards to the determinants of the extent of LDC, we find that residential attractiveness of a region influences the extent of LDC in a region; the size of the pool of unemployed in a region does not.     

Studying travertines for neotectonics investigations: Middle–Late Pleistocene syn-tectonic travertine deposition at Serre di Rapolano (Northern Apennines, Italy)

Middle–Late Pleistocene tectonic activity has been inferred through studies on travertine deposits exposed in a tract of the hinterland Northern Apennines. A detailed study on the relationships between tectonics and travertine deposition coupled with ²³⁰Th/²³⁴U age determination of travertines at Cava Oliviera quarry, located close to Serre di Rapolano village (southern Tuscany, Northern Apennines), allowed us to recognise Pleistocene faults, whose activity has been referred to 157–24 ka, at least. Travertine deposition was tectonically controlled by WSW-ENE striking, oblique and normal faults, associated to a main fault (named as the Violante Fault). This structure dissected a regional normal fault (known as the Rapolano Fault) Early–Middle Pliocene in age, which bounded the eastern side of the Pliocene Siena Basin, and gave rise to space accommodation for clayey and sandy marine sediments. Hydrothermal circulation (and related travertine deposition) was favoured by the damaging enhancement due to the fault–fault intersection. Tectonic activity has been also documented by deformation recorded by travertines, which suggest a main tectonic event between 64 ± 5 and 40 ± 5 ka. The tectonic activity described for the study area agrees with the Quaternary tectonic evolution documented in the surrounding areas (e.g. Mt. Amiata and Mt. Vulsini), as well as the Tyrrhenian margin of the Central Apennines, indicating that a widespread tectonic activity affected the inner part of the Apennines until the latest Quaternary.     

Transpressional tectonics and nappe stacking along the Southern Variscan Front of Morocco

The Southern Variscan Front in the Tinerhir area involves Palaeozoic allochthonous units (Ouaklim and Tilouine units) thrust onto the northern edge of the West African Craton during late Carboniferous time. Illite crystallinity data highlight an anchizonal grade for the Ouaklim Unit, and a diagenesis-anchizone transition for the Tilouine Unit during deformation phase D1. The tectonic stack is crosscut by major dextral reverse faults bounding E–W trending domains of dominant shortening deformation (central domain) and strike-slip deformation (northern and southern domains), later segmented by a network of post-Variscan faults. This complex deformation pattern is the result of kinematic partitioning of dextral transpression along the Southern Variscan Front, coeval with the Neovariscan (300–290 Ma) oblique convergence observed at the scale of the whole Moroccan Variscides. Partitioning of dextral transpression described in the Tinerhir area is consistent with dextral wrench faulting along the Tizi n’ Test Fault, and with Appalachian-style south-directed thrusting in the Tinerhir and Bechar-Bou Arfa areas.     

New data for the kinematic interpretation of the Alps–Apennines junction (Northwestern Italy)

Alps and Apennines are juxtaposed within an approximately 100 km-wide area covered by the Upper Eocene to Miocene successions of the Tertiary Piedmont Basin. The Upper Eocene–Oligocene evolution of this area was characterized to the north and west by the propagation of the SE-verging Southalpine thrust-fold belt that can be traced from the Po Plain subsurface until the Torino Hill-Saluzzese area, and to the south by a high-angle, broadly E–W oriented megashear zone that led to the juxtaposition of different crustal levels and controlled the development of a mosaic of partly independent sub-basins. Since the latest Oligocene the N-verging Apenninic tectonics prevailed in the collisional system and the Tertiary Piedmont Basin evolved as a wide thrust-top basin, bounded to the north by the N-verging Monferrato arc and characterized by a tectono-sedimentary evolution recording changes of subsidence and shift of depocentres in relation to crustal structures.     

The relationship between websterite and peridotite in the Balmuccia peridotite massif (NW Italy) as revealed by trace element variations in clinopyroxene

 Field, mineralogical and petrological data are presented on a newly found carbonatite occurrence associated with “kamafugite” lava at Cupaello, central Italy. This carbonatite occurrence is part of the Late Pleistocene Umbria-Latium ultra-alkaline district (ULUD) which extends southwards within the Apennines to Mount Vulture, delineating an important magmatic province along the most peripheral belt of the Tyrrhenian extensional tectonic system. This province is distinct, but probably related genetically with the more abundant and common leucite-bearing assemblages of the Roman Comagmatic Region and represents the first reported occurrence of carbonatite assemblages in the Mediterranean Basin. The Cupaello suite indicates that primary or near-primary mantle silicate melts of “kamafugitic” composition are transitional with Ca-carbonatite liquid and provides direct evidence of immiscibility of carbonatite from “kamafugite” magma. It is inferred that a primary mantle origin of Ca-carbonatites is conditional upon a potential silicate magma that may be coupled with the carbonatite, but may not have reached the surface. The data indicate a strong genetic link between ULUD Ca-carbonatites and some African analogues, supporting the view that their genesis depends on similar source and associated tectonic conditions. Received: 17 January 1995 / Accepted: 14 June 1995     

Fast collocation

In this paper a new method to compute in a fast and reliable way the collocation solution is presented. In order to speed up the numerical procedures, some restrictions on input data are needed.The basic assumption is that data are gridded and homogeneous; this implies that the autocovariance matrix entering in the collocation formula is of Toeplitz type. In particular, if observations are placed on a two dimensional planar grid, the autocovariance matrix is a symmetric block Toeplitz matrix and each block is itself a symmetric Toeplitz matrix (Toeplitz/Toeplitz structure). The analysis can be extended to a regular geographical grid, considered as a generalization of the planar one, taking into account the distortions on the Toeplitz/Toeplitz structure induced by the convergence of the meridians. The devised method is based on a combined application of the Preconditioned Conjugate Gradient Method and of the Fast Fourier Transform. This allows a proper exploitation of the Toeplitz/Toeplitz structure of the autocovariance matrix in computing the collocation solution.The numerical tests proved that the application of this algorithm leads to a relevant decrease in CPU time if compared with standard methods used to solve a collocation problem (Cholesky, Levinson).