A U-Pb zircon,and Rb-Sr and U-Th-Pb whole-rock study of a polymetamorphic terrane in the central Alps,Switzerland

U-Pb analyses of zircons from the southern paragneiss zone of the Gotthard massif in the central Alps indicate these rocks were derived from one or more source areas ≧ 1400 m.y. old and were strongly affected by both the Caledonian and Hercynian orogenies. Rb-Sr whole-rock analyses also appear to reflect the Hercynian event while Rb-Sr analyses of a metamorphic inclusion and a boudin indicate that these small-scale samples were affected by the Alpine orogeny. U-Pb whole rock data appear to reflect only the Hercynian event; these data, when corrected for primordial lead, furthermore yield an upper concordia intercept of 4500 m.y., possibly resulting from a U-Pb fractionation very early in the history of the earth. A more refined three-stage U-Pb evolution model yields an age of about 4480 m.y. rather than 4500 m.y. for this hypothesized early terrestrial differentiation. Geologically these data emphasize that: 1) the southern paragneiss zone of the Gotthard massif contains metasediments which have experienced the Caledonian orogeny and are at least 400 m.y. old; 2) the Hercynian episode in this region was pervasive indeed; and 3) the Alpine orogeny affected the Rb-Sr and U-Pb whole rock systems to a far lesser degree than the preceding orogenic episodes and apparently did not affect the U-Pb zircon systems investigated at all.     

Geological and Isotopic Constraints on the Metallogenic Evolution of the Proterozoic Sediment-Hosted Pb-Zn (Ag) Deposits of Brazil

Integrated studies of seven Proterozoic sediment-hosted, Pb-Zn-Ag sulfide deposits of Brazil, permit the estimation of the age of the hosting sequence and the mineralization, the nature of the sulfur and metal sources, the temperature range of sulfide formation and the environment of deposition. These deposits can be classified into three groups, according to their ages. (a) Archean to Paleoproterozoic: the Boquira deposit, in Bahia state, consists of stratiform massive and disseminated sulfides hosted by parametamorphic sequences of grunnerite-cummingtonite+magnetite that represent a silicate facies of the Boquira Formation (BF). Lead isotope data of galena samples indicate a time span between 2.7 and 2.5 Ga for ore formation, in agreement with the stratigraphic position of the BF. The relatively heavy sulfur isotope compositions for the disseminated and stratiform sulfides (+8.3 to +12.8 ‰ CDT)suggest a sedimentary source for the sulfur. (b) Paleo to Mesoproterozoic: stratiform and stratabound sulfides in association with growth faults are present in the Canoas mine (Ribeira, in Paraná state) and in the Caboclo mineralization (Bahia state). They are hosted by calcsilicates and amphibolites in the Canoas deposit, whereas in the Caboclo area the mineralization is associated with hydrothermally altered dolarenites at the base of the 1.2 Ga Caboclo Formation. The interpreted Pb-Pb age of the Canoas mineralization is coeval with the 1.7 Ga host rocks. Sulfur isotopic data for Canoas sulfides (+1.2 to +16 ‰ CDT) suggest a sea water source for the sulfur. The range between −21.1 and +8.8 ‰ CDT for the Caboclo sulfides could suggest the action of bacterial reduction of seawater sulfates, but this interpretation is not conclusive. (c) Neoproterozoic: stratiform and stratabound sulfide deposits formed during the complex diagenetic history of the host carbonate rocks from the Morro Agudo (Bambui Group), Irecê and Nova Redenção (Una Group), yield heavy sulfur isotope values (+18.9 to +39.4 ‰ CDT). The uniform heavy isotope composition of the barites from these deposits (+25.1 to +40.9 ‰) reflect their origin from Neoproterozoic seawater sulfates. The late-stage, and most important, metallic concentrations represent sulfur scavenged from pre-existing sulfides or from direct reduction of evaporitic sulfate minerals. Lead isotope data from the Bambui Group suggest focused fluid circulation from diverse Proterozoic sediment sources, that probably was responsible for metal transport to the site of sulfide precipitation. (d) Late Proterozoic to Early Paleozoic: lead-zinc sulfides (+pyrite and chalcopyrite) of Santa Maria deposits, in Rio Grande do Sul, form the matrix of arkosic sandstones and conglomerates, and are closely associated with regional faults forming graben structures. Intermediate volcanic rocks are intercalated with the basal siliciclastic members. Lead isotope age of the mineralization (0.59 Ga) is coeval with the host rocks. Sulfur isotopic values between −3.6 and +4.1 are compatible with a deep source for the sulfur.Geological, petrographic and isotopic data of the deposits studied suggest that they were formed during periods of extensional tectonics. Growth faults or reactivated basement structures probably were responsible for localized circulation of metal-bearing fluids within the sedimentary sequences. Sulfides were formed by the reduction of sedimentary sulfates in most cases. Linear structures are important controls for sulfide concentration in these Proterozoic basins.     

Geostatistical seismic inversion for non‐stationary patterns using direct sequential simulation and co‐simulation

Geostatistical seismic inversion methods are routinely used in reservoir characterisation studies because of their potential to infer the spatial distribution of the petro‐elastic properties of interest (e.g., density, elastic, and acoustic impedance) along with the associated spatial uncertainty. Within the geostatistical seismic inversion framework, the retrieved inverse elastic models are conditioned by a global probability distribution function and a global spatial continuity model as estimated from the available well‐log data for the entire inversion grid. However, the spatial distribution of the real subsurface elastic properties is complex, heterogeneous, and, in many cases, non‐stationary since they directly depend on the subsurface geology, i.e., the spatial distribution of the facies of interest. In these complex geological settings, the application of a single distribution function and a spatial continuity model is not enough to properly model the natural variability of the elastic properties of interest. In this study, we propose a three‐dimensional geostatistical inversion technique that is able to incorporate the reservoir's heterogeneities. This method uses a traditional geostatistical seismic inversion conditioned by local multi‐distribution functions and spatial continuity models under non‐stationary conditions. The procedure of the proposed methodology is based on a zonation criterion along the vertical direction of the reservoir grid. Each zone can be defined by conventional seismic interpretation, with the identification of the main seismic units and significant variations of seismic amplitudes. The proposed method was applied to a highly non‐stationary synthetic seismic dataset with different levels of noise. The results of this work clearly show the advantages of the proposed method against conventional geostatistical seismic inversion procedures. It is important to highlight the impact of this technique in terms of higher convergence between real and inverted reflection seismic data and the more realistic approximation towards the real subsurface geology comparing with traditional techniques.     

A restricted charged four-body problem

We consider a restricted charged four body problem which reduces to a two degrees of freedom Hamiltonian system, and prove the existence of infinite symmetric periodic orbits with arbitrarily large extremal period. Also, it is shown that an appropriate restriction of a Poincaré map of the system is conjugate to the shift homeomorphism on a certain symbolic alphabet.Partially supported by a grant of the CGICT no. P1386-0351.On leave of absence from Departamento de Fisica, Universidade de Lisboa. Partially supported by a grant of Fundaçao Calouste Gulbenkian no. 32/85/13.     

柴达木盆地达布逊湖地区3万年来气候演化的微古生物记录

柴达木盆地第四系富含各种生物化石，尤以介形类最为丰富。以盆地东部达布逊湖东南岸的达参1井浅部的介形类特征为基础，划分出了3万a来的9个古气候演化阶段，其中I1－I5对应于冰后期，Ⅱ1－Ⅱ4对应于末次冰期的晚冰期。这9个阶段中，26．3－20．0、12．2－10．1、8．0－4．5、3．8－2．5kaBP4个阶段生物丰度和分异度都较高，反映了当时气候温暖湿润，适于生物生长。20．3和2．8kaBP是晚更新世以来的两次气候极适宜时段，生物丰度和分异度都达到了最高，而30kaBP左右的生物突然大量灭绝和盐层开始析出是全球性的气候变冷以及青藏高原的第5次隆升的结果。     

Characteristics of Valadares Island aquifer,Paranaguá coastal plain,Brazil

. Aquifer characterization in terms of geologic–geomorphological considerations, pumping test and hydrochemistry has been carried out to evaluate the groundwater potential of one of the delicate coastal island systems in Parana State, Brazil. The Valadares Island, lying in the Atlantic coastal zone, represents a stabilized beach ridge having a thickness of more than 20 m unconsolidated quartz-rich sand. Field and laboratory investigations suggest that this homogeneous coastal aquifer can partially meet the local domestic demand of fresh water even though it is in hydraulic continuity with the estuarine and tidal systems of Paranaguá bay. Efficiency of the aquifer to hold and release water was determined by conducting a pumping test in one of the partially penetrating wells in the island for 24 h. The physical, chemical and biological analyses of samples from 12 5-cm diameter wells of the area have indicated that groundwater needs purification for drinking purpose. It is advocated that the groundwater potential of the island aquifer is worth considering for sustained but controlled exploitation.