Radar topography of domes on planetary surfaces

We investigate the possibility of measuring the heights and morphology of viscously emplaced domes using radar imagery. We accurately reproduce the known height and shape of a terrestrial salt dome, and estimate the heights of several venusian pancake domes to within a factor of two. The terrestrial salt dome is consistent with a Bingham flow, while the much larger venusian pancake domes are consistent with a Newtonian flow. Applying the same techniques to Ganesa Macula, a potential cryovolcanic dome on Titan, we estimate a height between 2.0-4.9 km. Additional factors such as variable roughness and composition might account for some of the discrepancies observed.     

The Dominican Republic–Central American Free Trade Agreement’s Symbolic Nod to Environmental Protection: Legal Perspectives on the Citizen Submission Process

The Dominican Republic–Central America Free Trade Agreement (CAFTA) contains a chapter on the environment, ostensibly included to mitigate the North American Free Trade Agreement (NAFTA) environmental oversights. The environment chapter created a citizen submission process designed to foster public participation in supporting each participating nation’s environmental laws. This article examines the outcomes to date of the citizen submission process, based on an analysis of the articles of the agreement and an examination of the rulings made on each case submitted under the citizen submission process. The analysis shows that CAFTA poses significant obstacles to citizen participation and has made minimal, if any, contributions to environmental law enforcement among the Parties to the agreement.     

Crossing Boundaries in a Collaborative Modeling Workspace

There is substantial literature on the importance of bridging across disciplinary and science–management boundaries. One of the ways commonly suggested to cross boundaries is for participants from both sides of the boundary to jointly produce information (i.e., knowledge co-production). But simply providing tools or bringing people together in the same room is not sufficient. Here we present a case study documenting the mechanisms by which managers and scientists collaborated to incorporate climate change projections into Colorado’s State Wildlife Action Plan. A critical component of the project was the use of a collaborative modeling and visualization workspace: the U.S. Geological Survey’s Resource for Advanced Modeling (RAM). Using video analysis and pre/post surveys from this case study, we examine how the RAM facilitated cognitive and social processes that co-produced a more salient and credible end product. This case provides practical suggestions to scientists and practitioners who want to implement actionable science.     

B and Li isotopes as intrinsic tracers for injection tests in aquifer storage and recovery systems

Boron and Li isotopes have been tested as environmental tracers of treated sewage injected into a sandy aquifer (Shafdan reclamation project, Israel). During a 38 days injection test in a newly dug injection well, a conservative artificial tracer (Br⁻) was monitored together with δ¹¹B and δ⁷Li in the injectate, in the unsaturated soil zone (porous cup) and an observation well in the aquifer. In spite of B and Li concentrations in the injectate close to background values, significant shifts of the isotope signatures could be observed over the duration of the injection test. Boron isotope ratios show a breakthrough curve delayed with respect to Br⁻ breakthrough due to some reversible sorption on the aquifer material. No isotope fractionation was observed in the unsaturated or the saturated zone so that B isotopes can be considered as conservative in the investigated part of the aquifer system. Lithium isotopes are strongly fractionated, probably due to sorption processes. Lithium concentrations point to a Li sink in the system, δ⁷Li values vary strongly with a tendency of ⁷Li depletion in the liquid phase over the duration of the experiment. This is opposite to the expected preferential sorption of ⁶Li onto clay minerals. Boron isotopes reveals a valuable tracer of artificial recharge of freshwaters derived from treated sewage, both for short term tracer tests and for long-term monitoring of artificial recharge, even if in aquifers with higher clay contents, sorption-linked isotope fractionation cannot be excluded. More data are needed on Li isotope fractionation in natural groundwater systems to assess the potential of this tracer as monitoring tool.     

Re-Suspension Technique for Improving Organic Rich Sediment-Water Quality in a Shallow Sea Area

The re-suspension method consists of (1) dispersion of the sediment by air-water jets, (2) pumping of the suspension (small particles and organic matter), (3) settlement in a tank, (4) filtration and (5) disposal of solids (followed by incineration in this case). The pilot test was performed to clean up an area of 3000 m². The dispersed depth of the bottom was approximately 50 cm. The time spent for the work was two weeks. The amount of re-suspended solid removed from the bottom was about 8 tonnes in dry mass. Since the solids contain high concentrations of chemical oxygen demand (COD), total phosphorous (T-P), total nitrogen (T-N) and sulfides, the remaining sediment was considerably improved. Quantitative analyses showed that the full-scale implementation would enable the removal of about 10% of the re-suspended solids, and reduce COD by 95%, T-P by 50%, T-N by 100% and sulfide by 75% for re-deposited sediments in comparison to the original sediments.     

Photochemical degradation of phenanthrene as a function of natural water variables modeling freshwater to marine environments

Photolysis rates of phenanthrene as a function of ionic strength (salinity), oxygen levels and humic acid concentrations were measured in aqueous solution over the range of conditions found in fresh to marine waters. Photolysis followed first order kinetics, with an estimated photodegradation half-life in sunlight in pure water of 10.3±0.7h, in the mid-range of published results. Photolysis rate constants decreased by a factor of 5 in solutions with humic acid concentrations from 0 to 10 mg C L(-1). This decrease could be modeled entirely based on competitive light absorption effects due to the added humics. No significant ionic strength or oxygen effects were observed, consistent with a direct photolysis mechanism. In the absence of significant solution medium effects, the photodegradation lifetime of phenanthrene will depend only on solar fluxes (i.e. temporal and seasonal changes in sunlight) and not vary with a freshwater to marine environment.     

Shifting accountabilities? Understanding the connections between national and provincial fisheries in Papua New Guinea

This paper examines the effects of fisheries decentralization strategies in Papua New Guinea. The paper assess the financial, human resources, information, and institutional mechanisms that the National Fisheries Authority uses to connect with provincial fisheries offices to show the consequences of institutional reforms. The findings suggest both intended and unintended effects, particularly in terms of shifting accountabilities and loyalty. These findings are broadly applicable to decentralization and institutional change scholars and practitioners interested in understanding how governments implement institutional change reforms and the effects of this implementation.     

Biofilm Detection in a Model Well‐Bore Environment Using Low‐Field NMR

This research addresses the challenges of the lack of non‐invasive methods and poor spatiotemporal resolution associated with monitoring biogeochemical activity central to bioremediation of subsurface contaminants. Remediation efforts often include growth of biofilm to contain or degrade chemical contaminants, such as nitrates, hydrocarbons, heavy metals, and some chlorinated solvents. Previous research indicates that nuclear magnetic resonance (NMR) is sensitive to the biogeochemical processes of biofilm accumulation. The current research focuses on developing methods to use low‐cost NMR technology to support in situ monitoring of biofilm growth and geochemical remediation processes in the subsurface. Biofilm was grown in a lab‐scale radial flow bioreactor designed to model the near wellbore subsurface environment. The Vista Clara Javelin NMR logging device, a slim down‐the‐borehole probe, collected NMR measurements over the course of eight days while biofilm was cultivated in the sand‐packed reactor. Measured NMR mean log T₂ relaxation times decreased from approximately 710 to 389 ms, indicating that the pore environment and bulk fluid properties were changing due to biofilm growth. Destructive sampling employing drop plate microbial population analysis and scanning electron and stereoscopic microscopy confirmed biofilm formation. Our findings demonstrate that the NMR logging tool can detect small to moderate changes in T₂ distribution associated with environmentally relevant quantities of biofilm in quartz sand.