Complex disturbance-driven reactivation of near-surface sediments in the largest dunefield in North America during the last 200 years

Understanding the historical activity of desert dune systems is important for identifying both the palaeoenvironmental drivers of change and the likelihood of future reactivation. Dating dune sediments in the Nebraska Sandhills has identified regional-scale dune activity over centennial and millennial timescales during the Holocene, occurring at 9.6–6.5, 3.8 and 2.5 ka, and most recently spanning the Medieval Climatic Anomaly 1050–650 years BP. These periods have been interpreted as palaeoclimatic evidence of intense aridity lasting decadal and centennial timescales. A detailed record of dune activity in the historical period, since EuroAmerican arrival, is lacking however, yet important for interpreting the role of human agency amongst the factors influencing disturbance. Without a high-resolution record of short-term, historical, local sediment mobilization, it is not possible to distinguish the environmental factor(s) responsible for local reactivation. In this paper, the individual drivers of vegetation disturbance are reviewed and presented alongside a luminescence-dated reconstruction of dune sediment deposition ages. This allows an integrated assessment of the relationship between drivers and environmental response over a recorded period. We focused our investigation on the aeolian reactivations of surface dune sediments and blowout features around the Niobrara Valley Preserve in the northern limits of the Nebraska Sandhills. Results show a near-continuous (within uncertainties) timeline of local reactivation across the sites studied, with variation between the individual features indicating that both regional (i.e. climatic) and local (i.e. land use) forcings contribute to surface disturbance. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Lipid biomarkers and bacterial lipase activities as indicators of organic matter and bacterial dynamics in contrasted regimes at the DYFAMED site, NW Mediterranean

This study investigated the relationships between dissolved organic matter (DOM) composition and bacterial dynamics on short time scale during spring mesotrophic (March 2003) and summer oligotrophic (June 2003) regimes, in a 0–500 m depth water column with almost no advection, at the DYFAMED site, NW Mediterranean. DOM was characterized by analyzing dissolved organic carbon (DOC), colored dissolved organic matter (CDOM) and lipid class biotracers. Bacterial dynamic was assessed through the measurement of in situ bacterial lipase activity, abundance, production and bacterial community structure. We made the assumption that by coupling the ambient concentration of hydrolysable acyl-lipids with the measurement of their in situ bacterial hydrolysis rates (i.e. the free fatty acids release rate) would provide new insights about bacterial response to change in environmental conditions. The seasonal transition from spring to summer was accompanied by a significant accumulation of excess DOC (+5 μM) (ANOVA, p<0.05, n=8) in the upper layer (0–50 m). In this layer, the free fatty acids release rate to the bacterial carbon demand (BCD) ratio increased from 0.6±0.3 in March to 1.3±1.0 in June (ANOVA, p<0.05, n=8) showing that more uncoupling between the hydrolysis of the acyl-lipids and the BCD occurred during the evolution of the season, and that free fatty acids contributed to the excess DOC. The increase of lipolysis index and CDOM absorbance (from 0.24±0.17 to 0.39±0.13 and from 0.076±0.039 to 0.144±0.068; ANOVA, p<0.05, n=8, respectively), and the higher contribution of triglycerides, wax esters and phospholipids (from <5% to 12–31%) to the lipid pool reflected the change in the DOM quality. In addition to a strong increase of bacterial lipase activity per cell (51.4±29.4–418.3±290.6 Ag C cell⁻¹ h⁻¹), a significant percentage of ribotypes (39%) was different between spring and summer in the deep chlorophyll maximum (DCM) layer in particular, suggesting a shift in the bacterial community structure due to the different trophic conditions. At both seasons, in the chlorophyll layers, diel variations of DOM and bacterial parameters reflected a better bioavailability and/or DOM utilization by bacteria at night (the ratio of free fatty acids release rate to bacterial carbon demand decreased), most likely related to the zooplankton trophic behaviour. In mesotrophic conditions, such day/night pattern was driving changes in the bacterial community structure. In more oligotrophic period, diel variations in bacterial community structure were depth dependent in relation to the strong summer stratification.     

The AMANDES tidal model for the Amazon estuary and shelf

The AMANDES project aims to study transports from the Andean mountains to the Atlantic Ocean through the Amazon system. This requires realistic estuarine modelling in this area strongly forced by tides and river discharge. As none of the existing models for this region would fit the actual needs of the project, a specific new generation model has been implemented.The model is based on the hydrodynamic finite element model T-UGOm. In a first step, we limit our investigations to tidal dynamics. As the Amazon estuary is a very shallow macro-tidal area, it is necessary to improve the available bathymetries and to develop a precise bottom friction parametrisation.In this paper, we discuss the implementation of a high resolution regional model. This allows us to develop a precise and accurate tidal model: for instance, the overall root mean square error on complex differences is reduced from 54 cm in a standard model to 27 cm in our best model. Such precise and accurate tidal modelling is a prerequisite for modelling particle transport.     

A hafnium isotope and trace element perspective on melting of the depleted mantle

New Hf isotope and trace element data on mid-ocean ridge basalts (MORB) from the Pacific Ocean basin are remarkably uniform (¹⁷⁶Hf/¹⁷⁷Hf≈0.28313–0.28326) and comparable to previously published data [Salters, Earth Planet. Sci. Lett. 141 (1996) 109–123; Patchett, Lithos 16 (1983) 47–51]. Atlantic MORB have ¹⁷⁶Hf/¹⁷⁷Hf ranging from 0.28302 to 0.28335 confirming the wide range originally identified by Patchett and Tatsumoto [Geophys. Res. Lett. 7 (1980) 1077–1080]. Indian MORB define an even wider range, from 0.28277 to 0.28337, but three exotic samples have very unradiogenic Hf isotope compositions. Their very low ¹⁷⁶Hf/¹⁷⁷Hf ratios, together with their trace element characteristics, require the presence of unusual plume-type material beneath the Indian ridge. All other Indian MORB have uniform Hf isotope compositions at about 0.2832, and define a small field displaced to the right of other MORB in Hf–Nd isotope space. The distinct nature of Indian MORB is best explained by the presence in Indian depleted mantle of old recycled oceanic crust and pelagic sediments. Sm/Hf ratios calculated from new high-precision rare earth element and Hf trace element data do not vary in MORB in the same way as in ocean island basalts (OIB): ratios are constant in OIB, but decrease with increasing Sm contents in MORB. The constancy of Sm/Hf in OIB is probably due to an overwhelming influence of residual garnet during melting. By contrast, the decrease of Sm/Hf in MORB is due to the effect of clinopyroxene in the residue of melting beneath ridges, an interpretation confirmed by quantitative modeling of melting. The relationship between Sm/Nd and Lu/Hf ratios in MORB does not require the presence of garnet in the residual mineralogy. The decoupling of Lu/Hf ratios and Hf isotope compositions – the so-called Hf paradox [Salters and Hart, EOS Trans. Am. Geophys. Union 70 (1989) 510] – can be explained by melting dominantly in the spinel field at shallow depths beneath mid-ocean ridges.     

Temporal variability of phosphorus fractions in Irish karst springs

Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg l^–1) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg l^–1) and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg l^–1), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg l^–1 due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge.     

Phyllosilicate minerals in the hydrothermal mafic–ultramafic-hosted massive-sulfide deposit of Ivanovka (southern Urals): comparison with modern ocean seafloor analogues

We have studied textural relationships and compositions of phyllosilicate minerals in the mafic–ultramafic-hosted massive-sulfide deposit of Ivanovka (Main Uralian Fault Zone, southern Urals). The main hydrothermal phyllosilicate minerals are Mg-rich chlorite, variably ferroan talc, (Mg, Si)-rich and (Ca, Na, K)-poor saponite (stevensite), and serpentine. These minerals occur both as alteration products after mafic volcanics and ultramafic protoliths and, except serpentine, as hydrothermal vein and seafloor mound-like precipitates associated with variable amounts of (Ca, Mg, Fe)-carbonates, quartz and Fe and Cu (Co, Ni) sulfides. Brecciated mafic lithologies underwent pervasive chloritization, while interlayered gabbro sills underwent partial alteration to chlorite + illite ± actinolite ± saponite ± talc-bearing assemblages and later localized deeper alteration to chlorite ± saponite. Ultramafic and mixed ultramafic–mafic breccias were altered to talc-rich rocks with variable amounts of chlorite, carbonate and quartz. Chloritization, locally accompanied by formation of disseminated sulfides, required a high contribution of Mg-rich seawater to the hydrothermal fluid, which could be achieved in a highly permeable, breccia-dominated seafloor. More evolved hydrothermal fluids produced addition of silica, carbonates and further sulfides, and led to local development of saponite after chlorite and widespread replacement of serpentine by talc. The Ivanovka deposit shows many similarities with active and fossil hydrothermal sites on some modern oceanic spreading centers characterized by highly permeable upflow zones. However, given the arc signature of the ore host rocks, the most probable setting for the observed alteration–mineralization patterns is in an early-arc or forearc seafloor–subseafloor environment, characterized by the presence of abundant mafic–ultramafic breccias of tectonic and/or sedimentary origin.Editorial responsibility: J. Hoefs