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831.
A new stegosaur species, Jiangjunosaurus junggarensis, gen. et sp. nov., is erected based on a specimen collected from the Upper Jurassic upper section of the Shishugou Formation in the Junggar Basin, Xinjiang, China. It represents the first stegosaur from the Jurassic of Xinjiang and increases the diversity of the dinosaur fauna in the Shishugou Formation. The new genus is characterized by symmetrical and proportionally wide tooth crowns, a sub-rectangular axial neural spine seen in lateral view, and large openings on the lateral surfaces of the cervical centra. A preliminary character analysis suggests that this new taxon is more derived than the Middle Jurassic stegosaur Huayangosaurus but more primitive than most other known stegosaur species.  相似文献   
832.
The hydrogen content of nominally anhydrous minerals is of great interest, because it can influence many physical and mechanical properties of mantle rocks. Moreover, the hydrogen diffusion profiles can be used to constrain timescales related to magma eruptions. Here, we report models of ionic diffusion for trace elements in anisotropic crystals and apply them to hydrogen diffusing out of mantle-derived olivine. We first compare and discuss the characteristics of 1D and 3D models and show that only 3D anisotropic diffusion models can lead to diffusion profiles exhibiting non-equilibrium plateau at the center of the solid along the slowest axis, as measured in natural samples. In a second part, we discuss the differences between hydration and dehydration of olivine for diffusion that is linked to two different atomic sites involved in hydrogen mobility. Finally, we apply our 3D anisotropic model to previous results on mantle-derived olivine from Pali-aike to better characterize diffusion coefficients and their anisotropy that could be relevant for dehydration of olivine. Our results show that dehydration has to be strongly anisotropic, with a fast [100] axis and a significantly slower [001] axis.  相似文献   
833.
This study uses MC‐ICP‐MS for the precise analysis of the stable tin isotopic composition in ore minerals of tin (cassiterite, stannite), tin metal and tin bronze. The ultimate goal is to determine the provenance of tin in ancient metal objects. We document the isotope compositions of reference materials and compare the precision of different isotope ratios and the accuracy of different procedures of mass fractionation correction. These data represent a base with which isotopic data of future studies can be directly compared. The isotopic composition of cassiterite and stannite can be determined after reduction to tin metal and bronze, respectively. Both metals readily dissolve in HCl, but while the solutions of tin metal can be directly measured, the bronze solutions must be purified with an anion exchanger. The correction of the mass bias is best performed with an internal Sb standard and an empirical regression method. A series of Sn isotope determinations on commercially available mono‐element Sn solutions as well as reference bronze materials and tin minerals show fractionations ranging from about ?0.09‰ to 0.05‰/amu. The combined analytical uncertainty (2s) was determined by replicate dissolutions of reference materials of bronze (BAM 211, IARM‐91D) and averages at about 0.005‰/amu.  相似文献   
834.
Bill Ruddiman (Climatic Change, 61, 261–293, 2003) recently suggested that early civilisations could have saved us from an ice age because land management over substantial areas caused an increase in atmospheric CO2 concentration. Ruddiman suggests a decreasing “natural course” of the Holocene greenhouse gases concentrations and sea-level by referring to analogous situations in the past, namely the last three interglacials. An examination of marine isotopic stage 11 would perhaps make Ruddiman’s argument even more thought-challenging. Yet, the hypothesis of a natural lowering of CO2 during the Holocene contradicts recent numerical simulations of the Earth carbon cycle during this period. We think that the only way to resolve this conflict is to properly assimilate the palæoclimate information in numerical climate models. As a general rule, models are insufficiently tested with respect to the wide range of climate situations that succeeded during the Pleistocene. In this comment, we present three definitions of palæoclimate information assimilation with relevant examples. We also present original results with the Louvain-la-Neuve climate-ice sheet model suggesting that if, indeed, the Holocene atmospheric CO2 increase is anthropogenic, a late Holocene glacial inception is plausible, but not certain, depending on the exact time evolution of the atmospheric CO2 concentration during this period.  相似文献   
835.
Due to the severity of arsenic contamination of soil and water resources around the world, finding new adsorbents for arsenic removal from the water is of high importance. The present study investigates the possible use and effectiveness of starch-stabilized Fe/Cu nanoparticles for adsorption of arsenic from aqueous solutions. First, Fe/Cu nanoparticles at various starch concentrations of 0, 0.02, 0.04 and 0.06 wt% were synthesized and characterized by X-ray diffraction, transmission electron microscopy and zeta potential/particle size analyzer. Then 0.04 wt% stabilized Fe/Cu nanoparticles were tested for the sorption of As(III) and As(V) from synthetic arsenic-contaminated water. To have an understanding about the arsenic adsorption mechanism of nanoparticles, X-ray photoelectron spectroscopy (XPS) was performed before and after adsorption. The results showed that starch provides nanoparticles with a neutral surface and stabilization of nanoparticles is possible with 0.04 wt% or higher concentrations of starch. For 0.04 wt% starch-stabilized Fe/Cu nanoparticles, the adsorption isotherms fit well within the Langmuir equation, with maximum sorption capacities of 90.1 mg/g for As(III) and 126.58 mg/g for As(V) at a pH of 7.0 from the aqueous arsenic solutions. Examining the XPS spectra of nanoparticles before and after adsorption showed that arsenic adsorption by this nanoparticle can be due to the formation of inner-sphere arsenic complexes on the particle surface, and the surface oxygen-containing functional groups involved in adsorption. The high sorption capacity suggests the potential for applying starch-stabilized Fe/Cu nanoparticles to the contaminated waters for removal of arsenic.  相似文献   
836.
Abstract

Different approaches used in hydrological modelling are compared in terms of the way each one takes the rainfall data into account. We examine the errors associated with accounting for rainfall variability, whether in hydrological modelling (distributed vs lumped models) or in computing catchment rainfall, as well as the impact of each approach on the representativeness of the parameters it uses. The database consists of 1859 rainfall events, distributed on 500 basins, located in the southeast of France with areas ranging from 6.2 to 2851 km2. The study uses as reference the hydrographs computed by a distributed hydrological model from radar rainfall. This allows us to compare and to test the effects of various simplifications to the process when taking rainfall information (complete rain field vs sampled rainfall) and rainfall–runoff modelling (lumped vs distributed) into account. The results appear to show that, in general, the sampling effect can lead to errors in discharge at the outlet that are as great as, or even greater than, those one would get with a fully lumped approach. We found that small catchments are more sensitive to the uncertainties in catchment rainfall input generated by sampling rainfall data as seen through a raingauge network. Conversely, the larger catchments are more sensitive to uncertainties generated when the spatial variability of rainfall events is not taken into account. These uncertainties can be compensated for relatively easily by recalibrating the parameters of the hydrological model, although such recalibrations cause the parameter in question to completely lose physical meaning.

Citation Arnaud, P., Lavabre, J., Fouchier, C., Diss, S. & Javelle, P. (2011) Sensitivity of hydrological models to uncertainty of rainfall input. Hydrol. Sci. J. 56(3), 397–410.  相似文献   
837.
The chemical potential of oxygen (µO2) in equilibrium with magnesiowüstite solid solution (Mg, Fe)O and metallic Fe has been determined by gas-mixing experiments at 1,473 K supplemented by solid-cell EMF experiments at lower temperatures. The results give:
where IW refers to the Fe-"FeO" equilibrium. The previous work of Srecec et al. (1987) and Wiser and Wood (1991) agree well with this equation, as does that of Hahn and Muan (1962) when their reported compositions are corrected to a new calibration curve for lattice parameter vs. composition. The amount of Fe3+ in the magnesiowüstite solid solution in equilibrium with Fe metal was determined by Mössbauer spectroscopy on selected samples. These data were combined with literature data from gravimetric studies and fitted to a semi-empirical equation:
These results were then used to reassess the activity-composition relations in (Mg, Fe)2SiO4 olivine solid solutions at 1,400 K, from the partitioning of Mg and Fe2+ between olivine and magnesiowüstite in equilibrium with metallic Fe experimentally determined by Wiser and Wood (1991). The olivine solid solution is constrained to be nearly symmetric with , with a probable uncertainty of less than ±0.5 kJ/mol (one standard deviation). The results also provide a useful constraint on the free energy of formation of Mg2SiO4.Editorial responsibility: B. Collins  相似文献   
838.
This multidisciplinary study aims to decipher the impact of ancient charcoal production on past and present-day soils in the northern Vosges Mountains. Soil observations in the field and laboratory were complemented by charcoal and phytolith studies on large thin sections, molecular analyses of organic pollutants, and phytolith analysis on bulk samples. The complex technosol platform records an ancient natural soil sequence buried by a human-made platform on which charcoal accumulated. The current upslope soil is an entic Podzol. Palaeoecological data collected in the buried soil are reliable owing to low bioactivity due to soil acidity. Podzolisation predated the platform construction. The presence of ashes induced low soil alkalisation developed in the charcoal hearth remains and appears to have generated the migration of subsequent iron/clay/organic bands throughout the platform sediment and the buried soil. Charcoal studied in thin sections revealed mainly Quercus and Fagus taxa. Phytolith studies suggest that a less dense or degraded forest preceded platform construction, probably due to former woodland coppicing or earlier disorganised wood gathering. The specific distribution of polycyclic aromatic hydrocarbons sorbed on charcoal has persisted in soils throughout centuries, but we have no evidence that charcoal-making activities contributed to diffuse global pollution.  相似文献   
839.
This Caledonian pluton exhibits a regular, sub-vertical banding in which layers of dark, relatively fine grained trondhjemite alternate with layers of light, coarse grained granite. The textures and the presence of cross-cutting bands of granite indicate that the light bands were derived by potash feldspathization of the trondhjemite. The geometry of the banding indicates that it formed during the “synplutonic” deformation of the pluton, largely in situ. The bands formed by segregation of alkalies into dilatant zones of movement produced during the deformation of partly consolidated magma.  相似文献   
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