Leachable particulate iron in the Columbia River,estuary, and near-field plume

This study examines the distribution of leachable particulate iron (Fe) in the Columbia River, estuary, and near-field plume. Surface samples were collected during late spring and summer of 2004–2006 as part of four River Influence on Shelf Ecosystems (RISE) cruises. Tidal amplitude and river flow are the primary factors influencing the estuary leachable particulate Fe concentrations, with greater values during high flow and/or spring tides. Near the mouth of the estuary, leachable particulate Fe [defined as the particulate Fe solubilized with a 25% acetic acid (pH 2) leach containing a weak reducing agent to reduce Fe oxyhydroxides and a short heating step to access intracellular Fe] averaged 770 nM during either spring tide or high flow, compared to 320 nM during neap tide, low flow conditions. In the near-field Columbia River plume, elevated leachable particulate Fe concentrations occur during spring tides and/or higher river flow, with resuspended shelf sediment as an additional source to the plume during periods of coastal upwelling and spring tides. Near-field plume concentrations of leachable particulate Fe (at a salinity of 20) averaged 660 nM during either spring tide or high flow, compared to 300 nM during neap tide, low flow conditions. Regardless of tidal amplitude and river flow, leachable particulate Fe concentrations in both the river/estuary and near-field plume are consistently one to two orders of magnitude greater than dissolved Fe concentrations. The Columbia River is an important source of reactive Fe to the productive coastal waters off Oregon and Washington, and leachable particulate Fe is available for solubilization following biological drawdown of the dissolved phase. Elevated leachable Fe concentrations allow coastal waters influenced by the Columbia River plume to remain Fe-replete and support phytoplankton production during the spring and summer seasons.     

Caribbean hydrological variability during the Holocene as reconstructed from crater lakes on the island of Grenada

Contemporary precipitation patterns in the Caribbean region are spatially variable, and the small number of Holocene paleoclimatic records may not adequately capture patterns of variation in the past. The hydrological history of Grenada was inferred from paleolimnological analyses of sediment cores from two crater lakes on the island. The basins were formed by volcanic activity some time during the Last Termination, but were dry between ca. 13 000 and ca. 7200 cal. a BP. After filling, the lakes were initially very shallow, and sedimentation was interrupted by a hiatus ca. 6300–5500 cal. a BP, followed by deposition of a thick tephra in both sites. After 5500 cal. a BP, lake level shows considerable multi‐centennial variability, superimposed upon a long‐term trend of generally higher lake level after 3200 cal. a BP. The pattern of lake‐level variation in Grenada shows some similarity with other Caribbean paleoclimatic records in terms of the timing of transitions, but differs from several classic studies in the sign of inferred precipitation change. The differences among records may reflect spatially variable precipitation patterns in the past in response to the position of the Intertropical Convergence Zone and to sea surface temperature influences on the trade winds and Caribbean low‐level jet. Copyright © 2011 John Wiley & Sons, Ltd.     

The Eltanin asteroid impact: possible South Pacific palaeomegatsunami footprint and potential implications for the Pliocene–Pleistocene transition

Large asteroid impacts are rare, and those into the deep ocean are rarer still. The Eltanin asteroid impact around 2.51 ± 0.07 Ma occurred at a time of great climatic and geological change associated with the Pliocene–Pleistocene boundary. Numerical models of the event indicate that a megatsunami was generated, although there is debate concerning its magnitude and the region‐wide extent of its influence. We summarise the existing evidence for possible Eltanin megatsunami deposits in Antarctica, Chile and New Zealand, while also examining other potential sites from several locations, mainly around the South Pacific region. In reviewing these data we note that these events were unfolding at the same time as those associated with the Pliocene–Pleistocene boundary and, as such, most of the geological evidence from that time has a climatic interpretation. The potential climatic and geological ramifications of the Eltanin asteroid impact, however, have failed to be considered by most researchers studying this time period. Although we are not advocating that all geological activity at that time is connected with the Eltanin asteroid impact, it raises interesting questions about the role potentially played by such catastrophic events in contributing to or even triggering epochal transitions. Copyright © 2012 John Wiley & Sons, Ltd.     

Metamorphism in oceanic layer 3, Gorringe Bank,eastern Atlantic

Gorringe Bank is an anomalously high structure of the eastern part of the north Atlantic, which was known to be composed of mantle-derived peridotites (layer 4) and gabbros (layer 3). During the submersible cruise CYAGOR II in 1981, the contact between layer 4 and layer 3 was observed on Mount Gettysburg and interpreted as tectonic. The overlying series of gabbro was extensively sampled on both mounts composing the bank, Gettysburg and Ormonde. Coarse-grained to pegmatoid clinopyroxene gabbros predominate and are associated with differentiated rocks (ferrogabbros and diorites). Cumulate gabbros are missing. The gabbroic section sampled is therefore interpreted as the upper part of the plutonic section. Most samples were strongly recrystallized during two distinct events. Metamorphism occurred close to the ridge axis, from interaction of a seawater-derived fluid with still hot gabbros. High temperature shear zones favoured fluid circulation, but the water/rock ratio — estimated from the sodium input — was very small in undeformed rocks (<1). The low W/R ratio explains the strong evolution of the fluid phase and therefore some particular compositions of secondary minerals. Low temperature alteration occurred when the gabbros were tectonically emplaced close to the sea bottom.     

Two-step deglaciation: 14C-Dated high-resolution δ18O records from the tropical Atlantic Ocean

Eight box cores from the tropical Atlantic were studied in detail with regard to foraminiferal oxygen isotopes, radiocarbon, and Globorotalia menardii abundance. A standard Atlantic oxygen-isotope signal was reconstructed for the last 20,000 yr. It is quite similar to the west-equatorial Pacific signal published previously. Deglaciation is seen to occur in two steps which are separated by a pause. Onset of deglaciation is after 15,000 yr B.P. The pause is centered between 11,000 and 12,000 yr B.P., but may be correlative with the Younger Dryas (10,500 yr B.P.) if allowance is made for a scale shift due to mixing processes on the sea floor. Step 2 is centered near 10,000 yr B.P. and is followed by a brief excursion toward light oxygen values. This excursion (the M event) may correlate with the Gulf of Mexico meltwater spike.     

Isotopic study of the Manaslu granite (Himalaya,Nepal): inferences on the age and source of Himalayan leucogranites

A detailed isotopic study of the Manaslu leucogranite was carried out. A U-Pb age of 25 Ma and a whole rock Rb-Sr age isochron of 18 Ma were obtained, suggesting that the magmatic activity lasted at least 7 Ma. Initial Sr isotopic ratios are very high (0.740 to 0.760) and initial Nd isotopic ratios are low ( _Nd ⁱⁿ : –13 to –16), and they show the existence of large isotopic variations even at the metre scale. These are not the result of perturbations by fluids but rather they reflect the initial isotopic heterogeneity of the source material which has not been obliterated by magmatic processes (e.g. fusion, mixing by convection). These results also support the crustal origin of this leucogranite. The Tibetan slab paragneisses, whose Sr and Nd isotopic ratios are very similar to those of the granite at an age of 20 Ma, are the most probable parental material. Nd model ages for both the leucogranite and the gneisses are in the range 1.5–2 Ga. A model of formation of the Manaslu granite by coalescence of different batches of magma is in agreement with the present data.     

Folding of passive layers and forms of minor structures near terminations of blind thrust faults—application to the central Appalachian blind thrust

The existence of detachment surfaces or décollement zones beneath folded rocks of the Valley and Ridge and Plateau provinces of the Appalachians has been recognized as an important condition of folding. Large folds at the border between the two provinces resulted primarily from repetition of strata by thrusting of blocks over ramp faults that connect detachement surfaces at different horizons. Some investigators have suggested that folds in the Plateau province of Pennsylvania were produced by splay faults arising from detachment surfaces, but field observations and theoretical analyses by Sherwin and by Wiltschko & Chapple suggest that the folds are a result of buckling of multilayered rocks above a décollement. An exception may be the Burning Springs anticline in West Virginia, which appears to have formed at the termination of a detachment surface.Investigation of the translation of an homogenous, viscous material above a flat detachment surface that terminates laterally indicates that the termination produces a broad, low-amplitude anticline in passive layering as a result of thickening induced by a gradient of shear stresses in the vertical direction. This thickening above the termination of a detachment is a mechanism of folding. If the viscous fluid contained mechanical layering, the fold would become amplified by buckling. Computations of stresses in the material indicate that minor faults should be generated first near the termination of the flat detachment surface. The Burning Springs anticline probably was initiated by termination of a detachment surface and subsequently amplified by buckling.