Cumulating processes at the crust-mantle transition zone inferred from Permian mafic-ultramafic xenoliths (Puy Beaunit,France)

Ultramafic and mafic xenoliths of magmatic origin, sampled in the Beaunit vent (northern French Massif Central), derive from the Permian (257 Ma) Beaunit layered complex (BLC) that was emplaced at the crust-mantle transition zone (∼1 GPa). These plutonic xenoliths are linked to a single fractional crystallisation process in four steps: peridotitic cumulates; websteritic cumulates; Al-rich mafic cumulates (plagioclase, pyroxenes, garnet, amphibole and spinel) and finally low-Al mafic cumulates. This sequence of cumulates can be related to the compositional evolution of hydrous Mg basaltic magma that evolved to high-Al basalt and finally to andesitic basalt. Sr and Nd isotopic compositions confirm the co-genetic character of the various magmatic xenoliths and argue for an enriched upper mantle source comparable to present mantle wedges above subduction zones. LILE, LREE and Pb enrichment are a common feature of all xenoliths and argue for an enriched sub-alkaline transitional parental magma. The existence of a Permian magma chamber at 30 km depth suggests that the low-velocity zone observed locally beneath the Moho probably does not represent an anomalous mantle but rather a sequence of mafic/ultramafic cumulates with densities close to those of mantle rocks.     

Folding of passive layers and forms of minor structures near terminations of blind thrust faults—application to the central Appalachian blind thrust

The existence of detachment surfaces or décollement zones beneath folded rocks of the Valley and Ridge and Plateau provinces of the Appalachians has been recognized as an important condition of folding. Large folds at the border between the two provinces resulted primarily from repetition of strata by thrusting of blocks over ramp faults that connect detachement surfaces at different horizons. Some investigators have suggested that folds in the Plateau province of Pennsylvania were produced by splay faults arising from detachment surfaces, but field observations and theoretical analyses by Sherwin and by Wiltschko & Chapple suggest that the folds are a result of buckling of multilayered rocks above a décollement. An exception may be the Burning Springs anticline in West Virginia, which appears to have formed at the termination of a detachment surface.Investigation of the translation of an homogenous, viscous material above a flat detachment surface that terminates laterally indicates that the termination produces a broad, low-amplitude anticline in passive layering as a result of thickening induced by a gradient of shear stresses in the vertical direction. This thickening above the termination of a detachment is a mechanism of folding. If the viscous fluid contained mechanical layering, the fold would become amplified by buckling. Computations of stresses in the material indicate that minor faults should be generated first near the termination of the flat detachment surface. The Burning Springs anticline probably was initiated by termination of a detachment surface and subsequently amplified by buckling.     

The Eltanin asteroid impact: possible South Pacific palaeomegatsunami footprint and potential implications for the Pliocene–Pleistocene transition

Large asteroid impacts are rare, and those into the deep ocean are rarer still. The Eltanin asteroid impact around 2.51 ± 0.07 Ma occurred at a time of great climatic and geological change associated with the Pliocene–Pleistocene boundary. Numerical models of the event indicate that a megatsunami was generated, although there is debate concerning its magnitude and the region‐wide extent of its influence. We summarise the existing evidence for possible Eltanin megatsunami deposits in Antarctica, Chile and New Zealand, while also examining other potential sites from several locations, mainly around the South Pacific region. In reviewing these data we note that these events were unfolding at the same time as those associated with the Pliocene–Pleistocene boundary and, as such, most of the geological evidence from that time has a climatic interpretation. The potential climatic and geological ramifications of the Eltanin asteroid impact, however, have failed to be considered by most researchers studying this time period. Although we are not advocating that all geological activity at that time is connected with the Eltanin asteroid impact, it raises interesting questions about the role potentially played by such catastrophic events in contributing to or even triggering epochal transitions. Copyright © 2012 John Wiley & Sons, Ltd.     

Photochemical degradation of phenanthrene as a function of natural water variables modeling freshwater to marine environments

Photolysis rates of phenanthrene as a function of ionic strength (salinity), oxygen levels and humic acid concentrations were measured in aqueous solution over the range of conditions found in fresh to marine waters. Photolysis followed first order kinetics, with an estimated photodegradation half-life in sunlight in pure water of 10.3±0.7h, in the mid-range of published results. Photolysis rate constants decreased by a factor of 5 in solutions with humic acid concentrations from 0 to 10 mg C L(-1). This decrease could be modeled entirely based on competitive light absorption effects due to the added humics. No significant ionic strength or oxygen effects were observed, consistent with a direct photolysis mechanism. In the absence of significant solution medium effects, the photodegradation lifetime of phenanthrene will depend only on solar fluxes (i.e. temporal and seasonal changes in sunlight) and not vary with a freshwater to marine environment.     

Earth’s Electromagnetic Environment

The natural spectrum of electromagnetic variations surrounding Earth extends across an enormous frequency range and is controlled by diverse physical processes. Electromagnetic (EM) induction studies make use of external field variations with frequencies ranging from the solar cycle which has been used for geomagnetic depth sounding through the 10\(^{-4}\)–10\(^4\) Hz frequency band widely used for magnetotelluric and audio-magnetotelluric studies. Above 10\(^4\) Hz, the EM spectrum is dominated by man-made signals. This review emphasizes electromagnetic sources at \(\sim\)1 Hz and higher, describing major differences in physical origin and structure of short- and long-period signals. The essential role of Earth’s internal magnetic field in defining the magnetosphere through its interactions with the solar wind and interplanetary magnetic field is briefly outlined. At its lower boundary, the magnetosphere is engaged in two-way interactions with the underlying ionosphere and neutral atmosphere. Extremely low-frequency (3 Hz–3 kHz) electromagnetic signals are generated in the form of sferics, lightning, and whistlers which can extend to frequencies as high as the VLF range (3–30 kHz).The roughly spherical dielectric cavity bounded by the ground and the ionosphere produces the Schumann resonance at around 8 Hz and its harmonics. A transverse resonance also occurs at 1.7–2.0 kHz arising from reflection off the variable height lower boundary of the ionosphere and exhibiting line splitting due to three-dimensional structure. Ground and satellite observations are discussed in the light of their contributions to understanding the global electric circuit and for EM induction studies.     

3-D assessment of peak-metamorphic conditions by Raman spectroscopy of carbonaceous material: an example from the margin of the Lepontine dome (Swiss Central Alps)

This study monitors regional changes in the crystallinity of carbonaceous matter (CM) by applying Micro-Raman spectroscopy to a total of 214 metasediment samples (largely so-called Bündnerschiefer) dominantly metamorphosed under blueschist- to amphibolite-facies conditions. They were collected within the northeastern margin of the Lepontine dome and easterly adjacent areas of the Swiss Central Alps. Three-dimensional mapping of isotemperature contours in map and profile views shows that the isotemperature contours associated with the Miocene Barrow-type Lepontine metamorphic event cut across refolded nappe contacts, both along and across strike within the northeastern margin of the Lepontine dome and adjacent areas. Further to the northeast, the isotemperature contours reflect temperatures reached during the Late Eocene subduction-related blueschist-facies event and/or during subsequent near-isothermal decompression; these contours appear folded by younger, large-scale post-nappe-stacking folds. A substantial jump in the recorded maximum temperatures across the tectonic contact between the frontal Adula nappe complex and surrounding metasediments indicates that this contact accommodated differential tectonic movement of the Adula nappe with respect to the enveloping Bündnerschiefer after maximum temperatures were reached within the northern Adula nappe, i.e. after Late Eocene time.     

Electrical conductivity of orthopyroxene and plagioclase in the lower crust

The electrical conductivities of lower crustal orthopyroxene and plagioclase, as well as their dependence on water content, were measured at 6–12 kbar and 300–1,000°C on both natural and pre-annealed samples prepared from fresh mafic xenolith granulites. The complex impedance was determined in an end-loaded piston cylinder apparatus by a Solarton-1260 Impedance/Gain Phase analyzer in the frequency range of 0.1–10⁶ Hz. The spectra usually show an arc over the whole frequency range at low temperature and an arc plus a tail in the high and low frequency range, respectively, at high temperature. The arc is due to conduction in the sample interior, while the tails are probably due to electrode effects. Different conduction mechanisms have been identified under dry and hydrous conditions. For the dry orthopyroxene, the activation enthalpy is ~105 kJ/mol, and the conduction is likely due to small polarons, e.g., electrons hopping between Fe²⁺ and Fe³⁺. For the dry plagioclase, the activation enthalpy is ~161 kJ/mol, and the conduction may be related to the mobility of Na⁺. For the hydrous samples, the activation enthalpy is ~81 kJ/mol for orthopyroxene and ~77 kJ/mol for plagioclase, and the electrical conductivity is markedly enhanced, probably due to proton conduction. For each mineral, the conductivity increases with increasing water content, with an exponent of ~1, and the activation enthalpies are nearly independent of water content. Combining these data with our previous work on the conductivity of lower crustal clinopyroxene, the bulk conductivity of lower crustal granulites is modeled, which is usually >~10⁻⁴ S/m in the range of 600–1,000°C. We suggest that the high electrical conductivity in most regions of the lower crust, especially where it consists mostly of granulites, can be explained by the main constitutive minerals, particularly if they contain some water. Contributions from other highly conducting materials such as hydrous fluids, melts, or graphite films are not strictly necessary to explain the observed conductivities.     

Static compression of α-MnS at 298 K to 21 GPa

To investigate the equation of state of -MnS at high pressure and the possibility of a phase transition, the compression curve was measured at 298 K from 0 to 21 GPa using powder x-ray diffraction with a diamond anvil cell. The compression data are fit to a thirdorder Birch-Murnaghan equation of state, with parameters K ₀ = 72(2) GPa and K ₀ = 4.2(13). To compare present results with previous work, the data sets from three previous investigations (Clendenen and Drickamer 1966; Wakabayashi et al. 1968; Kraft and Greuling 1988) are refit to a Birch-Murnaghan equation of state. In the low pressure region (P < 10=" gpa),=" the=" results=" of=" clendenen=" and=" drickamer=" (1966)=" agree=" with=" the=" present=" data;=" however=" the=" results=" of=" wakbayashi=" et=" al.=" (1968)=" differ=" by=" more=" than=" 10%.=" a=" greater=" discrepancy=" between=" the=" present=" and=" previous=" results=" occurs=" above=" 10=" gpa.=" kraft=" and=" greuling=" (1988)=" reported=" a=" structure=" transition=" at=" 7=" gpa,=" and=" clendenen=" and=" drickamer=" (1966)=" observed=" a=" structure=" distortion=" at=" approximately=" 10=" gpa;=" the=" present=" data=" show=" no=" evidence=" of=" either=" transition,=" and=" are=" well=" fit=" by=" a=" single=" equation=" of=" state=" from=" 0=" to=" 21=" gpa.=" nonhydrostatic=" stress=" is=" discussed=" as=" one=" possibility=" for=" the=">     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.