Monazite chemistry: evidence for a prehistoric journey

The chemistry of monazite from the black sand deposits of northern Sinai beach suggests that pegmatites and granites of the Eastern Desert of Egypt are the most likely source rocks. The floods associated with the pluvial periods prevailed in Egypt during the Pleistocene were able to erode the source rocks and liberate heavy minerals including monazite. The mineral grains were moved through several wadis and tributaries to the River Nile. At the confluence sites, these heavy minerals were mixed with the Ethiopian and central African heavy mineral assemblages. The grains continued to move together downriver until being deposited in their current locations.     

Pleistocene landscapes in central Iberia inferred from pollen analysis of hyena coprolites

New pollen data from hyena coprolites from central Spain are presented. The fossil faecal material has been recovered from two karstic systems in different localities, Villacastín and Los Torrejones, which are both around 1000 m a.s.l. The combined findings of bone remains and coprolites in both locations suggest the following chronology: late Middle Pleistocene for Villacastín and early Upper Pleistocene for Los Torrejones. The environments inferred from pollen are broadly in keeping with evidence from associated vertebrate fossil remains, and include a shifting mosaic of open and wooded habitats with abundant pine and juniper species, steppe‐grassland areas with composites and chenopods, and enclaves with mixed oak forests. However, Los Torrejones appears to have been less forested than Villacastín. The abundance of oaks in Villacastín may imply the presence of refugia within an interconnected network of several enclaves during the glacial stages in the Upper Pleistocene. A possible explanation for the patchiness of the landscape may be in the role of herbivores, although the long distances and variety of habitats that hyenas had to roam through could be another explanation for the heterogeneous pollen contents in their dung. Copyright © 2006 John Wiley & Sons, Ltd.     

Recycling of Proterozoic crust in the Andean Amazon foreland of Ecuador: implications for orogenic development of the Northern Andes

The retro‐arc foreland Andean Amazon Basin records sedimentary infill from the South American craton and the emerging Northern Andean chain from the middle Cretaceous until Present day. The U/Pb ages of detrital zircons indicate significant reworking of Archean‐Proterozoic (max. 2.9 Ga) and Paleozoic crust and sediments, which were eroded on both sides. Heavy mineral associations show that the material derived from Proterozoic craton was supplied by Cretaceous reworking of non‐metamorphosed (unannealed) Paleozoic and older sedimentary rocks, which cover the Amazon Craton. Following latest Cretaceous switch of the dominant sediment source to the Andean cordillera, the influx of Precambrian zircons persisted, and these zircons were derived from the metamorphosed basement and Paleozoic sediments of the Cordillera Real (Loja terrane). Re‐evaluation of existing detrital zircon fission‐track record proves that the rise of the Cordillera Real at the Cretaceous‐Tertiary transition was initiated by the collision of Caribbean Oceanic Plateau and associated arc elements from 75–65 Ma. A further important exhumation event also occurred in the Late Oligocene, which is correlated with the break‐up of the Farallon plate.     

Analysis of the water content in an unconfined aquifer with a partially penetrated pumping well

Most methods developed to represent water flow phenomena in an unconfined aquifer with a fully penetrated pumping well are either numerical, such as the well‐known FEMWTER model, or experimental; analytical models of a partially penetrated pumping well are rare. This study employs the linearized Richards equation as the governing equation, with the aid of Fourier Integral Transformation, to obtain an analytical solution of the water content distribution in an unconfined aquifer with a partially penetrated pumping well. The results from this study could serve to substantiate in some sense results from numerical models. In addition, the theory developed herein can be modified to simulate a vacuum‐pressured pumping well since it is derived by considering, among others, the location and length of a well screen with fluxes. Copyright © 2008 John Wiley & Sons, Ltd.     

Agricultural land use and hydrology affect variability of shallow groundwater nitrate concentration in South Florida

South Florida's Miami‐Dade agricultural area is located between two protected natural areas, the Biscayne and Everglades National Parks, subject to the costliest environmental restoration project in history. Agriculture, an important economic activity in the region, competes for land and water resources with the restoration efforts and Miami's urban sprawl. The objective of this study, understanding water quality interactions between agricultural land use and the shallow regional aquifer, is critical to the reduction of agriculture's potentially negative impacts. A study was conducted in a 4‐ha square field containing 0·9 ha of corn surrounded by fallow land. The crop rows were oriented NW–SE along the dominant groundwater flow in the area. A network of 18 monitoring wells was distributed across the field. Shallow groundwater nitrate–nitrogen concentration [N‐NO₃^?] was analyzed on samples collected from the wells biweekly for 3 years. Detailed hydrological (water table elevation [WTE] at each well, groundwater flow direction [GwFD], rainfall) and crop (irrigation, fertilization, calendar) data were also recorded in situ. Flow direction is locally affected by seasonal regional drainage through canal management exercised by the local water authority. The data set was analyzed by dynamic factor analysis (DFA), a specialized time series statistical technique only recently applied in hydrology. In a first step, the observed nitrate variation was successfully described by five common trends representing the unexplained variability. By including the measured hydrological series as explanatory variables the trends were reduced to only three. The analysis yields a quantification of the effects of hydrological factors over local groundwater nitrate concentration. Furthermore, a spatial structure across the field, matching land use, was found in the five remaining common trends whereby the groundwater [N‐NO₃^?] in wells within the corn rows could be generally separated from those in fallow land NW and SE of the crop strip. Fertilization, masked by soil/water/plant‐delayed processes, had no discernible effect on groundwater nitrate levels. Copyright © 2006 John Wiley & Sons, Ltd.     

Synsedimentary brecciation in the Eifelian (Middle Devonian) Baltic Basin: sudden catastrophe or diagenetic collapse?

The Eifelian sedimentary record in the epeiric Baltic Basin contains an extensive brecciated interval known as the Narva Breccia. During recent decades, the origin of this breccia has been attributed to (1) palaeoseismicity, (2) extraterrestrial impact event or (3) diagenetic collapse. Our studies show the presence of two different breccia types that form 11 stratigraphic horizons and contain several laterally and stratigraphically unrelated breccias. The occurrence of Type‐1 and Type‐2 breccias, together with carbonate sabkha and carbonate inter‐ to supratidal tidal flat deposits on the basin margins, indicates synsedimentary brecciation formed in a sabkha environment. Type‐2 breccia could also originate from wave‐cycling loading.     

Modelling chemo‐hydro‐mechanical behaviour of unsaturated clays: a feasibility study

Effective capabilities of combined chemo‐elasto‐plastic and unsaturated soil models to simulate chemo‐hydro‐mechanical (CHM) behaviour of clays are examined in numerical simulations through selected boundary value problems. The objective is to investigate the feasibility of approaching such complex material behaviour numerically by combining two existing models. The chemo‐mechanical effects are described using the concept of chemical softening consisting of reduction of the pre‐consolidation pressure proposed originally by Hueckel (Can. Geotech. J. 1992; 29 :1071–1086; Int. J. Numer. Anal. Methods Geomech. 1997; 21 :43–72). An additional chemical softening mechanism is considered, consisting in a decrease of cohesion with an increase in contaminant concentration. The influence of partial saturation on the constitutive behaviour is modelled following Barcelona basic model (BBM) formulation (Géotech. 1990; 40 (3):405–430; Can. Geotech. J. 1992; 29 :1013–1032). The equilibrium equations combined with the CHM constitutive relations, and the governing equations for flow of fluids and contaminant transport, are solved numerically using finite element. The emphasis is laid on understanding the role that the individual chemical effects such as chemo‐elastic swelling, or chemo‐plastic consolidation, or finally, chemical loss of cohesion have in the overall response of the soil mass. The numerical problems analysed concern the chemical effects in response to wetting of a clay specimen with an organic liquid in rigid wall consolidometer, during biaxial loading up to failure, and in response to fresh water influx during tunnel excavation in swelling clay. Copyright © 2005 John Wiley & Sons, Ltd.     

Exhumation across the Indus Suture Zone: a record of back sliding of the hanging wall

The Kohistan Arc Complex is an integral part of the NW Himalayan collision system and is bounded by two major suture zones, the Indus Suture Zone (ISZ) and the Northern Suture in the south and north respectively. Fission‐track analyses on samples collected along the Indus River across the arcuated ISZ in the Besham region are presented here. The footwall yields zircon and apatite fission‐track (FT) ages of ∼23 Ma and ∼3.7 Ma respectively; the hanging wall ages range from 24 to 42 Ma for zircon and ∼10 Ma for apatite. Thus, the change in ISZ kinematics from thrusting to normal faulting was not later than Oligocene and normal faulting on this ISZ segment was still active at least into early Pliocene times. At this time normal faulting had already ended at other ISZ segments, but it was still (or again) active across the ISZ in the Besham region most likely as a local phenomenon caused by the growth of the Indus Syntaxis, a transverse antiform parallel to the Nanga Parbat Syntaxis.     

Phosphorus in groundwater—an overlooked contributor to eutrophication?

This paper presents the first international assessment of phosphorus concentrations in groundwater, using data from the Republic of Ireland, Northern Ireland, Scotland, England and Wales. Phosphorus is considered to be the main limiting nutrient in most freshwater ecosystems. Controlling phosphorus inputs is thus considered the key to reducing eutrophication and managing ecological quality. Very little attention has been paid to evaluating transfers via groundwater due to the long‐held belief that adsorption and metal complex formation retain the majority of potentially mobile phosphorus. In each country, ecologically‐important phosphorus thresholds are exceeded in a significant number of groundwater samples. The relative contributions of potential sources for these elevated concentrations are currently unclear but there is evidence to suggest that they are at least partly anthropogenic. The results suggest that groundwater P concentrations are such that they may be a more important contributor to surface water phosphorus than previously thought. Copyright © 2008 John Wiley & Sons, Ltd.