Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Source flow expansion of monatomic gas into vacuum under external field of forces

The steady flow expansions of monatomic gases consisting of Maxwellia molecules into a vacuum moving under external forces with a source of spherical symmetry are investigated. The analysis is based on the B-G-K model of the Boltzmann equation with the approximation in hypersonic limit. The kinetic equation is solved by using the moment method. Analytical forms for the density and temperature are obtained for small and large distances from the source. The results show that the temperature in free expansion is less than that in the case of the expansion under the influence of external field of forces.     

Spatial and temporal variations of solar coronal loops

Skylab EUV observations of an active region near the solar limb were analyzed. Both cool (T < 10⁶ K) and hot (T > 10⁶ K) loops were observed in this region. For the hot loops the observed intensity variations were small, typically a few percent over a period of 30 min. The cool loops exhibited stronger variations, sometimes appearing and disappearing in 5 to 10 min. Most of the cool material observed in the loops appeared to be caused by the downward flow of coronal rain and by the upward ejection of chromospheric material in surges. The frequent EUV brightenings observed near the loop footpoints appear to have been produced by both in situ transient energy releases (e.g. subflares) and the infall/impact of coronal rain. The physical conditions in the loops (temperatures, densities, radiative and conducting cooling rates, cooling times) were determined. The mean energy required to balance the radiative and conductive cooling of the hot loops is approximately 3 × 10^–3 erg cm^–3 s^–1. One coronal heating mechanism that can account for the observed behavior of the EUV emission from McMath region 12634 is heating by the dissipation of fast mode MHD waves.     

Partial derivatives of surface wave phase velocities for flat anisotropic models

Summary. Surface wave behaviour in flat anisotropic structures is first illustrated by performing an exact computation on a simple two-layer model. The variational procedure of Smith & Dahlen is then used to compute the partial derivatives of surface wave phase velocities with respect to the elastic parameters in more realistic earth models. Linear relationships between the partial derivatives for a general anisotropic structure and those for a transversely isotropic structure are derived. When considering waves propagating in a fixed direction, there are only four independent derivatives for Rayleigh waves, and two for Love waves. To avoid the lack of resolution in an inverse method, we propose to use physically constrained models. These results are illustrated by using a model with hexagonal symmetry and a symmetry axis oriented either vertically or horizontally. Quasi-Love- and quasi-Rayleigh-wave partial derivatives are computed for both axis orientations. Modes up to the second overtone and periods ranging between 45 and 130 s have been considered. Finally, anomalies of phase velocity are computed in an oceanic model made of 1/6 oriented olivine crystals with horizontal or vertical preferred orientations of the a -axis.     

A comparison of artificial solar granules with real solar granules

The lifetimes, characteristics of the shapes as well as lengths and perimeters of artificial solar granules (Nordlund, 1982, 1984a) are compared with data from the literature and parameters determined from two different sets of observed granules. No significant differences of the parameters for these sets of granules are detectable.Mitteilungen aus dem Kiepenheuer-Institut Nr. 251.     

Arsenic incorporation in a salt marsh ecosystem

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.