Robust Regulation of Alkalinity in Highly Uncertain Continuous Anaerobic Digestion Processes

In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.     

The use of radon as tracer in environmental sciences

Radon can be used as a naturally occurring tracer for environmental processes. By means of grab-sampling or continuous monitoring of radon concentration, it is possible to assess several types of dynamic phenomena in air and water. We present a review of the use of radon and its progeny at the University of Cantabria. Radon can be an atmospheric dynamics indicator related with air mass interchange near land-sea discontinuities as well as for the study of vertical variations of air parameters (average values of different types of stability: 131–580 Bq m^?3). Concerning indoor gas, we present some results obtained at Altamira Cave (Spain): from 222 to 6549 Bq m^?3 (Hall) and from 999 to 6697 Bq m^?3 (Paintings Room). Finally, variations of radon concentration in soil (0.3 to 9.1 kBq m^?3) and underground water (values up to 500 Bq l^?1) provide relevant information about different geophysical phenomena.     

Strike‐slip tectonics and basin inversion in the Western Mediterranean: the Post‐Messinian evolution of the Alboran Sea

A comprehensive interpretation of single and multichannel seismic reflection profiles integrated with biostratigraphical data and log information from nearby DSDP and ODP wells has been used to constrain the late Messinian to Quaternary basin evolution of the central part of the Alboran Sea Basin. We found that deformation is heterogeneously distributed in space and time and that three major shortening phases have affected the basin as a result of convergence between the Eurasian and African plates. During the Messinian salinity crisis, significant erosion and local subsidence resulted in the formation of small, isolated, basins with shallow marine and lacustrine sedimentation. The first shortening event occurred during the Early Pliocene (ca. 5.33–4.57 Ma) along the Alboran Ridge. This was followed by a major transgression that widened the basin and was accompanied by increased sediment accumulation rates. The second, and main, phase of shortening on the Alboran Ridge took place during the Late Pliocene (ca. 3.28–2.59 Ma) as a result of thrusting and folding which was accompanied by a change in the Eurasian/African plate convergence vector from NW‐SE to WNW‐ESE. This phase also caused uplift of the southern basins and right‐lateral transtension along the WNW‐ENE Yusuf fault zone. Deformation along the Yusuf and Alboran ridges continued during the early Pleistocene (ca. 1.81–1.19 Ma) and appears to continue at the present day together with the active NNE‐SSW trending Al‐Idrisi strike‐slip fault. The Alboran Sea Basin is a region of complex interplay between sediment supply from the surrounding Betic and Rif mountains and tectonics in a zone of transpression between the converging African and European plates. The partitioning of the deformation since the Pliocene, and the resulting subsidence and uplift in the basin was partially controlled by the inherited pre‐Messinian basin geometry.     

Possibilities of GPS kinematic measurements for geological survey in East Slovakia

This paper deals with transformation procedures for observed GPS data from the world geodetic system WGS-84 into the national geodetic grid datum S-UTCN (system of united trigonometric cadaster network) and Baa (the Baltic Sea after adjustment). Transformation from WGS-84 into SUTCN is performed most frequently by means of the 7-element Helmert transformation with three identical points. Geodetic network was adjusted by two ways.     

Deforestation and fragmentation of seasonal tropical forests in the southern Yucatán,Mexico (1990–2006)

The southern Yucatán (SY) has been recognized as a hotspot of biodiversity with great risk of deforestation. Land change analysis, based on classified Landsat TM and ETM?+?satellite imagery (1990, 2000 and 2006), was used to estimate the annual deforestation rates of 141 land management units of the SY, and spatial patterns of forest fragmentation around and within the Calakmul Biosphere Reserve (CBR), which comprises approximately one-third of the region. Results indicate a decrease in annual deforestation rates over 1990–2006, from 0.15% year^?1 to 0.06% year^?1, but with significant sub-regional variations in the quantity and rate of forest loss. Despite a decline in deforestation during this period, there was considerable fragmentation both inside and outside the CBR. While population pressures and the expansion of pasture have caused deforestation across the region, agricultural intensification, diversified income strategies and reserve conservation may have contributed to reduced forest loss during the study period.     

Mapping burns and natural reforestation using thematic Mapper data

Remote sensing techniques are specially suitable to detect and to map areas affected by forest fires. In this work, Landsat 5 Thematic Mapper (TM) data has been used to study a number of forest fires that occurred in the province of Valencia (Spain) and to monitor the vegetation regeneration over burnt areas.

A reference area (non‐burnt forest) was established to assess the change produced by fire. The radiance in the thermal band (10.4–12.5 μm) and the normalized difference in reflectance between near 1R (0.76–0.90 μm) and middle IR (2.08–2.35 μm) were the most suitable parameters to map burnt areas. This index can also be used for monitoring vegetation regeneration in burnt areas. About a month after the fire, the burns show temperatures of 5–6 °C higher than those found in the reference area, and the vegetation index shows negative values whereas the reference area values remain positive. The differences between the burns and the reference area for the vegetation index decrease with time as vegetation regenerates.     

Disentangling Turbulent Gas Diffusion from Non-diffusive Transport in the Boundary Layer

Boundary-Layer Meteorology - An analysis based on the law of linear momentum conservation demonstrates unequivocally that the mass fraction is the scalar whose gradient determines gas diffusion,...     

Projections of severe droughts in future climate in Southeast Brazil: a case study in Southern Minas Gerais State,Brazil

Theoretical and Applied Climatology - South of Minas Gerais state, in Southeast Brazil, is known for the coffee crop production (more than 30% of country’s production) and hydroelectricity...     

The evolution of the hydrothermal IOCG system in the Mantoverde district,northern Chile: new evidence from microthermometry and stable isotope geochemistry

New microthermometric data combined with stable isotope geochemistry and paragenetic relationships support a previously suggested cooling–mixing model for the iron oxide–copper–gold mineralization in the Mantoverde district. Fluid inclusions show characteristics of a CO₂-bearing aqueous NaCl ± CaCl₂ salt system. The evolution of the Mantoverde hydrothermal system is characterized by (1) an early hypersaline, high to moderate temperature fluid; (2) a moderate saline, moderate temperature fluid; and (3) a low saline, moderate to low temperature fluid. Early magnetite formation took place at median temperatures of 435.0°C, whereas hematite formed at median temperatures of 334.4°C. The main sulfide mineralization texturally post-dates the iron oxides and occurred before late-stage calcite, which developed at a median temperature of 244.8°C. Boiling occurs only locally and is of no relevance for the ore formation. The microthermometric and stable isotope data are supportive for a fluid cooling and mixing model, and suggestive for a predominantly magmatic–hydrothermal fluid component during the iron oxide and main sulfide mineralization. Thereafter, the incursion of a nonmagmatic fluid of ultimately meteoric or seawater gains more importance.     

Fluid evolution of the Hub Stock, Horní Slavkov–Krásno Sn–W ore district, Bohemian Massif, Czech Republic

The Horní Slavkov–Krásno Sn–W ore district is hosted by strongly altered Variscan topaz–albite granite (Krudum granite body) on the northwestern margin of the Bohemian Massif. We studied the fluid inclusions on greisens, ore pockets, and ore veins from the Hub Stock, an apical expression of the Krudum granite. Fluid inclusions record almost continuously the post-magmatic cooling history of the granite body from ～500 to <50°C. Rarely observed highest-temperature (～500°C) highest-salinity (～30?wt.% NaCl eq.) fluid inclusions are probably the result of secondary boiling of fluids exsolved from the crystallizing magma during pressure release which followed hydraulic brecciation of the gneissic mantle above the granite cupola. The greisenization was related to near-critical low-salinity (0–7?wt.% NaCl eq.) aqueous fluids with low amount of CO₂, CH₄, and N₂ (≤10?mol% in total) at temperatures of ～350–400°C and pressures of 300–530 bar. Crush-leach data display highly variable and negatively correlated I/Cl and Br/Cl values which are incompatible with both orthomagmatic and/or metamorphic origin of the fluid phase, but can be explained by infiltration of surficial and/or sedimentary fluids. Low fluid salinity indicates a substantial portion of meteoric waters in the fluid mixture that is in accordance with previous stable isotope data. The post-greisenization fluid activity associated with vein formation and argillitization is characterized by decreasing temperature (<350 to <50°C), decreasing pressure (down to ～50–100 bar), and mostly also decreasing salinity.