‘Thailand was a desert' during the mid‐Cretaceous: Equatorward shift of the subtropical high‐pressure belt indicated by eolian deposits (Phu Thok Formation) in the Khorat Basin,northeastern Thailand

The Tibetan Plateau is a key factor in controlling the present‐day climate and atmospheric circulation pattern in Asia. The pattern of atmospheric circulation after the uplift of the plateau is well known, whereas direct evidence is lacking regarding the nature of the circulation pattern prior to the uplift. The distribution of desert directly reflects the position of the subtropical high‐pressure belt, and the prevailing surface‐wind pattern recorded in desert deposits reveals the position of its divergence axis. Cretaceous eolian sandstone of the Phu Thok Formation is extensively exposed in the northern Khorat Basin, northeastern Thailand. We conducted a sedimentological study on this formation to reconstruct temporal changes in the latitude of the subtropical high‐pressure belt in low‐latitude Asia during the Cretaceous. Spatio‐temporal changes in the paleo‐wind directions recorded in the Phu Thok Formation reveal that the Khorat Basin mainly belonged to the northeast trade wind belt and subtropical high‐pressure belt was situated to the north of the Khorat Basin during the initial stages of deposition, shifted southward to immediately above the basin during the main phase of deposition, and then shifted northward again to the north of the basin during the final stages of deposition. The paleomagnetic polarity sequence obtained for the Phu Thok Formation comprises three zones of normal polarity and two of reversed polarity, correlating to chrons M1n to C34n of the geomagnetic polarity time scale. This result suggests that the Phu Thok Formation is mid‐Cretaceous in age (from c. 126 Ma to c. 99–93 Ma), similar to the age of eolian sandstone in the Sichuan Basin, southern China (the Jiaguan Formation). These results, in combination with paleo‐wind direction data, suggest the development of low‐latitude desert and an equatorward shift of the subtropical high‐pressure belt (relative to the present‐day) in Asia during the mid‐Cretaceous.     

Sources and depositional processes of tsunami deposits: Analysis using foraminiferal tests and hydrodynamic verification

Foraminiferal tests are commonly found in tsunami deposits and provide evidence of transport of sea floor sediments, sometimes from source areas more than 100 m deep and several kilometers away. These data contribute to estimates of the physical properties of tsunami waves, such as their amplitude and period. The tractive force of tsunami waves is inversely proportional to the water depth at sediment source areas, whereas the horizontal sediment transport distance by tsunami waves is proportional to the wave period and amplitude. We derived formulas for the amplitudes and periods of tsunami waves as functions of water depth at the sediment source area and sediment transport distance based on foraminiferal assemblages in tsunami deposits. We applied these formulas to derive wave amplitudes and periods from data on tsunami deposits in previous studies. For some examples, estimated wave parameters were reasonable matches for the actual tsunamis, although other cases had improbably large values. Such inconsistencies probably reflect: (i) local amplification of tsunami waves by submarine topography, such as submarine canyons; and (ii) errors in estimated water depth at the sediment source area and sediment transport distance, which mainly derive from insufficient identification of foraminiferal tests.     

Soft‐sediment deformation structures in Cretaceous non‐marine deposits of southeastern Gyeongsang Basin,Korea: Occurrences and origin

A variety of soft‐sediment deformation structures formed during or shortly after deposition occurs in the Cretaceous Seongpori and Dadaepo Formations of the southeastern Gyeongsang Basin exposed along coastal areas of southeastern Korean Peninsula for 0.5–2 km. These are mostly present in a fluvial plain facies, with interbedded lacustrine deposits. In this study, the features of different kinds of soft‐sediment deformation structures have been interpreted on the basis of sedimentology of structure‐bearing deposits, comparison with normal sedimentary structures, timing and mechanism of deformation, and triggering mechanisms. The soft‐sediment deformation structures can be classified into four morphological groups: (i) load structures (load casts, ball‐and‐pillow structures); (ii) soft‐sediment intrusive structures (dish‐and‐pillars, clastic dykes, sills); (iii) ductile disturbed structures (convolute folds, slump structures); and (iv) brittle deformation structures (syndepositional faulting, dislocated breccia). The most probable triggering mechanisms resulting in these structures were seismic shocks. These interpretations are based on the following field observations: (i) location of the study area within tectonically active fault zone reactivated several times during the Cretaceous; (ii) deformation structures confined to single stratigraphic levels; (iii) lateral continuity and occurrences of various soft‐sediment deformation structures in the deformed level over large areas; (iv) absence of depositional slope to indicate gravity sliding or slumping; and (v) similarity to the structures produced experimentally. The soft‐sediment deformation structures in the study areas are thus interpreted to have been generated by seismic shocks with an estimated magnitude of M > 5, representing an intermittent record of the active tectonic and sedimentary processes during the development and evolution of two formations from the late Early Cretaceous to the Late Cretaceous.     

Metal Ion Extraction with Bipyridine Derivatives as Chelating Ligands in Supercritical Carbon Dioxide

Three fluorinated bipyridine ligands have been designed and synthesized as chelating agents for the extraction of metal ions in supercritical CO₂ (sc‐CO₂). The ligand solubilities in sc‐CO₂ were investigated at different temperatures and pressures, and the measured data have been correlated using a semiempirical model. The calculated results showed satisfactory agreement with the experimental data. Based on these data, metal ion extraction with the three compounds as chelating agents in sc‐CO₂ was performed from spiked filter paper, whereby ligand 1 showed the highest extraction efficiency, especially for Ni²⁺ and Cu²⁺. The extraction constants, K_ex, of the three chelating ligands were seen to increase with increasing extraction efficiency for the same metal ion in the same extraction system.     

Effect of Initial Azo Dye Concentration and Biomass Acclimation on Sludge Digestion and Dye Co‐treatment

The effect of a reactive azo dye (the hydrolyzed form of Reactive Orange 107, HRO107) on the digestion of municipal waste sludge (WS) was studied. The study also focused on the effect of acclimation of the anaerobic mixed culture on dye treatment. Anaerobic batch assays were carried out in serum bottles under mesophilic conditions. Unacclimated and acclimated anaerobic mixed cultures were used for the study. Both unacclimated and acclimated anaerobic cultures completely reduced HRO107 during WS digestion. Inhibitory HRO107 concentration was found to be 800 mg/L for unacclimated mixed culture. Acclimation increased the inhibitory concentration level from 800 to 3200 mg/L. Sulfanilic acid and four other unidentified dye reduction end products were detected at the end of the assays. The results of this study indicated that anaerobic municipal WS digesters have the potential to be a cost efficient and effective pre treatment method.     

Atmospheric and Surface Water Pollution Interpretation in the Gdańsk Beltway Impact Range by the Use of Multivariate Analysis

The present study deals with the application of the hierarchical cluster analysis and non‐parametric tests in order to interpret the Gdańsk Beltway impact range. The data set represents concentration values for major inorganic ions (Na⁺, NH, K⁺, Mg²⁺, Ca²⁺, F⁻, Cl⁻, NO, and SO) as well as electrolytic conductivity and pH measured in various water samples [precipitation, throughfall water, road runoff, and surface water (drainage ditches, surface water reservoirs, and spring water)] collected in the vicinity of the beltway. Several similarity groups were discovered both in the objects and in the variables modes according to the water sample. In the majority of cases clear anthropogenic (fertilizers usage and transport, road salting in winter) and semi‐natural (sea salt aerosols, erosion of construction materials) impacts were discovered. Spatial variation was discovered for road runoff samples and samples collected from surface water reservoirs and springs. Surprisingly no clear seasonal variability was discovered for precipitation chemistry, while some evidences for existing of summer and winter specific chemical profile was discovered for road runoff samples. In general, limited range of the Gdańsk Beltway impact was proven.     

Analysis of the contribution of natural sources of radiation to the total dose received by workers

People working with ionising radiation are receiving radiation coming from artificial and natural sources. In Spain, as in many other countries, there is a serious control by the national authorities, Spanish Nuclear Safety Council, of the dose the workers receive from artificial sources. However, until the publication of the European Basic Safety Standards Directive, 96/29/EURATOM, the old criteria referring to the “above natural background” were widely used. This directive was incorporated to the Spanish legislation in July 2001 (BOE 178); in its Title VII it recommends to evaluate the dose coming from natural sources and take it into account for establishing the safety criteria. It is noteworthy to assess the natural doses received at homes and the dose received by workers of radioactive installations subject to regulations, and to compare the two results. The social and economical implications of the results derived can be important in the practical application of the recommendations included in the above-mentioned BOE 178 Directive.     

Copula‐based joint probability function for PGA and CAV: a case study from Taiwan

This study aims to develop a joint probability function of peak ground acceleration (PGA) and cumulative absolute velocity (CAV) for the strong ground motion data from Taiwan. First, a total of 40,385 earthquake time histories are collected from the Taiwan Strong Motion Instrumentation Program. Then, the copula approach is introduced and applied to model the joint probability distribution of PGA and CAV. Finally, the correlation results using the PGA‐CAV empirical data and the normalized residuals are compared. The results indicate that there exists a strong positive correlation between PGA and CAV. For both the PGA and CAV empirical data and the normalized residuals, the multivariate lognormal distribution composed of two lognormal marginal distributions and the Gaussian copula provides adequate characterization of the PGA‐CAV joint distribution observed in Taiwan. This finding demonstrates the validity of the conventional two‐step approach for developing empirical ground motion prediction equations (GMPEs) of multiple ground motion parameters from the copula viewpoint. Copyright © 2016 John Wiley & Sons, Ltd.     

The structural,geometric and volumetric changes of a polythermal Arctic glacier during a surge cycle: Comfortlessbreen,Svalbard

Various parameters of the most recent surge of the polythermal glacier Comfortlessbreen in northwest Svalbard, have been assessed through a combination of remote sensing and ground observations. Analysis of a digital elevation model time‐series shows a marked change in the geometry of the glacier from quiescence (1990 and earlier) into the late surge phase (2009). The transfer of 0.74 km³ of ice caused up to 80 m of surface drawdown in the reservoir area, above the equilibrium line, whilst ice built up in a spatially concentrated manner in the receiving zone, below the equilibrium line. A ramp of ice, c. 100 m above quiescent level, developed in the lower reaches of the glacier late in the surge. Also in the lower reaches of the glacier, structures attributable to the passage of a kinematic wave are identified and the migration of a surge front on the glacier is thus inferred. In a conceptual model, we consider that a bend in the valley, in which the glacier resides, and convergence with tributary glaciers, to be significant factors in the style of surge evolution. Their flow‐restrictive interference results in slow initial mass‐transfer and the growth of a surge front within 3–4 km of the terminus. Copyright © 2015 John Wiley & Sons, Ltd.