Geochemistry,chronology and stratigraphy of Neogene tuffs of the Central Andean region

Tuff layers are vital stratigraphic tools that allow correlations to be made between widely dispersed exposures. Despite their widespread occurrence in the central Andes, tuffs from both natural exposures and sedimentary cores extracted from the region's extensive salars (salt pans) are relatively unstudied. Here we lay the foundation for a tephrostratigraphic framework in the central Andes (14–28°S) by chemically and morphologically characterizing ash shards, and in some cases dating 36 Neogene distal tuffs. These tuffs occur in lacustrine and alluvial deposits from the southern Bolivian Altiplano and adjacent Atacama Desert. All tuffs are calc-akaline rhyolites, consistent with their setting in the Central Andean Volcanic Zone. Five of the older tuffs were ⁴⁰Ar/³⁹Ar dated and yield an age range of 6.63–0.75 Ma. Organic material associated with tuffs deposited into paleolake sediments, paleowetland deposits, or urine-encrusted rodent middens provide constraints on the age of several Late Pleistocene and Holocene tuffs.These tuffs provide key stratigraphic markers and ages for lake cycles and archeological sites on the Bolivian Altiplano and for assessing rates of surficial processes and archeology in both the Atacama and Altiplano. While modern climate, and consequently questions about geomorphic processes and climate change, differs in the hyperarid Atacama and the semi-arid Altiplano, the most extensive air-fall tuffs covered both regions, placing the Atacama and the Bolivian Altiplano in the same tephrostratigraphic province. For example, the Escara B tuff (～1.85 Ma), can be securely identified in both the Altiplano and Atacama. On the Altiplano, dates from the Escara B and E tuffs securely establish the age of the Escara Formation—representing the oldest expansive lake documented on the Bolivian Altiplano. By contrast, the presence of the Escara B tuff below ～6 m of alluvial sediment at the Blanco Encalado site in the Atacama desert yields information about sedimentation rates in this hyperarid region. Indeed, most tuffs from the Atacama Desert are older than 600,000 years, even though they occur within fluvial terraces immediately adjacent to the alluvial fans that are still active. Most of these geomorphic surfaces in the Atacama also possess well-developed saline soils that, when combined with the radiometric ages of the distal tuffs, suggest slow rates of geomorphic change and exceptional landscape stability for this area during the Quaternary.In contrast, younger tuffs are more abundant in the more recent lake records of the Altiplano. The Chita tuff was deposited at ～15,650 cal yr B.P., during the regressive phase of the region's deepest late Quaternary lake cycle—the “Tauca lake cycle”—which spanned 18.1–14.1 cal yr B.P. Two Holocene tuffs, the Sajsi tuff and the Cruzani Cocha tuff, are widespread. The Sajsi tuff was deposited just before 1700 cal yr B.P., whereas the Cruzani Cocha tuff appears to be mid-Holocene in age and shows some chemical affinities to a Holocene tuff (202B) deposited between 4420 and 5460 cal yr B.P. in a urine-encased rodent midden in the Atacama Desert.     

Tree growth response to the 1913 eruption of Volcán de Fuego de Colima, Mexico

The impact of volcanic eruptions on forest ecosystems can be investigated using dendrochronological records. While long-range effects are usually mediated by decreased air temperatures, resulting in frost rings or reduced maximum latewood density, local effects include abrupt suppression of radial growth, occasionally followed by greater than normal growth rates. Annual rings in Mexican mountain pine (Pinus hartwegii Lindl.) on Nevado de Colima, at the western end of the Mexican Neovolcanic Belt, indicate extremely low growth in 1913 and 1914, following the January 1913 Plinian eruption of Volcán de Fuego, 7.7 km to the south. That event, which is listed among the largest explosive eruptions since A.D. 1500, produced ashflow deposits up to 40 m thick and blanketed our study area on Nevado de Colima with a tephra fallout 15–30 cm deep. Radial growth reduction in 1913–14 was ≥30% in 73% of the sampled trees. We geostatistically investigated the ecological impact of the eruption by mapping the decrease in xylem increment and found no evidence of a spatial structure in growth reduction. Little information has been available to date on forest species as biological archives of past environments in the North American tropics, yet this historical case study suggests that treeline tropical sites hold valuable records of prehistoric phenomena, including volcanic eruptions.     

Sensitivity of a hydraulic model to channel erosion uncertainty during extreme flooding

Recent research into flood modelling has primarily concentrated on the simulation of inundation flow without considering the influences of channel morphology. River channels are often represented by a simplified geometry that is implicitly assumed to remain unchanged during flood simulations. However, field evidence demonstrates that significant morphological changes can occur during floods to mobilize the boundary sediments. Despite this, the effect of channel morphology on model results has been largely unexplored. To address this issue, the impact of channel cross‐section geometry and channel long‐profile variability on flood dynamics is examined using an ensemble of a 1D–2D hydraulic model (LISFLOOD‐FP) of the ~1 : 2000 year recurrence interval floods in Cockermouth, UK, within an uncertainty framework. A series of simulated scenarios of channel erosional changes were constructed on the basis of a simple velocity‐based model of critical entrainment. A Monte‐Carlo simulation framework was used to quantify the effects of this channel morphology together with variations in the channel and floodplain roughness coefficients, grain size characteristics and critical shear stress on measures of flood inundation. The results showed that the bed elevation modifications generated by the simplistic equations reflected an approximation of the observed patterns of spatial erosion that enveloped observed erosion depths. The effect of uncertainty on channel long‐profile variability only affected the local flood dynamics and did not significantly affect the friction sensitivity and flood inundation mapping. The results imply that hydraulic models generally do not need to account for within event morphodynamic changes of the type and magnitude of event modelled, as these have a negligible impact that is smaller than other uncertainties, e.g. boundary conditions. Instead, morphodynamic change needs to happen over a series of events to become large enough to change the hydrodynamics of floods in supply limited gravel‐bed rivers such as the one used in this research. Copyright © 2014 John Wiley & Sons, Ltd.     

Partitioning of polycyclic aromatic hydrocarbons between water and particles compared to bioaccumulation in mussels: a harbour case

Water and particles from three sites located in Halifax Harbour, near and further away from combined municipal sewage effluents (CMSE) were analysed for parental and alkylated polycyclic aromatic hydrocarbons (par and alkPAH). Bioavailability of PAH was compared for inter-tidal mussels collected at the same sites in April and November. The PAH fingerprint determined over 9 sampling times covering a period of 19 months differed more between phases (water and particles) and seasons, than between sites. In the spring, more alkPAH associated with diesel and gasoline were detected in the soluble phase, along with more bioaccumulation of alkPAH in inter-tidal mussels. A broader number of parPAH were detected in mussels collected in the fall. The mean sum of dissolved alkPAH concentrations was higher in water at the site closer to raw CMSE than at the other two sites and particles of that site. However, lowest bioconcentration factors (BCF) were determined in mussels of this more contaminated site. Similar biota-particle accumulation factors (BPAF) were determined for parPAH in mussels from the three sites, all lower than the BCF of alkPAH. The study indicates that sewage treatment plants will reduce the amount of parPAH especially larger than fluoranthene and pyrene from being deposited in the harbour; that alk naphthalenes and fluorenes present in water will continue to be discharged; that the disturbance of sediments can make particle-bound PAH available to mussels.     

Distorted Froude‐scaled flume analysis of large woody debris

This paper presents the results of a movable‐boundary, distorted, Froude‐scaled hydraulic model based on Abiaca Creek, a sand‐bedded channel in northern Mississippi. The model was used to examine the geomorphic and hydraulic impact of simplified large woody debris (LWD) elements. The theory of physical scale models is discussed and the method used to construct the LWD test channel is developed. The channel model had bed and banks moulded from 0·8 mm sand, and flow conditions were just below the threshold of motion so that any sediment transport and channel adjustment were the result of the debris element. Dimensions and positions of LWD elements were determined using a debris jam classification model. Elements were attached to a dynamometer to measure element drag forces, and channel adjustment was determined through detailed topographic surveys. The fluid drag force on the elements decreased asymptotically over time as the channel boundary eroded around the elements due to locally increased boundary shear stress. Total time for geomorphic adjustment computed for the prototype channel at the Q₂ discharge (discharge occurring once every two years on average) was as short as 45 hours. The size, depth and position of scour holes, bank erosion and bars created by flow acceleration past the elements were found to be related to element length and position within the channel cross‐section. Morphologies created by each debris element in the model channel were comparable with similar jams observed in the prototype channel. Published in 2001 John Wiley & Sons, Ltd.     

Fishing safety policy and research

Fishing has been and is still one of the most dangerous of all human activities. In the field of fishing safety policy, it is acknowledged that the development of a working legal framework of reference is a vital prior condition for the implementation of measures aimed at its improving safety. However, the research work on fishing safety does not have at disposal records of a sufficient number of accidents and in most cases is not comparable from one country to another. Moreover, there is no work that focuses on a global view of fishing safety. The aim of the present work is to outline the state-of-the-art in fishing safety. To this end, aspects of fishing safety which are a major concern of institutions, organizations and researchers alike are analysed. Thus, several questions are addressed, such as: what institutional policy is given to the activity of the fishing sector to improve safety; what aspects and/or parameters are normally used to analyse fishing accidents; what is the usual spatial domain of this analysis; and what are the topics of the research carried out in fishing safety? The results of this analysis, among other aspects, identify eight specific lines of research followed in fishing safety and five which deal with aspects of safety at sea related to the fishing sector.     

Influence of the spatial resolution of satellite-derived vegetation parameters on the biogenic Volatile Organic Compounds (VOC) emission modeling

Vegetation is a natural source of Volatile Organic Compounds (VOC) that plays an important role in atmospheric chemistry. The main objective of the current study is to implement a model to quantify process-based VOC emissions from plants that focuses on the relationship between the sensitivity of VOC emission estimates to spatial resolution data, based on scientific knowledge and vegetation dynamics derived from satellite observations. The Normalized Difference Vegetation Index (NDVI) and Leaf Area Index (LAI) were elected to examine this issue using different resolutions of satellite-derived products: 22m from the DEIMOS-1 satellite, and 250m and 1000m provided by MODIS. The study is focused on an area of 80×80km² in Portugal for 2011. Detailed land cover and meteorological data are also included in the emission quantification algorithm. The primary outcomes were determined using a multi-scale analysis showing spatial and temporal variations in the vegetation parameters and modeling results. The results confirm that the emissions model is highly sensitive to the spatial resolution of the satellite-derived data, resulting in about a 30% difference in total isoprene emissions for the study area.     

System Reliability Analysis of an Offshore Jacket Platform

This study investigates strategies for solving the system reliability of large three-dimensional jacket structures.These structural systems normally fail as a result of a series of different components failures.The failure characteristics are investigated under various environmental conditions and direction combinations.Theβ-unzipping technique is adopted to determine critical failure components,and the entire system is simplified as a series-parallel system to approximately evaluate the structural system reliability.However,this approach needs excessive computational effort for searching failure components and failure paths.Based on a trained artificial neural network(ANN),which can be used to approximate the implicit limit-state function of a complicated structure,a new alternative procedure is proposed to improve the efficiency of the system reliability analysis method.The failure probability is calculated through Monte Carlo simulation(MCS)with Latin hypercube sampling(LHS).The features and applicability of the above procedure are discussed and compared using an example jacket platform located in Chengdao Oilfield,Bohai Sea,China.This study provides a reference for the evaluation of the system reliability of jacket structures.