Low calcification rates and calcium carbonate production in Porites panamensis at its northernmost geographic distribution

Porites panamensis is a hermatypic coral present in the eastern Pacific Ocean. Skeletal growth parameters have been reported, but studies of the relationship between annual calcification rates and environmental controls are scarce. In this study, we investigated three aspects of the annual calcification rates of P. panamensis: growth parameters among three P. panamensis populations; the sea surface temperature as a calcification rate control spanning a latitudinal gradient; and calcium carbonate production among three sites. Growth parameters varied among the sites due to the colony growth form. Massive colonies in the north showed a higher calcification rate than encrusting colonies in the south (mean: 1.22–0.49 g CaCO₃ · cm^?2 · yr^?1), where variations in calcification rates were related to growth rate (0.91–0.38 cm · yr^?1) rather than to skeletal density differences (overall mean ± SD, 1.31 ± 0.04 g CaCO₃ · cm^?3). Our results showed a positive linear relationship between annual calcification rates and sea surface temperatures within these P. panamensis populations. Differences were related to distinct oceanographic environments (within and at the entrance of the Gulf of California) with different sea surface temperature regimes and other chemical properties. Different populations calcified under different environmental conditions. Calcium carbonate production was dependent upon the calcification rate and coral cover and so carbonate production was higher in the north (coral cover 12%) than in the south (coral cover 3.5). Thus, the studied sites showed low calcium carbonate production (0.25–0.43 kg CaCO₃ · m^?2 · yr^?1). Our results showed reduced calcification rates, regional temperature regime control over calcification rates, different growth forms, low coral cover and low calcium carbonate production rates in P. panamensis.     

Petrographic and geochemical characterization of the granitic rocks of the Araguainha impact crater,Brazil

Petrographic and geochemical data obtained on the Araguainha impact crater (Goiás/Mato Grosso States, Brazil) indicate the existence of several molten products that originated during impact‐induced congruent melting of an alkali‐granite exposed in the inner part of the central uplift of the structure. Although previous studies have described these melts to some extent, there is no detailed discussion on the petrographic and geochemical variability in the granite and its impactogenic derivatives, and therefore, little is known about the geochemical behavior and mobility of trace elements during its fusion in the central part of the Araguainha crater. This paper demonstrates that the preserved granitoid exposed in the core of the structure is a magnesium‐rich granite, similar to postcollisional, A‐type granites, also found in terrains outside the Araguainha crater, in the Brasília orogenic belt. The molten products are texturally distinct and different from the original rock, but have very similar geochemical composition, making it difficult to separate these lithotypes based on concentrations of major and minor elements. This also applies for trace and rare earth elements (REE), thus indicating a high degree of homogenization during impact‐induced congruent melting under high pressure and postshock temperature conditions. Petrographic observations, along with geochemical data, indicate that melting occurs selectively, where some of the elements are transported with the melt. Simultaneously, there is an effective dissolution of the rock (granite), which leads to entrainment of the most resistant solid phases (intact or partially molten minerals) into the melt. Minerals more resistant to melting, such as quartz and oxides, contribute substantially to a chemical balance between the preserved granite and the fusion products generated during the meteoritic impact.     

Comparison of four meteorite penetration funnels in the Campo del Cielo crater field,Argentina

Abstract– More craters may be discovered in the future, but as it is currently known, the Campo del Cielo crater field is 18 km long by 4 km at its widest point. Such a distribution of craters suggests that the parent meteoroid entered and traversed the atmosphere at a very low angle relative to horizontal. The crater field contains at least 20 small craters produced by the larger fragments of the parent meteoroid. Four of these are explosion analog craters and the rest are penetration funnels. During four field seasons, we have constructed topographic and magnetic maps of four of the penetration funnels as found, and then dug trenches across them to learn their original structures and recover meteorites preserved within them. Structures of these penetration funnels indicate very low angles of impact, i.e., 9–16° relative to horizontal. This supports the idea that the parent meteoroid traversed the atmosphere at a low angle. Data given here for the four penetration funnels include projectile masses, lengths, widths, depths, and estimates of impact angles and azimuths. One of the penetration funnels described here (No. 6) can almost be classified as an explosion analog crater.     

Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.     

Goethite surface reactivity: III. Unifying arsenate adsorption behavior through a variable crystal face - Site density model

We developed a model that describes quantitatively the arsenate adsorption behavior for any goethite preparation as a function of pH and ionic strength, by using one basic surface arsenate stoichiometry, with two affinity constants. The model combines a face distribution-crystallographic site density model for goethite with tenets of the Triple Layer and CD-MUSIC surface complexation models, and is self-consistent with its adsorption behavior towards protons, electrolytes, and other ions investigated previously. Five different systems of published arsenate adsorption data were used to calibrate the model spanning a wide range of chemical conditions, which included adsorption isotherms at different pH values, and adsorption pH-edges at different As(V) loadings, both at different ionic strengths and background electrolytes. Four additional goethite-arsenate systems reported with limited characterization and adsorption data were accurately described by the model developed. The adsorption reaction proposed is:

     

Geochemistry and Sm–Nd isotopic systematics of Ediacaran–Ordovician,sedimentary and bimodal igneous rocks in the western Acatlán Complex,southern Mexico: Evidence for rifting on the southern margin of the Rheic Ocean

Ordovician igneous rocks in the western Acatlán Complex (Olinalá area) of southern Mexico include a bimodal igneous suite that intrudes quartzites and gneisses of the Zacango Unit, and all these rocks were polydeformed and metamorphosed in the amphibolite facies during the Devono-Carboniferous. The Ordovician igneous rocks consist of the penecontemporaneous amphibolites, megacrystic granitoids and leucogranite, the latter dated at ca. 464 Ma. Geochemical and Sm–Nd data indicate that the amphibolites have a differentiated tholeiitic signature, and that its mafic protoliths formed in an extensional setting transitional between within-plate and ocean floor. The amphibolites are variably contaminated by a Mesoproterozoic crustal source, inferred to be the Oaxacan basement exposed in the adjacent terrane. The most primitive samples have εNdt (t = 465 Ma) values significantly below that of the contemporary depleted mantle and were probably derived from the sub-continental lithospheric mantle. The megacrystic granites were most probably derived by partial melting of an arc crustal source (similar to the Oaxacan Complex) and triggered by the ascent of mafic magma from the lithospheric mantle. Sm–Nd isotopic signatures suggest that metasedimentary rocks from Zacango Unit were derived from adjacent Oaxacan Complex. Trace elements relationships (e.g. La/Th vs. Hf) and REE patterns suggest provenance in felsic-intermediate igneous rocks with a calc-alkaline signature. The Ordovician bimodal magmatism is inferred to have resulted from rifting on the southern flank of the Rheic Ocean and is an expression of a major rifting event that occurred along much of the northern Gondwanan margin in the Ordovician.     

The Response of Estuarine Macrobenthic Communities to Natural- and Human-Induced Changes: Dynamics and Ecological Quality

Anthropogenic activities are a disturbance factor of coastal systems and can be widely recognized as a major threat to the health of coastal systems. However, natural events cannot be disregarded from management issues because of their significant influence on the communities living in these areas. Based on long-term subtidal data from the Mondego Estuary (Portugal), the effects of natural events (e.g., floods and droughts) on macrobenthic communities were compared with the anthropogenic events. Sampling stations were grouped into characteristic zones (mouth, north arm, south arm) so the community dynamics of each of these estuarine areas could be followed over time. Environmental assessment was performed for stations using the Benthic Assessment Tool (BAT), and compared with the existing pressures. Human impacts persist over a number of years and gradually reduce ecosystem health, as discussed in the European Water Framework Directive. Paradoxically, natural events cause stronger impacts but are of a shorter duration, which allows for a faster recovery of macrobenthic communities. The study showed that caution should be taken when developing and implementing water policies so as not to disregard the importance of the different events (natural and human-caused) on the ecosystem health (e.g., community degradation and water quality and ecological quality status assessment).     

Uncovering spatiotemporal micromobility patterns through the lens of space–time cubes and GIS tools

Journal of Geographical Systems - In the past ten years, cities have experienced a burst of micromobility services as they offer a flexible transport option that allows users to cover short trips...     

Influence of the spatial resolution of satellite-derived vegetation parameters on the biogenic Volatile Organic Compounds (VOC) emission modeling

Vegetation is a natural source of Volatile Organic Compounds (VOC) that plays an important role in atmospheric chemistry. The main objective of the current study is to implement a model to quantify process-based VOC emissions from plants that focuses on the relationship between the sensitivity of VOC emission estimates to spatial resolution data, based on scientific knowledge and vegetation dynamics derived from satellite observations. The Normalized Difference Vegetation Index (NDVI) and Leaf Area Index (LAI) were elected to examine this issue using different resolutions of satellite-derived products: 22m from the DEIMOS-1 satellite, and 250m and 1000m provided by MODIS. The study is focused on an area of 80×80km² in Portugal for 2011. Detailed land cover and meteorological data are also included in the emission quantification algorithm. The primary outcomes were determined using a multi-scale analysis showing spatial and temporal variations in the vegetation parameters and modeling results. The results confirm that the emissions model is highly sensitive to the spatial resolution of the satellite-derived data, resulting in about a 30% difference in total isoprene emissions for the study area.