Crustal thickness and adakite occurrence in the Philippines: Is there a relationship?

Adakites are increasingly being recognized worldwide in a variety of tectonic settings. Models on the formation of this geochemically distinct class of volcanic rocks have evolved from partial melting of subducted young, hot oceanic slabs to magmatism resulting from oblique subduction, low‐angle or flat subduction, or even slab‐tearing. Some workers have also pointed to the partial melting of thickened crust to explain the generation of adakitic melts. Rare earth element ratios from adakites and adakitic rocks in the Philippines were used in this study to obtain approximations of the levels where they were generated. These were tied to available geophysical data that defines the crustal thickness of the areas where the samples were collected. High Sm/Yb and La/Yb ratios denote the involvement of amphiboles, and in some cases garnet, in the generation of adakites and adakitic magmas. The presence of amphibole and garnet as residual phases suggests high pressures corresponding to thicker crust (～30 to 45 km). Adakites and adakitic rocks formed through processes other than melting of subducted young oceanic crust would need ≥30 km to account for the heavy rare earth element signatures. If mantle fractionation is not the process involved, crustal thickness is critical to generate adakites and adakitic rocks.     

Buruanga peninsula and Antique Range: Two contrasting terranes in Northwest Panay,Philippines featuring an arc–continent collision zone

Alternating chert–clastic sequences juxtaposed with limestone blocks, which are units typical of accretionary complexes, constitute the Buruanga peninsula. New lithostratigraphic units are proposed in this study: the Unidos Formation (Jurassic chert sequence), the Saboncogon Formation (Jurassic siliceous mudstone–terrigenous mudstone and quartz‐rich sandstone), the Gibon Formation (Jurassic(?) bedded pelagic limestone), the Libertad Metamorphics (Jurassic–Cretaceous slate, phyllite, and schist) and the Buruanga Formation (Pliocene–Pleistocene reefal limestone). The first three sedimentary sequences in the Buruanga peninsula show close affinity with the ocean plate stratigraphy of the North Palawan terrane in Busuanga Island: Lower–Middle Jurassic chert sequences overlain by Middle–Upper Jurassic clastics, juxtaposed with pelagic limestone. Moreover, the JR5–JR6 (Callovian to Oxfordian) siliceous mudstone of the Saboncogon Formation in the Buruanga peninsula correlates with the JR5–JR6 siliceous mudstone of the Guinlo Formation in the Middle Busuanga Belt. These findings suggest that the Buruanga peninsula may be part of the North Palawan terrane. The rocks of the Buruanga peninsula completely differ from the Middle Miocene basaltic to andesitic pyroclastic and lava flow deposits with reefal limestone and arkosic sandstone of the Antique Range. Thus, the previously suggested boundary between the Palawan microcontinental block and the Philippine Mobile Belt in the central Philippines, which is the suture zone between the Buruanga peninsula and the Antique Range, is confirmed. This boundary is similarly considered as the collision zone between them.     

Influence of ambient flow around the horseshoe crabLimulus polyphemus on the distribution and orientation of selected epizoans

Cumulatively scored distributions of the slipper shell gastropodCrepidula sp., the sand-building polychaete wormSabellaria vulgaris, the calcareous meandering tubed polychaeteFilograna implexa, the barnacleSemibalanaus balanoides, and the lacy bryozoanSchizoporella sp. were mapped on a cm-square gridded silhouette of the prosoma, opisthosoma, and movable spines, and telson of the horseshoe crabLimulus polyphemus stranded on Reeds Beach, Cape May County, New Jersey in the Delaware Bay. Statistically tested and contoured epizoan frequencies for 81 males and 59 females revealed that slipper shells and agglutinated worm tubes are concentrated near the movable spines on the opisthosoma, but rare on recessed chilarial or opercular pleurites, the prosoma, and telson. Barnacles are disproportionately concentrated in entapophyseal pits on the opisthosoma and in the longitudinal furrows flanking the cardiac lobe of the prosoma. Bryozoans are concentrated near movable marginal spines of the opisthosoma, but also found on all areas of the prosoma, opisthosoma, and hinge area in between, as well as the telson. Different morphologic sites for their respective modal concentrations may result from competitive exclusion of bryozoans by barnacles. Genal angles have lower statistically predicted frequencies of bryozoans, barnacles, and sand worm tubes. Apertural openings of calcareous tubes are predominantly posteriorly oriented whereas the anterior magin of slipper shells are randomly oriented on the opisthosoma. Eschewing differential mortality, nonrandom distributions indicate possible: rugophilic (groove-seeking) larval settlement behavior for barnacles that preferred the recessed hinge area, longitudinal grooves, and pits; rheophilic (current-seeking) larval settlement behavior for the gastropods and tube-building polychaetes that filter feed in the eddies generated near the movable spines of the downcurrent-sloping opisthosoma; and geotactic (gravity-influenced) larval settlement or post-settlement migration to the vaulted crest (cardiac lobe). Deficiencies of protruding epizoic skeletons on the genal angles and anterior margin of the host may be due to removal by abrasion as the horseshoe crab plowed through sediment or shearing of the epizoans from the carapace substratum in strong currents or waves.     

Adakitic lavas in the Central Luzon back‐arc region,Philippines: lower crust partial melting products?

Abstract Volcanism in the back-arc side region of Central Luzon, Philippines, with respect to the Manila Trench is characterized by fewer and smaller volume volcanic centers compared to the adjacent forearc side-main volcanic arc igneous rocks. The back-arc side volcanic rocks which include basalts, basaltic andesites, andesites and dacites also contain more hydrous minerals (ie, hornblende and biotite). Adakite-like geochemical characteristics of these back-arc lavas, including elevated Sr, depleted heavy rare earth elements and high Sr/Y ratios, are unlikely to have formed by slab melting, be related to incipient subduction, slab window magmatism or plagioclase accumulation. Field and geochemical evidence show that these adakitic lavas were most probably formed by the partial melting of a garnet-bearing amphibolitic lower crust. Adakitic lavas are not necessarily arc–trench gap region slab melts.     

Gravity variations along the Southeast Bohol Ophiolite Complex (SEBOC), Central Philippines: Implications on Ophiolite Emplacement

Abstract The basement complex of Bohol Island consists of the Southeast Bohol Ophiolite Complex (SEBOC), Cansiwang Melange and Alicia Schist. The SEBOC is a complete, but dismembered ophiolite with outcrops generally trending northeast– southwest and dipping north-west. The harzburgite units of the SEBOC are almost always observed to be thrusted onto the Cansiwang Melange, which in turn is thrusted onto the Alicia Schist. Bouguer gravity values on Bohol range from about +60 mGal in the west to +120 mGal in the east, in the region to the north-east of the SEBOC outcrops. Based on the present distribution of the SEBOC units and their thrust fault relationship with the Cansiwang Melange and Alicia Schist, it is proposed that the SEBOC was emplaced by onramping towards the south-eastward direction. However, the orientation of the Bouguer highs suggests that the thrusting direction of the ophiolite units is towards the south-west and not towards the south-east.     

Comparison of laboratory testing protocols to field observations of the weathering of sulfide-bearing mine tailings

A laboratory weathering study using a humidity cell procedure was conducted on two sulfide-bearing tailing samples from a metallurgical site in Ontario (Canada). The test was accompanied by microbiological studies to enumerate the major groups of sulfur-oxidizing bacteria and determine their potential role at different stages during the oxidation process. To evaluate the utility of this method, results were compared with those of previous laboratory and field studies on the same materials. The mineralogy of the laboratory samples differs only by the addition of a small amount of hydronium-bearing natrojarosite [(Na,H₃O)Fe₃(SO₄)₂(OH)₆] to one sample. The progress of sulfide oxidation and the rates of solute release were determined to evaluate the extent of mineral dissolution. These processes were influenced strongly by the capacity of the material to generate acidity, which was enhanced by the presence of hydronium-bearing natrojarosite. Acid-neutralization processes occurring during the laboratory tests were affected by reaction kinetics, consistent with field observations. In particular, the extent of carbonate-mineral dissolution appears to be different in the laboratory than in the field, where more prolonged rock–water interaction allowed more complete chemical equilibration. As a consequence, the capacity of this test procedure to predict weathering reactions in mine tailings is limited by its inability to reproduce the weathering sequence observed in the field. The results of the microbiological study showed that distinct groups of sulfur-oxidizing bacteria operate at different stages of the oxidative process, as was observed in field studies where tailings oxidation occurred under natural conditions, suggesting that microbiological tests performed for laboratory studies are reflective of field conditions.     

Response of the bacterial community to in situ bioremediation of organic-rich sediments

A field trial experiment was carried out to assess the potential of bioremediation for mobilisation of carbon in organic-rich sediments. Both bioaugmentation (bio-fixed microorganisms) and biostimulation (oxygen release compounds--ORC) protocols have been tested and the response of the bacterial community has been described to assess the baseline for bioremediation potential. Multifactorial ANOVA revealed that bioaugmentation protocol had an effect in stimulate mobilisation processes and significantly enhanced extra-cellular enzymatic activity rates. In contrast biostimulation treatment did not have an effect on mobilisation rates but contributed to enhance bacterial efficiency through a maximization of the bacterial production:enzymatic activity ratio. Average calculation of net mobilised carbon showed that 23% increase of mobilised pool was accounted for bioaugmentation in summer. Although biostimulation accounted for a smaller increase in mobilised carbon (<10%), the use of ORC resulted in an increased mineralisation and net carbon loss via respiration. Based on our results, a conceptual model for application of bioremediation to face the problem of sediment eutrophication is discussed.     

A local landscape in transition between production and consumption goals: can new management arrangements preserve the local landscape character?

Around towns in the Alentejo region, the landscape is dominated by a characteristic agricultural small-scale mosaic. These areas are central in the region landscape character – even if the large-scale latifundia landscape of the extensive silvo-pastoral systems is most commonly associated with the region. In the last two decades, these parcels became extremely attractive for new comers, who settle in the rural context as residents, week-end visitors, being often also lifestyle farmers. The paper presents a case study landscape, in Montemor-o-Novo, a small town 100 km from Lisbon, highly subject to the pressure for consumption uses, by urban users. The study shows that the new owners, even if they have settled in the area due to the tranquility and social bindings of the rural, end up doing farming, with new or reshaped production objectives, markets and models, but at the same time maintaining the traditional farm systems. Thus, the landscape character is maintained, so far. Nevertheless, the role of these neo-rurals and lifestyle farmers is still an unseen role, both by the agriculture and the planning sectors. And thus the question is, whether the combination of actors and land management drivers will continue maintaining the landscape in the future.     

Ficopomatus'Reefs' in the Po River Delta (Northern Adriatic): Their Constructional Dynamics, Biology, and Influences on the Brackish-water Biota

Abstract. The serpulid polychaete Ficopomatus enigmaticus (F auvel , 1923) builds huge aggregates in the "Sacca del Canarin", a brackish inlet of the Po River Delta (Italy). Distribution, structure and development of these 'reefs'. together with their associated biota, were studied by field observations and settlement panels from 1977 to 1979. Some aspects of the serpulid biology (settlement periods, tube growth, life strategy) were also taken into account. Ficopomatus reefs influence in many ways the brackish-water ecosystem: they form the main hard substrate; are major sediment source; help in regulating the trophic status of the lagoon; and act as refuge for many invertebrate species.