Trace metal assessment in soils in a small city and its rural surroundings,Pensacola, FL,USA

This study assesses the origin and pollution of trace metals in surface soils in a region with contrasting land uses (urban vs. rural). Principal component analysis (PCA) reveals that Cr and Ni are predominantly of geogenic origin. These two trace metals are also the only ones with statistically significant correlations with soil particle size and organic matter content. Copper, Pb and Zn, and possibly Hg, are of anthropogenic origin, but their concentrations rarely reach levels described as strongly polluted by pollution indexes. The concentrations of these anthropogenic trace metals are statistically not different in urban and rural areas, except for Pb that is higher in the urban area. This general lack of a difference between the two land uses indicates that the influence of this small urban area on trace metal concentrations in soils is minor. Lead and Zn have the most, but still a modest number, of strongly polluted sites, mainly in an industrial part of the city. GIS analysis shows that, based on the pollution load index (PLI), overall concentrations of trace metals also reach their highest levels in that industrial area. These observations indicate that the influence of industry on trace metal pollution in soil exceeds that of other urban activities in the region. Local background concentrations were found to be very different from general crustal background concentrations. This demonstrates the importance of the careful selection of a background type in studies like this.     

Geochemical correlations between effusive and explosive silicic volcanics in the Saraykent region (Yozgat), central Anatolia,Turkey

Two main volcanic events are distinguished between Saraykent and Akçakışla in the Yozgat province of central Anatolia: (1) early Late Cretaceous–Palaeocene effusive activity, that produced a sequence of intermediate to felsic ‘basal lavas’; and (2) marginally later Palaeocene explosive activity that formed a series of covering ignimbrite flows. Due to their close temporal and spatial relation, geochemical comparisons were made between the silicic members of the lavas and ignimbrites, to identify chemical groups and their relative petrogenesis. The basal lavas range from calc‐alkaline basaltic andesites to dominant rhyolites. Based on trace element correlations three main geochemical groups were identified: the Akçakışla rhyolites (present as domes); Akçakışla rhyodacites‐dacites (lava flows); and Ozan‐Saraykent rhyolites (lava flows). Large‐ion lithophile elements have been mobile in all the groups, but mainly in the Akçakışla rhyolites. Rare earth element (REE) patterns show marked similarity between the Ozan and Saraykent basal lavas. The Akçakışla dome rhyolites are more fractionated with lower La_N/Yb_N ratios (c.10), whereas the Akçakışla basal lavas have much higher La_N/Yb_N ratios (c.30). The chemical coherence and petrographic similarities between the Saraykent and Ozan lavas suggest a single suite related via fractionation. Three geochemical groups were also established for the ignimbrites: Saraykent ignimbrite; Bağlıca ignimbrite‐Toklu‐Kızıldağ crystal tuffs; and Keklikpınar ignimbrite. The ignimbrites, like the basal lavas, display a pronounced depletion in Ba on ORG‐normalized plots. Relative to the basal lavas, chondrite‐normalized patterns for the ignimbrites are different in displaying negative Eu anomalies that indicate feldspar fractionation. The lack of geochemical overlap or coherence between any of the lava and ignimbrite groups suggests that they represent distinct eruptive events and are not related in any simple volcanic development and cogenetic sense. Two geochemical features are common to all the volcanic rock groups: (1) the presence of a Nb‐Ta anomaly, which is generally accepted as a crustal signature; and (2) the relatively low Y abundances which appear characteristic for the region as a whole. These fundamental features of the local silicic volcanism largely reflect source composition and effects. Copyright © 2002 John Wiley & Sons, Ltd.     

The stability of a remediated bed in Hamilton Harbour,Lake Ontario,Canada

ABSTRACT In situ measurements of lakebed sediment erodibility were made on three sites in Hamilton Harbour, Lake Ontario, using the benthic flume Sea Carousel. Three methods of estimating the surface erosion threshold (τ_c(0)) from a Carousel time series were evaluated: the first method fits measures of bed strength to eroded depth (the failure envelope) and evaluates threshold as the surface intercept; the second method regresses mean erosion rate (E_m) with bed shear stress and solves for the floc erosion rate (E_f) to derive the threshold for E_m = E_f = 1 × 10^?5 kg m^?2 s^?1; the third method extrapolates a regression of suspended sediment concentration (S) and fluid transmitted bed shear stress (τ₀) to ambient concentrations. The first field site was undisturbed (C) and acted as a control; the second (W) was disturbed through ploughing and water injection as part of lakebed treatment, whereas the third site (OIP) was disturbed and injected with an oxidant used for remediation of contaminated sediment. The main objectives of this study were: (1) to evaluate the three different methods of deriving erosion threshold; (2) to compare the physical behaviour of lacustrine sediments with their marine estuarine counterparts; and (3) to examine the effects of ploughing and chemical treatment of contaminated sediment on bed stability. Five deployments of Sea Carousel were carried out at the control site. Mean erosion thresholds for the three methods were: τ_c(0) = 0·5 (±0·06), 0·27 (±0·01) and 0·34 (±0·03) Pa respectively. Method 1 overpredicted bed strength as it was insensitive to effects in the surface 1–2 mm, and the fit of the failure envelope was also highly subjective. Method 2 exhibited a wide scatter in the data (low correlation coefficients), and definition of the baseline erosion rate (E_f) is largely arbitrary in the literature. Method 3 yielded stable (high correlation coefficients), reproducible and objective results and is thus recommended for evaluation of the erosion threshold. The results of this method correlated well with sediment bulk density and followed the same trend as marine counterparts from widely varying sites. Mass settling rates, expressed as a decay constant, k, of S(t), were strongly related to the maximum turbidity at the onset of settling (S_max) and were also in continuity with marine counterparts. Thus, it appears that differences in salinity had little effect on mass settling rates in the examples presented, and that biological activity dominated any effects normally attributable to changes in salinity. Bedload transport of eroded aggregates (2–4 mm in diameter) took place by rolling below a mean tangential flow velocity (U_y) of 0·32 ms^?1 and by saltation at higher velocities. Mass transport as bedload was a maximum at U_y = 0·4 ms^?1, although bedload never exceeded 1% of the suspended load. The proportion of material moving as bedload was greatest at the onset of erosion but decreased as flow competence increased. Given the low bulk density and strength of the lakebed sediment, the presence of a bedload component is notable. Bedload transport over eroding cohesive substrates should be greater in estuaries, where both sediment density and strength are usually higher. Significant differences between the ploughed and control sites were apparent in both the erosion rate and the friction coefficient (φ), and suggest that bed recovery after disruption is rapid (< 24 h). τ_c(0) increased linearly with time after ploughing and recovered to the control mean value within 3 days. The friction coefficient was reduced to zero by ploughing (diagnostic of fluidization), but increased linearly with time, regaining control values within 6 days. No long‐term reduction in bed strength due to remediation was apparent.     

Direct luminescence chronology of the Epipaleolithic Kebaran site of Nahal Hadera V,Israel

We report direct luminescence ages for the culture‐bearing sediments of the Kebaran site of Nahal Hadera V (NHV) in the coastal plain of Israel. Although the site contains, in addition to rich lithic deposits, plentiful mammalian bone, it has proved to be undatable using radiocarbon dating, in spite of the fact that the cultural context places the time of occupation well within the range of radiocarbon dating. In contrast, luminescence dating of the site sediments proved successful. Luminescence ages were determined using the single aliquot additive‐dose (SAA) method, applied to sand‐sized quartz extracts to determine past equivalent doses (D_e). Dose rates (R) were calculated using thick source alpha counting for the uranium (U) and thorium (Th) concentrations and x‐ray fluorescence analysis for the potassium (K₂0) concentration. Of the five samples collected at the site, four represent cultural and subcultural deposits and the fifth represents the geological substrate for the archaeological deposit, a quartz‐rich, carbonate‐cemented dune sand known as aeolianite or kurkar. The luminescence age of the kurkar is 42.7 ± 6.3 ka. Human occupation of the site occurred between 21.3 ka and 14.0 ka ago, during the Last Glacial Maximum. © 2003 Wiley Periodicals, Inc.     

Petrogenesis of the Greenhills Complex,Southland, New Zealand: magmatic differentiation and cumulate formation at the roots of a Permian island-arc volcano

A Permian (~265 Ma) intrusive complex which formed as a magmatic feeder reservoir to an immature island-arc volcano is fortuitously exposed in southern New Zealand. Known as the Greenhills Complex, this intrusion was emplaced at shallow crustal levels and consists of two layered bodies which were later intruded by a variety of dykes. Cumulates, which include dunite, olivine clinopyroxenite, olivine gabbro, and hornblende gabbro-norite, are related products of parent-magma fractionation. Both primary (magmatic) and secondary platinum-group minerals occur within dunite at one locality. Using the composition of cumulus minerals, mafic dykes and melt inclusions, we have determined that the parent magmas of the complex were hydrous, low-K island-arc tholeiites of ankaramitic affinities. Progressive magmatic differentiation of this parent magma generated fractionated melt of high-alumina basalt composition which is now preserved only as dykes which cut the Complex. Field evidence and cumulus mineral profiles reveal that the magma chambers experienced turbulent magmatic conditions during cumulate-rock formation. Recharge of the chambers by primitive magma is likely to have coincided with eruption of residual melt at the surface. Similar processes are inferred to account for volcanic-rock compositions in other parts of this arc terrane and in modern island-arc systems.     

Late Ordovician climbing‐dune cross‐stratification: a signature of outburst floods in proglacial outwash environments?

Climbing dune‐scale cross‐statification is described from Late Ordovician paraglacial successions of the Murzuq Basin (SW Libya). This depositional facies is comprised of medium‐grained to coarse‐grained sandstones that typically involve 0·3 to 1 m high, 3 to 5 m in wavelength, asymmetrical laminations. Most often stoss‐depositional structures have been generated, with preservation of the topographies of formative bedforms. Climbing‐dune cross‐stratification related to the migration of lower‐flow regime dune trains is thus identified. Related architecture and facies sequences are described from two case studies: (i) erosion‐based sandstone sheets; and (ii) a deeply incised channel. The former characterized the distal outwash plain and the fluvial/subaqueous transition of related deltaic wedges, while the latter formed in an ice‐proximal segment of the outwash plain. In erosion‐based sand sheets, climbing‐dune cross‐stratification results from unconfined mouth‐bar deposition related to expanding, sediment‐laden flows entering a water body. Within incised channels, climbing‐dune cross‐stratification formed over eddy‐related side bars reflecting deposition under recirculating flow conditions generated at channel bends. Associated facies sequences record glacier outburst floods that occurred during early stages of deglaciation and were temporally and spatially linked with subglacial drainage events involving tunnel valleys. The primary control on the formation of climbing‐dune cross‐stratification is a combination between high‐magnitude flows and sediment supply limitations, which lead to the generation of sediment‐charged stream flows characterized by a significant, relatively coarse‐grained, sand‐sized suspension‐load concentration, with a virtual absence of very coarse to gravelly bedload. The high rate of coarse‐grained sand fallout in sediment‐laden flows following flow expansion throughout mouth bars or in eddy‐related side bars resulted in high rates of transfer of sands from suspension to the bed, net deposition on bedform stoss‐sides and generation of widespread climbing‐dune cross‐stratification. The later structure has no equivalent in the glacial record, either in the ancient or in the Quaternary literature, but analogues are recognized in some flood‐dominated depositional systems of foreland basins.     

Diagenetic formation of gypsum and dolomite in a cold‐water coral mound in the Porcupine Seabight,off Ireland

Authigenic gypsum was found in a gravity core, retrieved from the top of Mound Perseverance, a giant cold‐water coral mound in the Porcupine Basin, off Ireland. The occurrence of gypsum in such an environment is intriguing, because gypsum, a classic evaporitic mineral, is undersaturated with respect to sea water. Sedimentological, petrographic and isotopic evidence point to diagenetic formation of the gypsum, tied to oxidation of sedimentary sulphide minerals (i.e. pyrite). This oxidation is attributed to a phase of increased bottom currents which caused erosion and enhanced inflow of oxidizing fluids into the mound sediments. The oxidation of pyrite produced acidity, causing carbonate dissolution and subsequently leading to pore‐water oversaturation with respect to gypsum and dolomite. Calculations based on the isotopic compositions of gypsum and pyrite reveal that between 21·6% and 28·6% of the sulphate incorporated into the gypsum derived from pyrite oxidation. The dissolution of carbonate increased the porosity in the affected sediment layer but promoted lithification of the sediments at the sediment‐water interface. Thus, authigenic gypsum can serve as a signature for diagenetic oxidation events in carbonate‐rich sediments. These observations demonstrate that fluid flow, steered by environmental factors, has an important effect on the diagenesis of coral mounds.     

Primitive Ordovician (Floian) echinoderms from Sandu,Guizhou Province,South China,and their significance

Pelmatozoans diversified primarily during the Middle and Late Ordovician Period, with Early Ordovician records being much more limited, resulting in many gaps in our knowledge of the early stages of their diversification. Dissociated pelmatozoan ossicles have been found abundantly in one section in the Tonggao Formation (Tetragraptus approximatus Biozone, Floian, Early Ordovician). Most of the ossicles are thecal plates and stem ossicles from hemicosmitoid and glyptocystitoid cystoids. Thecal plates of ‘Cheirocrinus’ sp., Polycosmites sp., and other plates of uncertain affinity are described. A different ossicle type, Pentagonopentagonalis (col.), may represent crinoid remains; this would be one of the earliest occurrences of the class. The thecal ossicles and columnals are all considered, as both sets of data are desirable to determine the most complete estimate of generic diversity. The echinoderm ossicles may have been transported in from shallower water palaeoenvironments and clusters of ossicles may represent coprolites or regurgitates. Estimates of Early Ordovician palaeogeography that place this site at 30°S or near the palaeoequator are supported by the physiological requirements of the primitive echinoderms described herein. Copyright © 2014 John Wiley & Sons, Ltd.     

Relict silicate inclusions in extraterrestrial chromite and their use in the classification of fossil chondritic material

Chromite is the only common meteoritic mineral surviving long-term exposure on Earth, however, the present study of relict chromite from numerous Ordovician (470 Ma) fossil meteorites and micrometeorites from Sweden, reveals that when encapsulated in chromite, other minerals can survive for hundreds of millions of years maintaining their primary composition. The most common minerals identified, in the form of small (<1-10 μm) anhedral inclusions, are olivine and pyroxene. In addition, sporadic merrillite and plagioclase were found.Analyses of recent meteorites, holding both inclusions in chromite and corresponding matrix minerals, show that for olivine and pyroxene inclusions, sub-solidus re-equilibration between inclusion and host chromite during entrapment has led to an increase in chromium in the former. In the case of olivine, the re-equilibration has also affected the fayalite (Fa) content, lowering it with an average of 14% in inclusions. For Ca-poor pyroxene the ferrosilite (Fs) content is more or less identical in inclusions and matrix. By these studies an analogue to the commonly applied classification system for ordinary chondritic matrix, based on Fa in olivine and Fs in Ca-poor pyroxene, can be established also for inclusions in chromite. All olivine and Ca-poor pyroxene inclusions (>1.5 μm) in chromite from the Ordovician fossil chondritic material plot within the L-chondrite field, which is in accordance with previous classifications. The concordance in classification together with the fact that inclusions are relatively common makes them an accurate and useful tool in the classification of extraterrestrial material that lacks matrix silicates, such as fossil meteorites and sediment-dispersed chromite grains originating primarily from decomposed micrometeorites but also from larger impacts.