New Olivine Reference Material for In Situ Microanalysis

A new olivine reference material – MongOL Sh11‐2 – for in situ analysis has been prepared from the central portion of a large (20 × 20 × 10 cm) mantle peridotite xenolith from a ~ 0.5 My old basaltic breccia at Shavaryn‐Tsaram, Tariat region, central Mongolia. The xenolith is a fertile mantle lherzolite with minimal signs of alteration. Approximately 10 g of 0.5–2 mm gem quality olivine fragments were separated under binocular microscope and analysed by EPMA, LA‐ICP‐MS, SIMS and bulk analytical methods (ID‐ICP‐MS for Mg and Fe, XRF, ICP‐MS) for major, minor and trace elements at six institutions world‐wide. The results show that the olivine fragments are sufficiently homogeneous with respect to major (Mg, Fe, Si), minor and trace elements. Significant inhomogeneity was revealed only for phosphorus (homogeneity index of 12.4), whereas Li, Na, Al, Sc, Ti and Cr show minor inhomogeneity (homogeneity index of 1–2). The presence of some mineral and fluid‐melt micro‐inclusions may be responsible for the inconsistency in mass fractions obtained by in situ and bulk analytical methods for Al, Cu, Sr, Zr, Ga, Dy and Ho. Here we report reference and information values for twenty‐seven major, minor and trace elements.     

Mechanics of normal fault networks subject to slip-weakening friction

We seek to understand how the stress interactions and the slip-weakening process combine within a non-coplanar, normal fault network to allow a slip instability to develop, and shape the final slip distribution on the system. In a first part, we perform a non-linear spectral analysis to investigate the conditions of stability and the process of slip initiation in an antiplane non-coplanar fault system subject to a slip-dependent friction law. That numerical model allows determining the zones that are able to slip within a fault network, as well as the location of the stress singularities. The resulting slip profiles on the faults show only a few different shapes, some of them with long, linear sections. This leads to formulate a general classification of slip profiles that can be used to infer the degree of fault interaction within any non-coplanar system. In a second part of work, we use our modelling to try reproducing the cumulative slip profiles measured on three real normal interacting faults forming a large-scale en echelon system. For that, we assume that cumulative slip profiles can be compared to the first static modal solution of our conceptual model. We succeed reproducing the profiles quite well using a variable weakening along the faults. Overall, the weakening rate decreases in the direction of propagation of the fault system. Yet, modelling the slip along the propagating, isolated termination segment of the system requires an unlikely distribution of weakening. This suggests that factors not considered in our analysis may contribute to slip profile shaping on isolated, propagating faults.     

Monitoring biomarkers in fish (Lepidorhombus boscii and Callionymus lyra) from the northern Iberian shelf after the Prestige oil spill

Hepatic biomarker responses were measured in two demersal fish species (Lepidorhombus boscii and Callionymus lyra) from the northern Iberian shelf associated with the massive Prestige oil spill (POS), five months after the accident. The biomarkers selected were 7-ethoxyresorufin-O-deethylase (EROD), glutathione-S-transferase (GST), glutathione reductase (GR), catalase (CAT), and DNA integrity. Interspecies differences and spatial variations in biomarker responses were observed along the shelf. GST, GR and CAT activities were significantly elevated in L. boscii in the most oil impacted area (Finisterre) and positively correlated (p<0.05) with POS tar aggregate densities. The lack of previous data from the area together with the existence of chronic background pollution of the shelf implies that the observed biomarker responses cannot be solely attributed to the petroleum hydrocarbon components of the spilled oil. This first biological effect assessment showed that L. boscii is a potentially suitable target species to be used in future biomonitoring programmes along the northern Iberian shelf.