Isotopic and textural discrimination between hypogene,ancient supergene,and modern sulfates at the Questa mine,New Mexico

Chemical and mineralogical changes due to pyrite weathering are of interest with respect to understanding long-term physical stability of mine rock piles at the Questa mine, New Mexico. The ability to discriminate between ancient and modern processes is important for establishing the extent of modern weathering within the piles. Initial inventories of sulfur minerals and representative isotope compositions in rocks from orebodies, the hydrothermal alteration zones associated with orebodies, hydrothermal alteration scars, and mine rock piles were determined. Ore body sulfides have δ³⁴S_CDT of 0 ± 4‰, typical for sulfides formed by magmatic processes in stockwork Mo systems. Pyrite from alteration scars has a wide range of δ³⁴S values from 0.0‰ to −13.6‰. Sulfate from the ore body has markedly positive δ³⁴S (5–10‰) accompanied by positive δ¹⁸OSO₄${\delta }^{18}{\text{O}}_{{\text{SO}}_4}$ values (6–15‰) reflecting equilibrium formation from magmatic fluids. Sulfates from alteration scars have δ³⁴S values over a broad range, similar to alteration scar pyrites, from −10.6‰ to 0‰ and δ¹⁸OSO₄${\delta }^{18}{\text{O}}_{{\text{SO}}_4}$ of 0 ± 3‰. Sulfates with fine grained, delicate, and euhedral mineral habits suggesting recent formation within the mine rock piles, have δ³⁴S values similar to orebody pyrite and alteration scars but more negative δ¹⁸OSO₄${\delta }^{18}{\text{O}}_{{\text{SO}}_4}$ values (−3‰ to −10‰). Sulfates from all three sources occur in these piles, and their stable isotope values have proven useful in differentiating them and their environments of formation (i.e., hypogene, ancient supergene, and recent weathering). Correlating the isotopic compositions with textures allows petrographic assessment for the origins of sulfate minerals in the rock piles, but this must be applied with caution because some sulfate mineral recycling has occurred.     

Safe separation distance score: a new metric for evaluating wildland firefighter safety zones using lidar

Safety zones are areas where firefighters can retreat to in order to avoid bodily harm when threatened by burnover or entrapment from wildland fire. At present, safety zones are primarily designated by firefighting personnel as part of daily fire management activities. Though critical to safety zone assessment, the effectiveness of this approach is inherently limited by the individual firefighter’s or crew boss’s ability to accurately and consistently interpret vegetation conditions, topography, and spatial characteristics of potential safety zones (e.g. area and geometry of a forest clearing). In order to facilitate the safety zone identification and characterization process, this study introduces a new metric for safety zone evaluation: the Safe Separation Distance Score (SSDS). The SSDS is a numerical representation of the relative suitability of a given area as a safety zone according to its size, geometry, and surrounding vegetation height. This paper describes an algorithm for calculating pixel-based and polygon-based SSDS from lidar data. SSDS is calculated for every potential safety zone within a lidar dataset covering Tahoe National Forest, California, USA. A total of 2367 potential safety zones with an SSDS ≥1 were mapped, representing areas that are suitable for fires burning in low wind and low slope conditions. The highest SSDS calculated within the study area was 9.65, a score that represents suitability in the highest wind-steepest slope conditions. Potential safety zones were clustered in space, with areas in the northern and eastern portions of the National Forest containing an abundance of safety zones while areas to the south and west were completely devoid of them. SSDS can be calculated for potential safety zones in advance of firefighting, and can allow firefighters to carefully compare and select safety zones based on their location, terrain, and wind conditions. This technique shows promise as a standard method for objectively identifying and ranking safety zones on a spatial basis.     

Sharks caught in the KwaZulu-Natal bather protection programme,South Africa. 13. The tiger shark Galeocerdo cuvier

The current study provides long-term catch rate and biological data for tiger sharks Galeocerdo cuvier caught in the KwaZulu-Natal bather protection programme. Between 1978 and 2014, 1 760 G. cuvier were caught in nets and between 2007 and 2014, 108 G. cuvier were caught on drumlines. Standardised catch rates increased significantly over time (p < 0.001) for both small (≤180 cm precaudal length, PCL) and large sharks (>180 cm). There was also a significant temporal increase in the mean size of sharks across gear types (p < 0.001). A quasi-Poisson generalised additive mixed model showed that the deployment of drumlines had no significant effect on the catch rate of sharks in nets. The nets, however, caught significantly larger sharks (mean 184.5 cm, SD 39) than did drumlines (mean 138.6 cm, SD 36.5; p < 0.001). The size frequency of the catch was unimodal and females significantly outnumbered males in both gear types. Few young-of-the-year (0.8%) or mature sharks (1.8%) were caught. Only 23 (4.7%) of the 486 sharks tagged and released were recaptured, with the majority (87.0%) of those recaptured <150 km from their original tagging locality. The results from this study suggest an increasing local population trend in G. cuvier along the KwaZulu-Natal coast.     

Mass data processing of time series Landsat imagery: pixels to data products for forest monitoring

Free and open access to the Landsat archive has enabled the implementation of national and global terrestrial monitoring projects. Herein, we summarize a project characterizing the change history of Canada’s forested ecosystems with a time series of data representing 1984–2012. Using the Composite2Change approach, we applied spectral trend analysis to annual best-available-pixel (BAP) surface reflectance image composites produced from Landsat TM and ETM+ imagery. A total of 73,544 images were used to produce 29 annual image composites, generating ～400 TB of interim data products and resulting in ～25 TB of annual gap-free reflectance composites and change products. On average, 10% of pixels in the annual BAP composites were missing data, with 86% of pixels having data gaps in two consecutive years or fewer. Change detection overall accuracy was 89%. Change attribution overall accuracy was 92%, with higher accuracy for stand-replacing wildfire and harvest. Changes were assigned to the correct year with an accuracy of 89%. Outcomes of this project provide baseline information and nationally consistent data source to quantify and characterize changes in forested ecosystems. The methods applied and lessons learned build confidence in the products generated and empower others to develop or refine similar satellite-based monitoring projects.     

Effects of Tree Size,Shade Tolerance,and Spatial Pattern on the Mortality of Woody Plants in a Seminatural Forest in Central Kentucky

Previous biogeographical research has investigated the mortality of woody plants, emphasizing tree size, shade tolerance, and competition individually as critical factors. Few researchers, though, have empirically evaluated the simultaneous and relative importance of these three factors in a single study. Based on a thirty-five-year study within the University of Kentucky Arboretum, we report that none of the factors exerted an overriding influence on the tree survivorship alone. Rather, they were tightly intertwined in a complex way. Our study indicates that the three factors have contributed perhaps equally or at least simultaneously to the overall demographic processes in the woodland.     

Modified passive capillary samplers for collecting samples of snowmelt infiltration for stable isotope analysis in remote,seasonally inaccessible watersheds 1: laboratory evaluation

Snowmelt is the most significant source of runoff generation and recharge in many of the mountainous watersheds worldwide and this is especially true in the southwestern United States. Yet, the isotopic and geochemical composition of the soil–meltwater endmember remains poorly constrained. Using the isotopic compositions of snow and snowmelt runoff samples taken from the landscape surface as proxies for soil–meltwater endmembers is problematic since they are typically not representative of the actual composition of soil meltwater. Furthermore, the applicability of current methodologies to collect the isotopic composition of meltwater is limited because of the remote and often seasonally inaccessible nature of the terrain where snowpacks develop. Therefore, a robust methodology requiring little maintenance or monitoring is desirable. A lab experiment was conducted to determine the suitability of using a modified passive capillary sampler (M‐PCAPS) design to collect snowmelt infiltration for isotopic analysis. Passive capillary samplers are constructed from fiberglass wicks that can be installed in the soil to sample vadose‐zone waters under a wide range of matric potentials and require little maintenance. Results from this lab experiment indicate that the wicking process associated with M‐PCAPS does not fractionate water but certain precautions are necessary to prevent exchange between the wick and the atmosphere. In this experiment, M‐PCAPS effectively tracked the changing isotopic composition of a soil reservoir undergoing evaporation. Therefore, M‐PCAPS provide a robust methodology to sample the isotopic composition of snowmelt infiltration in remote watersheds and similar applications. Copyright © 2009 John Wiley & Sons, Ltd.     

On the coattails of climate? Opportunities and threats of a warming Earth for biodiversity conservation

The relationship between climate change and biodiversity was a central issue at the 10th Conference of the Parties (COP 10) to the Convention on Biological Diversity (CBD). In this paper we draw from participant observation data collected at COP 10, and related policy documentation, to examine how concerns about climate change are shaping the conservation policy landscape – in terms of the knowledge and rationales used as inputs, networks of actors involved, objectives sought, and actions proposed. We find that debates at the intersection of climate and biodiversity were overwhelmingly framed in relation to, or through the lens of carbon. Through a discussion of four core Climate-Motivated Responses, we illustrate how “carbon-logic”, and the initiatives that it generates, simultaneously creates threats to the objectives sought by some actors, and opportunities for the objectives sought by others. We situate our observations in the context of some of the historical dilemmas that have faced conservation, and discuss this current moment in the dynamic trajectory of conservation governance: a moment when decisions about conserving biodiversity are becoming entangled with carbon-logic and the market. In this case, while some actors seek opportunities for biodiversity ends by riding the coattails of the climate agenda, the threats of doing so may undermine the biological and social objectives of the CBD convention itself.     

Amazonian magnetostratigraphy: Dating the first pulse of the Great American Faunal Interchange

The chronostratigraphy of the youngest Neogene deposits of the Amazon Basin, which comprise the Madre de Dios Formation in eastern Peru, remains unresolved. Although ⁴⁰Ar/³⁹Ar dates on two volcanic ashes from this formation in Peru provide critical baseline data points, stratigraphic correlations among scattered riverine outcrops in adjacent drainage basins remain problematic. To refine the chronostratigraphy of the Madre de Dios Formation, we report here the magnetostratigraphy of an outcrop on the Madre de Dios River in southeastern Peru. A total of 18 polarity zones was obtained in the ～65-m-thick Cerro Colorado section, which we correlate to magnetozones Chrons C4Ar to C2An (9.5–3.0 Ma) based on the prior ⁴⁰Ar/³⁹Ar dates. These results confirm the late Miocene age of a gomphothere recovered from the Ipururo Formation, which underlies the late Miocene Ucayali Unconformity at the base of the Cerro Colorado outcrop. The results also support earlier interpretations of a late Miocene age for other fossils of North American mammals recovered from basal conglomeratic deposits of the Madre de Dios Formation immediately above the Ucayali Unconformity. These mammals include other gomphotheres, peccaries, and tapirs, and their presence in South America in the late Miocene is recognized as part of the first pulse of the Great American Faunal Interchange.     

Determination of Free Cd,Cu and Zn Concentrations in Lake Waters by In Situ Diffusion Followed by Column Equilibration Ion-exchange

Combining in situ diffusion and column ion-exchange equilibration, we measured free metal ion concentrations (Cd, Cu and Zn) in water samples collected from the epilimnion of 14 lakes in the Rouyn-Noranda area (600 km north-west of Montreal, QC, Canada). Lakes were selected to represent a wide range of physico-chemical characteristics (hardness, pH, dissolved organic matter—DOM, degree of metal contamination), to determine the influence of these parameters on metal speciation. Total dissolved metal concentrations, as determined within the diffusion cells, varied over one to two orders of magnitude: [Cd] 0.19–2.9 nM; [Cu] 36–190 nM; [Zn] 7–2,800 nM. The proportion of total dissolved metal present as free Cd²⁺ and Zn²⁺ was relatively constant for the 14 selected lakes, despite the wide pH (4.5–8) and DOM (3–23 mg C/L) ranges, probably reflecting the inverse relationship observed between pH and DOM; this proportion did, however, vary with DOM and pH for Cu. Our experimental free metal ion concentrations were compared with those calculated with the thermodynamic models WHAM (Windermere Humic Aqueous Model VI) and ECOSAT 4.7 (incorporating the NICA-Donnan model). Measured and calculated values were in reasonable agreement for both Cd and Zn although measured values were generally slightly higher, i.e. less than one order of magnitude. For several lakes, measured free Cu concentrations were, however, much higher than the calculated values, suggesting that these models overestimate Cu complexation. The gap between measured and calculated free metal ion concentration becomes more important as the total metal concentration decreases and as pH increases.     

Keeping the stress off the sheep? Agricultural intensification, neoliberalism, and ‘good’ farming in New Zealand

Under neoliberal schemes like audit systems, consumer demands born of concerns about food safety, the environment and animal welfare are theoretically poised to influence agricultural production systems (Campbell and Le Heron, 2007). Whether such influences might reverse or redirect the trend toward environmentally-damaging rampant productivism of the 20th century hinges in part on the subjective positions of farmers and the ways in which they inform how farmers respond to policy and market signals.In this paper we argue the need for a genuine engagement with both the complexities of farmer subjectivity and the interactions amongst farmer subjectivity and agro-ecologies, and animal bodies in particular. This paper presents a case study of sheep farmers on the South Island that reveals contestation and transitions in traditional markers of “good farming”, particularly animal health. We observe how such transitions arise from reconfigurations of the relationships between agro-ecological, political and social histories. In this paper’s formulation, neither state subsidies nor neoliberalism in agriculture is primary cause or ultimate effect of the transformation of agricultural practice. Rather, changes in the political economy expose contradictions in farmer subjectivities, the resolution of which may block or reinforce trends suggested by the political economy. We suggest that contested ideas about animal health within the social field of pastoral farming in New Zealand makes it possible that New Zealand’s sheep growers may take the high road of best environmental practice via highly audited environmental standards of production demanded by elite consumer markets, or that they may remain in the intensifying trajectory of continuing to drive the sheep’s body to its maximum possible intensity of production. The mixed legacy of neoliberal reform is that it has simultaneously enabled both of these contradictory trajectories in New Zealand pastoralism.