Approaches to equilibrium in the distribution of trace elements among the principal minerals in a high-grade metamorphic terrane

X-ray fluorescence, instrumental neutron activation, and particle-induced X-ray emission methods were used to determine the distribution of numerous trace elements among garnet (Grt), Ca-pyroxene (Cpx), hornblende (Hbl), biotite (Bt), plagioclase (Pl) and K-feldspar (Kf) in a high-grade metamorphic terrane within the Grenville Province of the Canadian Shield. Results are presented as distribution formulae, e.g. Sr: Kf 1.1 Pl 16 Hbl 2.2 Cpx 1.0 Bt 1.2 Grt Sc: Hbl 1.1 Cpx 1.0 Grt 7.8 Bt 22 Pl 2.6 Kf V: Hbl 1.15 Bt 2.07 Cpx 6.0 Grt (1.4% CaO)>1 (Pl, Kf) Zn: Bt 1.6 Hbl 1.62 Cpx 2.9 Grt 10 Pl Ga: Bt 1.2 Hbl 1.2 Pl 2.5 Cpx 1.3 Grt where numbers are distribution ratios, e.g. ppm Sr in Hbl/ppm Sr in Cpx=2.2. Examples of inter-element similarities and differences are (a) both Rb and Cs are concentrated in biotite relative to K-feldspar, but for Rb the ratio is 2.3 and for Cs it is 16, (b) the distribution formulae for seven lanthanides are similar except for the position of garnet, e.g. Ce: Hbl 2.7 Cpx 2.8 Pl 1.1 Bt 11 Kf 16 Grt Yb: Grt 2.8 Hbl 2.7 Cpx 9 Pl 1.0 Bt 7 Kf and (c) all of Sr, eight lanthanides, Zr, V and Cr are concentrated in hornblende relative to Ca-pyroxene by a factor that lies in the narrow range of 2.2–3.1. There is a larger variation (departure from the mean) in some distribution ratios than in others. Thus the mean ratios (Hbl/Cpx) for each of six elements and in parentheses the percentage relative standard deviation are Zn 1.62 (8.6), V 2.38 (12), Cr 2.42 (18), Sr 2.7 (28), Ba 2.9 (36) and Ni 1.66 (38). We suggest that variation of this kind is the result of differences from place to place in the magnitude of deformation and recrystallization (which facilitated the rearrangement of atoms), combined with rates of lattice and crystal-boundary diffusion that are unique for the various elements, thus permitting some trace elements to approach equilibrium more closely than others.     

Proximity in a Ghanaian savanna: Human reactions to the African palm civet Nandinia binotata

Understanding human reactions to wildlife, including the differing reactions of different groups to different species, is important given that expanding human population and settlements increasingly result in natural habitat loss or modification and, consequently, wildlife adaptation and encroachment into cleared and created human spaces such as wastelands and farms. This paper examines the importance of gender and age in the responses of rural coastal villagers in Ghana to the presence of African palm civets. Social data gathered from 450 residents in six villages indicated that women and young people were significantly more fearful of civets, seeing them as village marauders, food thieves and livestock predators. Women were also more likely to carry sticks and beat thick vegetation to dispel civets out of concern for the safety of their children and homes. These findings may inform both rural development and conservation debates and policies.     

How processing digital elevation models can affect simulated water budgets

For regional models, the shallow water table surface is often used as a source/sink boundary condition, as model grid scale precludes simulation of the water table aquifer. This approach is appropriate when the water table surface is relatively stationary. Since water table surface maps are not readily available, the elevation of the water table used in model cells is estimated via a two-step process. First, a regression equation is developed using existing land and water table elevations from wells in the area. This equation is then used to predict the water table surface for each model cell using land surface elevation available from digital elevation models (DEM). Two methods of processing DEM for estimating the land surface for each cell are commonly used (value nearest the cell centroid or mean value in the cell). This article demonstrates how these two methods of DEM processing can affect the simulated water budget. For the example presented, approximately 20% more total flow through the aquifer system is simulated if the centroid value rather than the mean value is used. This is due to the one-third greater average ground water gradients associated with the centroid value than the mean value. The results will vary depending on the particular model area topography and cell size. The use of the mean DEM value in each model cell will result in a more conservative water budget and is more appropriate because the model cell water table value should be representative of the entire cell area, not the centroid of the model cell.     

Melting and thermal expansion in the Fe–FeO system at high pressure

Melting in the Fe–FeO system was investigated at pressures up to 93 GPa using synchrotron X-ray diffraction (XRD) and a laser heated diamond anvil cell (DAC). The criteria for melting were the disappearance of reflections associated with one of the end-member phases upon raising the temperature above the eutectic and the reappearance of those reflections on dropping the temperature below the eutectic. The Fe–FeO system is a simple eutectic at 50 GPa and remains eutectic to at least 93 GPa. The eutectic temperature was bound at several pressure points between 19 and 93 GPa, and in some cases the liquidus temperature was also determined. The eutectic temperature rises rapidly with pressure closely following the melting curve of pure Fe. A detailed phase diagram at 50 GPa is presented; the eutectic temperature is 2500 ± 150 K and the eutectic composition is bound between 7.6 ± 1.0 and 9.5 ± 1.0 wt.% O. The coefficient of thermal expansion of FeO is a strong function of volume and decreases with pressure according to a simple power law.     

Evaluation of stony coral indicators for coral reef management

Colonies of reef-building stony corals at 57 stations around St. Croix, US Virgin Islands were characterized by species, size and percentage of living tissue. Taxonomic, biological and physical indicators of coral condition were derived from these measurements and assessed for their response to gradients of human disturbance—a requirement for indicators used in regulatory assessments under authority of the Clean Water Act. At the most intensely disturbed location, five of eight primary indicators were highly correlated with distance from the source of disturbance: Coral taxa richness, average colony size, the coefficient of variation of colony size, total topographic coral surface area, and live coral surface area. An additional set of exploratory indicators related to rarity, reproductive and spawning mode and taxonomic identity were also screened. The primary indicators demonstrated sufficient precision to detect levels of change that would be applicable in a regional-scale regulatory program.     

Detrital zircon U-Pb-He double dating: A method of quantifying long- and short-term exhumation rates in collisional orogens

A U-Pb-He double-dating method is applied to detrital zircons with core-rim structure from the Ganges River in order to determine average short- and long-term exhumation rates for the Himalayas. Long-term rates are calculated from the U/Pb ages of metamorphic rims of the grains that formed during the Himalayan orogeny and their crystallization temperatures, which are calculated from the Ti-in-zircon thermometer. Short-term rates are calculated from(U-Th)/He ages of the grains with appropriate closure temperatures. The results show that short-term rates for the Himalayas, which range from 0.70 ± 0.09 to 2.67 ± 0.40 km/Myr and average 1.75 ± 0.59(1±) km/Myr, are higher and more varied than the long-term rates, which range from 0.84 ± 0.16 to 1.85 ± 0.35 km/Myr and average 1.26 ± 0.25(1±) km/Myr. The differences between the long-term and short-term rates can be attributed to continuous exhumation of the host rocks in different mechanisms in continental collision orogen. The U/Pb ages of 44.0 ± 3.7 to 18.3 ± 0.5 Ma for the zircon rims indicate a protracted episode of ~25 Myr for regional metamorphism of the host rocks at deeper crust, whereas the(U-Th)/He ages of 42.2 ± 1.8 to 1.3 ± 0.2 Ma for the zircon grains represent a protracted period of ~40 Myr for exposure of the host rocks to shallower crustal level. In particular, the oldest(U-Th)/He ages of the zircon grains are close to the oldest U/Pb ages for the rims, indicating that some parcels of the rocks that contain zircons were rapidly exhumed from deep to shallow levels in the stage of collisional orogeny. On the other hand, some parcels of the rocks may have been carried upwards by thrust faults in the post-collisional stage. The parcels could be carried upwards by the thrust faults that steepen as they near the surface, or by transient movement faults so that areas of rapid exhumation became areas of slow exhumation and visa versa on a time scale of a few Myr in order to maintain the continuous exhumation. In this regard, the Ganges River must be preferentially sampling areas that are currently undergoing above average rates of uplift.     

The stabilizing effect of viscosity on magnetic wind flows from accretion discs

Magnetically channelled winds are believed to be a feature of most accretion discs. It has been shown that such flows can remove significant amounts of angular momentum from the disc and make a major contribution to driving the inflow. For a suitable range of poloidal magnetic field bending, only a small fraction of the disc mass is lost in the wind flow, so most material reaches the inner region of the disc. However, discs driven purely by such a process are prone to a field-bending instability which can lead to runaway mass loss. It is shown here that a small amount of disc viscosity can quench such an instability and allow steady disc-wind models to be constructed. The effects of perturbations to the coupling between the radial and vertical structures are allowed for, with the thermal balance having particular relevance. Runaway increases in field bending are prevented by increases in the disc temperature and magnetic diffusivity mainly caused by viscous dissipation.     

Radar Detection of Near-Earth Asteroids 2062 Aten, 2101 Adonis, 3103 Eger, 4544 Xanthus, and 1992 QN

We describe Doppler-only radar observations of near-Earth asteroids 2062 Aten, 2101 Adonis, 3103 Eger, 4544 Xanthus, and 1992 QN that were obtained at Arecibo and Goldstone between 1984 and 1996. Estimates of the echo spectral bandwidths, radar cross sections, and circular polarization ratios of these objects constrain their pole-on breadths, radar albedos, surface roughnesses, taxonomic classes, rotation periods, and pole directions. Aten's bandwidth is consistent with its radiometrically determined diameter of 0.9 km. Adonis has a rotation periodP≤ 11 h and an effective diameter (the diameter of a sphere with the same projected area as the asteroid) between 0.3 and 0.8 km. The radar properties of Adonis suggest it is not a member of taxonomic classes C or M. The effective diameter of Xanthus is between 0.4 and 2.2 km with a rotation periodP≤ 20 h. Echoes from 1992 QN constrain the asteroid's pole-on breadth to be ≥0.6 km and probably exclude it from the C and M taxonomic classes. The strongest Eger echoes are asymmetric with bandwidths that set lower bounds of 1.5 and 2.3 km on the minimum and maximum breadths of the asteroid's pole-on silhouette. If Eger is modeled as a 1.5 × 2.3 km biaxial ellipsoid, then its effective diameter for an equatorial view is 1.5 km end-on and 1.9 km broadside or pole-on, implying a geometric albedo smaller than published values but still consistent with a classification as an E-type object. The near-unity circular polarization ratios of Adonis, Eger, and 1992 QN are among the highest values measured for any asteroid or comet and suggest extreme near-surface roughness at centimeter to meter scales.     

Garn Prŷs: A mid-Silurian canyon,feeder to the Denbigh Grits of North Wales

A fining-upward, siliciclastic sequence of Wenlock strata, coarsely rudaceous at the base, infilled a canyon, about 4.5 km wide and 1700 m deep, in older strata. The rudaceous deposits, at the flat base of the canyon, are composed mainly of rounded cobbles and boulders of acid volcanic rocks. These are interpreted as cohesionless debris-flow deposits that were succeeded by northward-directed high concentration turbidity currents. The infill is deduced to have been derived from a terrain of acid volcanic rocks to the south, similar in Nd isotope composition to the Llewelyn Volcanic Group of Snowdonia. It implies mid-Silurian uplift and erosion of the Harlech Dome.