The behavior of apatite during crustal anatexis: Equilibrium and kinetic considerations

The solubility and dissolution kinetics of apatite in felsic melts at 850°–1500°C have been examined experimentally by allowing apatite crystals to partially dissolve into apatite-undersaturated melts containing 0–10 wt% water. Analysis of P and Ca gradients in the crystal/melt interfacial region enables determination of both the diffusivities and the saturation levels of these components in the melt. Phosphorus diffusion was identified as the rate-limiting factor in apatite dissolution. Results of four experiments at 8 kbar run in the virtual absence of water yield an activation energy (E) for P diffusion of 143.6 ± 2.8 kcal-mol^?1 and frequency factor (D₀) of 2.23^+2.88_?1.26 × 10⁹cm²-sec^?1. The addition of water causes dramatic and systematic reduction of both E and D₀ such that at 6 wt% H₂O the values are ~25 kcal-mol^?1 and 10^?5 cm²-sec^?1, respectively. At 1300°C, the diffusivity of P increases by a factor of 50 over the first 2% of water added to the melt, but rises by a factor of only two between 2 and 6%, perhaps reflecting the effect of a concentration-dependent mechanism of H₂O solution. Calcium diffusion gradients do not conform well to simple diffusion theory because the release of calcium at the dissolving crystal surface is linked to the transport rate of phosphorus in the melt, which is typically two orders of magnitude slower than Ca. Calcium chemical diffusion rates calculated from the observed gradients are about 50 times slower than calcium tracer diffusion.Apatite solubilities obtained from these experiments, together with previous results, can be described as a function of absolute temperature (T) and melt composition by the expression: In D^apatite/melt_P = [(8400 + ((SiO₂ ? 0.5)2.64 × 10⁴))/T] ? [3.1 + (12.4(SiO₂ ? 0.5))] where SiO₂ is the weight fraction of silica in the melt. This model appears to be valid between 45% and 75% SiO₂, 0 and 10% water, and for the range of pressures expected in the crust.The diffusivity information extracted from the experiments can be directly applied to several problems of geochemical interest, including I) dissolution times for apatite during crustal anatexis, and 2) pileup of P, and consequent local saturation in apatite, at the surfaces of growing major-mineral phases.     

On the ultracompact nature of 4U 1822−000

We report the discovery of a periodic modulation in the optical lightcurve of the candidate ultracompact X-ray binary 4U 1822−000. Using time-resolved optical photometry taken with the William Herschel Telescope we find evidence for a sinusoidal modulation with a semi-amplitude of 8 per cent and a period of 191 min, which is most likely close to the true orbital period of the binary. Using the van Paradijs & McClintock relation for the absolute magnitude and the distance modulus allowing for interstellar reddening, we estimate the distance to 4U 1822−000 to be 6.3 kpc. The long orbital period casts severe doubts on the ultracompact nature of 4U 1822−000.     

A method for assessing local variation among scattered measurements

Automatic triangulation of scattered locations permits analysis of local variation in a dependent variable through calculation of a roughness index. This is approached by treating triangles of the triangulation (including the dependent variable) as vectorial structures, and accumulating at each data point the vector sum of the cluster of triangles surrounding it. The roughness index is defined as the complement of the ratio of the area of a triangle cluster to the area of component triangles as projected onto a gradient plane defined by their vector sum. The roughness index provides a measure of consistency of data values relative to surrounding observations and can be interpreted as a local index of reliability of interpolation.     

MAGNETISM OF METEORITES: A REVIEW OF RUSSIAN STUDIES

We present here a summary review of the work of Russian scientists, primarily Gus'kova and Pochtarev, on the magnetism of meteorites. They have measured the initial natural remanent magnetization and the magnetic susceptibility in more than 900 meteorite samples from collections throughout the Soviet Union. More sophisticated studies, involving both thermal and alternating field demagnetization experiments, were also conducted on a few samples. Meteorites almost invariably retain evidence of ancient magnetic fields in their pre-terrestrial history     

Glutathione S-transferase from an antarctic fish, Dissostichus mawsoni

Glutathione S-transferase activity was measured in the hepatic cytosol front Dissostichus mawsoni and Pagothenia borchgrevinki. Activity measures with 1-chloro-2,4-dinitrobenzene as substrate were 11·2 and 16·7 μmol/min/g tissue respectively. Little or no activity was detected when p-nitrobenzyl chloride or 3,4-dichloro-1-nitrobenzene were used as substrate. The hepatic glutathione S-transferases from D. mawsoni were partially purified using gel filtration and chromatofocusing. Three peaks of activity were resolved. The major isozyme (158-fold purification) eluting at pH7·1 appeared to be catalytically a homodimer. The isozyme was highly inhibited by triphenyltin chloride (IC₅₀ = 0·1 μ) while inhibition constants for Cibicron Blue 3GA, bromosulphophalein and hematin were 1·1, 20 and 34 μ respectively.     

Cultural and economic residential sorting of Auckland’s population, 1991–2013: an entropy approach

Journal of Geographical Systems - Auckland, the largest city of New Zealand, is one of the most diverse cities in the world, with more than 40% of its population born abroad, more than 200...     

The Millennium Galaxy Catalogue: bulge–disc decomposition of 10 095 nearby galaxies

We present near-infrared (NIR) adaptive optics-assisted spectroscopic observations of the  CO (Δμ= 2)  absorption bands towards the centre of the giant elliptical galaxy NGC 1399. The observations were made with NAOS-CONICA (on the European Southern Observatory's Very Large Telescope) and have a full width at half-maximum resolution of 0.15 arcsec (14 pc). Kinematic analysis of the observations reveals a decoupled core and strongly non-Gaussian line-of-sight velocity profiles in the central 0.2 arcsec (19 pc). NIR imaging also indicates an asymmetric elongation of the central isophotes in the same region.
We use spherical orbit-superposition models to interpret the kinematics, using a set of orthogonal 'eigen-velocity profiles' that allow us to fit models directly to spectra. The models require a central black hole of mass  1.2^+0.5_−0.6× 10⁹ M_⊙  , with a strongly tangentially biased orbit distribution in the inner 40 pc.     

Recent morphological evolution of the Lower Mississippi River

This study documents slope and stream power changes in the Lower Mississippi River during the pre-cutoff (1880s–1930s), and post-cutoff (1943–1992) periods. The study reach extends from New Madrid, MO, to Natchez, MS, a distance of about 900 km. Analyses for six major reaches and 13 sub-reaches for the pre- and post-cutoff periods indicate that the river presently has a much larger slope and stream power than prior to the cutoffs. The largest increases have occurred between Fulton, TN, and Lake Providence, LA, where slope and stream power increases range from about 27% to 36% and 20% to 38%, respectively. Increases in slope and stream power in reaches upstream and downstream have also occurred, but to a lesser degree. Previous investigations have shown that no coarsening of the bed material has occurred since 1932, and that the bed material may actually be somewhat finer overall. As the Lower Mississippi River is not a sediment-starved system, an increase in stream power with no change in D₅₀ would be expected to be offset by an increase in the bed material load as the river adjusts towards equilibrium. Previous investigators have inferred a reduction in the sediment loads on the Mississippi River this century based on analyses of total measured suspended loads. However, these results should be viewed as primarily representing the changes in wash load and should not be taken to imply that bed material loads have also decreased. Therefore, the bed material loads in the study reach should be greater than in the pre-cutoff period. Excess stream power in the sub-reaches directly affected by cutoffs resulted in scour that increased downstream bed material load. These elevated sediment loads play a key role in driving morphological adjustments towards equilibrium in the post-cutoff channel. The stability status of the channel in the study reach currently ranges from dynamic equilibrium in the farthest upstream reaches through severe degradation to dynamic equilibrium in the middle reaches, and aggradation in the lowest reaches. These evolutionary trends cannot be explained by consideration of changes in slope and stream power alone. Changes in the incoming bed material load to each reach generated by upstream channel evolution must also be considered.     

Trace metals in the Western Pacific: temporal and spatial variability in the concentrations of Cd, Cu, Mn and Ni

Profiles of total dissolvable Cd, Cu, Mn and Ni are reported for samples collected from the southwest Pacific in 1989, from the western equatorial Pacific along 155°E at 5°S, 0° and 5°N in 1990 and 1993, and along the equator from 143°E to 152°E and in the Bismarck Sea in 1997 and 2000. Profiles of Cd along 155°E in 1990 and along the equator were essentially the same but, in 1993, Cd values at 5°N were higher by a factor of about 1.5–2 than at 5°S over the depth range 500–1500 m. Similar, but less pronounced, differences were observed for PO₄ and Ni. Cd and Ni were both strongly correlated with PO₄, and an even stronger correlation was found between Ni and Cd. The concentration of Ni did not fall below ≈2 nmolkg⁻¹, even in the nitrate-depleted waters of the western equatorial Pacific, where primary production is strongly dependent on recycled nitrogen (mainly ammonia and urea). It is proposed that this residual Ni is not bioavailable and that Ni could be biolimiting, since the metabolism of urea requires the nickel-containing enzyme urease. The impact of the Sepik River on Cd, Cu and Ni concentrations was small but elevated concentrations of Mn were observed near the Sepik River and close to the coast suggesting that the rivers and sediments on the north coast of New Guinea are a significant local source of Mn to the Bismarck Sea. Simple mass balance calculations show that the elevated levels of Mn observed in the Equatorial Undercurrent cannot be due to input from the rivers of New Guinea and they were attributed to the trapping of particulate matter due to strong current shear. A strong hydrothermal source of Mn was observed in the central Bismarck Sea.